Water-soluble copper phthalocyanine dyestuffs, their preparation and
their use
    4.
    发明授权
    Water-soluble copper phthalocyanine dyestuffs, their preparation and their use 失效
    水溶性铜酞菁染料,其制备及其用途

    公开(公告)号:US5882360A

    公开(公告)日:1999-03-16

    申请号:US918599

    申请日:1997-08-24

    摘要: The present application relates to water-soluble copper phthalocyanine dyestuffs of the formula I ##STR1## in which CuPc is a copper phthalocyanine radical;X is a straight-chain or branched alkylene having 2 to 6 carbon atoms;Y is a straight-chain or branched alkylene having 2 to 6 carbon atoms or a straight-chain or branched alkylene having 1 to 6 carbon atoms which is substituted by hydroxyl, carboxyl or amino;R.sup.1 and R.sup.2 independently of one another are hydrogen or alkyl having 1 to 4 carbon atoms;R.sup.3 represents hydrogen, alkyl having 1 to 4 carbon atoms, hydroxyalkyl having 1 to 4 carbon atoms or aminoalkyl having 1 to 4 carbon atoms;R.sup.4 is hydrogen or alkyl having 1 to 4 carbon atoms;M is a monovalent cation or one equivalent of a polyvalent cation;a and b independently of one another are 1 or 2 andc is 0 or 1the sum a+b+c being 3 or 4,processes for their preparation, their use for dyeing and printing naturally occurring and synthetic fiber materials, and recording liquids, in particular for the inkjet process, and liquid formulations for pulp-dyeing of paper which comprise the dyestuffs according to the invention.

    摘要翻译: 本申请涉及式I的苯胺衍生物的水溶性铜酞菁染料; X是具有2至6个碳原子的直链或支链亚烷基; Y是具有2至6个碳原子的直链或支链亚烷基或被羟基,羧基或氨基取代的具有1至6个碳原子的直链或支链亚烷基; R 1和R 2彼此独立地是氢或具有1至4个碳原子的烷基; R 3表示氢,具有1至4个碳原子的烷基,具有1至4个碳原子的羟基烷基或具有1至4个碳原子的氨基烷基; R4是氢或具有1至4个碳原子的烷基; M是一价阳离子或一当量的多价阳离子; a和b彼此独立地为1或2,c为0或1,总和a + b + c为3或4,其制备方法,用于染色和印刷天然存在的和合成纤维材料,以及记录液 ,特别是用于喷墨方法,以及用于纸浆染色的液体制剂,其包含根据本发明的染料。

    Ink and ink jet recording method employing the same
    6.
    发明授权
    Ink and ink jet recording method employing the same 失效
    墨水和墨水喷射记录方法

    公开(公告)号:US5123960A

    公开(公告)日:1992-06-23

    申请号:US584895

    申请日:1990-09-18

    摘要: An ink in which a dye and a liquid carrier medium are present. The ink includes a dye comprising a compound represented by the following general formula (I): ##STR1## wherein Ph is a copper or nickel phthalocyanine residue, M is an alkali metal or ammonium, R.sub.1 and R.sub.2 are each H, --(CH.sub.2 CH.sub.2 O).sub.m --R.sub.3 or --(CH.sub.2 CHOH).sub.m --R.sub.3 in which R.sub.3 is H, CH.sub.3, C.sub.2 H.sub.5 or CH.sub.2 OH and in which m is a number from 0 to 4, a is a number from 0 to 2, X is a lower alkylene or phenylene group, C is a number from 2 to 3, and b is a number from 0 to 2 with the proviso that when b is 0, then Y and Z are respectively Cl, OH or OR.sub.4 is an alkyl group having 1 or 2 carbons or a hydroxyalkyl group, and when b is not 0, then Y is Cl, NR.sub.5 R.sub.6 or OR.sub.7 and Z is NR.sub.5 R.sub.6, OR.sub.7, a substituted or unsubstituted anilino group or a substituted or unsubstituted phenoxy group, wherein R.sub.5 and R.sub.6 are respectively H, an alkyl group, an alkylalkoxy group or a hydroxyalkyl group and have 4 or less carbons in total and, wherein R.sub.7 is H, an alkyl group having 1 to 3 carbons or a substituted or unsubstituted phenyl group.

    Substituted phthalocyanine
    8.
    发明授权
    Substituted phthalocyanine 失效
    取代酞菁

    公开(公告)号:US4824948A

    公开(公告)日:1989-04-25

    申请号:US162513

    申请日:1988-03-01

    摘要: A phthalocyanine compound of the formula:(R--X--).sub.m Pc (--Y--R.sup.1 --Z--).sub.n (--SO.sub.3 M).sub.p IwhereinPc is a phthalocyanine nucleus (Pc);eachR independently is a monovalent aromatic radical linked to a peripheral carbon atom of the Pc nucleus through X;X selected from S, Se and Te;m is 4 to 16;eachR.sup.1 independently is a divalent aromatic radical linked to two adjacent peripheral carbon atoms of the Pc nucleus through Y and Z;Y is selected from S, NT, Se and Te;Z is selected from S, Se, Te, NT and O;T is selected from H, alkyl and aryl;n is 0 to 7;M is H, a metal or optionally-substituted ammonium;andP is from 1 to 16.The compounds have a significant absorption band in the near infra red and depending on the number of sulphonic acids groups and the nature of the counter ion are soluble in aqueous and polar organic media. The compounds are useful in many applications where absorption of infra-red radiation is desirable, such as in OCR readable inks, rapid-drying inks, security printing and reprographic toners.

    Cuprophthalocyanine type compounds
    10.
    发明授权
    Cuprophthalocyanine type compounds 失效
    铜酞菁型化合物

    公开(公告)号:US4771132A

    公开(公告)日:1988-09-13

    申请号:US865980

    申请日:1986-05-22

    CPC分类号: C09B62/10 C09B47/26 D06P1/38

    摘要: A cuprophthalocyanine type compound represented by formula [1] in the form of free acid ##STR1## (wherein D is a cuprophthalocyanine radical; B is an alkylene group of 2 to 4 carbon atoms or a phenylene group which may have one or two carboxyl group(s) or sulfonic acid group(s) as a substituent(s); R is a lower alkyl group or a lower alkoxy-lower alkyl group; X is a carboxyl group or a carbamoyl group and combines with the 3- or 4-position of the pyridine ring; l is 1, 2 or 3; m is 0, 1 or 2; n is 1 or 2; and the sum of l, m and n is 2, 3 or 4) as well as a method for dyeing cellulosic fiber materials using the said compounds.

    摘要翻译: 由游离酸形式[1]表示的式[1]表示的酞菁酞菁类化合物(其中D为铜酞菁基; B为2至4个碳原子的亚烷基或亚苯基,可以具有一个或多个 两个羧基或磺酸基作为取代基; R是低级烷基或低级烷氧基 - 低级烷基; X是羧基或氨基甲酰基,并与3- 或吡啶环的4-位; l为1,2或3; m为0,1或2; n为1或2; l,m和n的和为2,3或4)以及 使用所述化合物染色纤维素纤维材料的方法。