公开(公告)号：US07759534B2

公开(公告)日：2010-07-20

申请号：US12181771

申请日：2008-07-29

申请人： Philibert Leflaive ,  Lue Wolff ,  Damien Leinekugel Le Cocq

发明人： Philibert Leflaive ,  Lue Wolff ,  Damien Leinekugel Le Cocq

IPC分类号： C07C7/12

CPC分类号： B01D15/185 ,  C07C7/12 ,  C07C7/13 ,  C07C15/08

摘要： Process for separating paraxylene with a purity that is at least equal to 99.5% by weight from an aromatic feedstock F in a single adsorption stage in a simulated moving bed (SMB), comprising different numbers of beds, allocated to a zone 1 between the supply of the desorbent D and the draw-off of the extract E; a zone 2 between the draw-off of the extract E and the supply of the feedstock F; a zone 3 between the supply of the feedstock and the draw-off of the raffinate R; a zone 4 between the draw-off of the raffinate R and the supply of the desorbent D, wherein an SMB of 12 adsorbent beds has bed configuration (2, 5, 3, 2), an SMB of 15 adsorbent beds has bed configuration (3, 6, 4 , 2), or an SMB of 19 adsorbent beds has bed configuration (4, 7, 6, 2), wherein the desorbent in this latter case is paradiethylbenzene.

摘要翻译： 在模拟移动床（SMB）中在单个吸附阶段中从芳香原料F分离至少等于99.5重量％的纯度的对二甲苯的方法，包括不同数量的床，分配给供应的区域1 的脱附剂D和萃取物E的排出物; 提取物E的抽出和原料F的供给之间的区域2; 在原料供应和萃余液R的排出之间的区域3; 在萃余液R的抽出和解吸剂D的供应之间的区域4，其中12个吸附床的SMB具有床构型（2,5,3,2），15个吸附床的SMB具有床构型 3，6，4，2），或19个吸附剂床的SMB具有床构型（4,7,6,2），其中在后一种情况下的解吸剂是对二甲基苯。

公开(公告)号：US20090018380A1

公开(公告)日：2009-01-15

申请号：US12181771

申请日：2008-07-29

申请人： Philibert LEFLAIVE ,  Lue Wolff ,  Damien Leinekugel Le Cocq

发明人： Philibert LEFLAIVE ,  Lue Wolff ,  Damien Leinekugel Le Cocq

IPC分类号： C07C7/12

CPC分类号： B01D15/185 ,  C07C7/12 ,  C07C7/13 ,  C07C15/08

摘要： Process for separating paraxylene with a purity that is at least equal to 99.5% by weight from an aromatic feedstock F in a single adsorption stage in a simulated moving bed (SMB), comprising different numbers of beds, allocated to a zone 1 between the supply of the desorbent D and the draw-off of the extract E; a zone 2 between the draw-off of the extract E and the supply of the feedstock F; a zone 3 between the supply of the feedstock and the draw-off of the raffinate R; a zone 4 between the draw-off of the raffinate R and the supply of the desorbent D, wherein an SMB of 12 adsorbent beds has bed configuration (2, 5, 3, 2), an SMB of 15 adsorbent beds has bed configuration (3, 6, 4, 2), or an SMB of 19 adsorbent beds has bed configuration (4, 7, 6, 2), wherein the desorbent in this latter case is paradiethylbenzene.

摘要翻译： 在模拟移动床（SMB）中在单个吸附阶段中从芳香原料F分离至少等于99.5重量％的纯度的对二甲苯的方法，包括不同数量的床，分配给供应的区域1 的脱附剂D和萃取物E的排出物; 提取物E的抽出和原料F的供给之间的区域2; 在原料供应和萃余液R的排出之间的区域3; 在萃余液R的抽出和解吸剂D的供应之间的区域4，其中12个吸附床的SMB具有床构型（2,5,3,2），15个吸附床的SMB具有床构型 3，6，4，2），或19个吸附剂床的SMB具有床构型（4,7,6,2），其中在后一种情况下的解吸剂是对二甲基苯。

公开(公告)号：US07838714B2

公开(公告)日：2010-11-23

申请号：US12181525

申请日：2008-07-29

申请人： Philibert Leflaive ,  Luc Wolff ,  Damien Leinekugel Le Cocq

发明人： Philibert Leflaive ,  Luc Wolff ,  Damien Leinekugel Le Cocq

IPC分类号： C07C7/12

CPC分类号： B01D15/185 ,  B01D53/06 ,  B01D2257/7027 ,  C07C7/13 ,  C07C15/08

摘要： Process for separation of metaxylene, with at least 99% by weight of purity of an aromatic feedstock F, in a single adsorption stage in a simulated moving bed in an SMB device that comprises 12, 13 or 15 adsorbent beds with different numbers of beds being employed in zone 1 between the supply of the desorbent D and the draw-off of the extract E; zone 2 between the draw-off of the extract E and the supply of the feedstock F; zone 3 between the supply of the feedstock and the draw-off of the raffinate R; and zone 4 between the draw-off of the raffinate R and the supply of the desorbent D whereby the process is carried out according to a configuration of zones (a, b, c, d), whereby a, b, c, and d represent the number of adsorbent beds that operate respectively in zones 1, 2, 3, 4 in which there is used: Either an SMB of 12 adsorbent beds operating according to the configuration (2, 5, 3, 2), Or an SMB of 13 adsorbent beds operating according to the configuration (2, 5, 4, 2), Or an SMB of 15 adsorbent beds operating according to the configuration (2, 6, 4, 3).

摘要翻译： 在SMB装置的模拟移动床的单个吸附阶段中分离具有至少99重量％芳族原料F的至少99重量％的间二甲苯的方法，所述SMB装置包含12,13或15个具有不同床数的吸附剂床 在供应解吸剂D与提取物E的排出之间的区域1中使用; 提取物E的抽出和原料F的供给之间的区域2; 在原料供应和萃余液R的排出之间的区域3; 和抽提物R的抽出和解吸剂D的供给之间的区域4，由此根据区域（a，b，c，d）的构造进行处理，由此a，b，c和d 表示分别在其中使用的区域1,2,3,4中操作的吸附剂床的数量：根据配置（2,5,3,2）操作的12个吸附床的SMB，或者根据配置（2,5,3,2）操作的SMB或者 13个吸附床根据结构（2,5,4,2）操作，或15个吸附床的SMB（根据配置操作（2,6,4,3））。

公开(公告)号：US20090036726A1

公开(公告)日：2009-02-05

申请号：US12181525

申请日：2008-07-29

申请人： Philibert Leflaive ,  Luc Wolff ,  Damien Leinekugel Le Cocq

发明人： Philibert Leflaive ,  Luc Wolff ,  Damien Leinekugel Le Cocq

IPC分类号： C07C7/12

CPC分类号： B01D15/185 ,  B01D53/06 ,  B01D2257/7027 ,  C07C7/13 ,  C07C15/08

摘要： Process for separation of metaxylene, with at least 99% by weight of purity of an aromatic feedstock F, in a single adsorption stage in a simulated moving bed in an SMB device that comprises 12, 13 or 15 adsorbent beds with different numbers of beds being employed in zone 1 between the supply of the desorbent D and the draw-off of the extract E; zone 2 between the draw-off of the extract E and the supply of the feedstock F; zone 3 between the supply of the feedstock and the draw-off of the raffinate R; and zone 4 between the draw-off of the raffinate R and the supply of the desorbent D whereby the process is carried out according to a configuration of zones (a, b, c, d), whereby a, b, c, and d represent the number of adsorbent beds that operate respectively in zones 1, 2, 3, 4 in which there is used: Either an SMB of 12 adsorbent beds operating according to the configuration (2, 5, 3, 2), Or an SMB of 13 adsorbent beds operating according to the configuration (2, 5, 4, 2), Or an SMB of 15 adsorbent beds operating according to the configuration (2, 6, 4, 3).

摘要翻译： 在SMB装置的模拟移动床的单个吸附阶段中分离具有至少99重量％芳族原料F的至少99重量％的间二甲苯的方法，所述SMB装置包含12,13或15个具有不同床数的吸附剂床 在供应解吸剂D与提取物E的排出之间的区域1中使用; 提取物E的抽出和原料F的供给之间的区域2; 在原料供应和萃余液R的排出之间的区域3; 和抽提物R的抽出和解吸剂D的供给之间的区域4，由此根据区域（a，b，c，d）的构造进行处理，由此a，b，c和d 表示分别在其中使用的区域1,2,3,4中操作的吸附剂床的数量：根据配置（2,5,3,2）操作的12个吸附床的SMB，或者根据配置（2,5,3,2）操作的SMB或者 13个吸附床根据结构（2,5,4,2）操作，或15个吸附床的SMB（根据配置操作（2,6,4,3））。

公开(公告)号：US09365470B2

公开(公告)日：2016-06-14

申请号：US14125317

申请日：2012-04-26

申请人： Philibert Leflaive ,  Damien Leinekugel Le Cocq

发明人： Philibert Leflaive ,  Damien Leinekugel Le Cocq

IPC分类号： C07C7/12 ,  C07C7/13 ,  B01D15/18

CPC分类号： C07C7/12 ,  B01D15/1807 ,  B01D15/1842 ,  C07C7/13 ,  C07C15/08

摘要： A simulated moving bed separation process is characterized in that the feed and desorbant injection streams are each divided into N streams (N being a whole number strictly greater than 1) injected respectively at N distinct feed injection points and at N distinct desorbant injection points, and in that the extract and raffinate withdrawal points are also each divided into N streams each withdrawn from N distinct withdrawal points, the device being constituted by 4×N chromatographic zones.

摘要翻译： 模拟移动床分离过程的特征在于，分别在N个不同的进料喷射点和N个不同的脱盐喷射点处分别注入进料和解吸剂注入流分别注入N个流（N为严格大于1的整数） 因为提取物和萃余液提取点也分别分为N个流，每个流从N个不同的取出点中取出，该装置由4×N色谱区构成。

公开(公告)号：US08123952B2

公开(公告)日：2012-02-28

申请号：US13059773

申请日：2009-07-29

申请人： Xavier Decoodt ,  Gerard Hotier ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

发明人： Xavier Decoodt ,  Gerard Hotier ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

IPC分类号： B01D15/08

CPC分类号： B01D15/1835 ,  C07C7/12 ,  C10G25/06 ,  C10G25/12 ,  C10G53/08 ,  C10G2300/1096 ,  C10G2400/02 ,  C10G2400/30 ,  C07C15/08

摘要： A process for separating a feed F by simulated moving bed adsorption in a SMB device comprises at least one zone 1 for desorption of the compounds produced in the extract, a zone 2 for desorption of the compounds produced in the raffinate, a zone 3 for adsorption of the compounds produced in the extract, a zone 4 located between the raffinate withdrawal and the desorbant supply, the device comprising external by-pass lines Li/i+1 directly connecting two successive plates Pi and Pi+1;in which the degree of opening of means for restricting the flushing flow rate of the by-pass lines Li/i+1 are sequentially modified such that: 1) in an operational zone where there is at least one closed by-pass line, a super-synchronicity of the flushing flow rate is established in all of the by-pass lines which are not closed belonging to the zone under consideration, said super-synchronicity being defined by the following formula: S=a+b(nf/nt) in which the constant a is a constant in the range −5 to 5 and b is a constant in the range 40 to 100; 2) if there is no closed by-pass line in the zone under consideration (in other words if all of the by-pass lines of the zone are open), then a flow is established in all of the flushing lines of said zone which corresponds to the synchronicity plus or minus 8%.

摘要翻译： 通过SMB装置中的模拟移动床吸附分离进料F的方法包括至少一个用于解吸萃取物中生成的化合物的区1，用于解吸萃余液中生成的化合物的区2，用于吸附的区3 在提取物中产生的化合物，位于萃余液提取和解吸剂供应之间的区域4，该装置包括直接连接两个连续板Pi和Pi + 1的外部旁路管线Li / i + 1; 其中顺序修改限制旁路线Li / i + 1的冲洗流量的装置的打开程度，使得：1）在存在至少一个封闭旁路线的操作区域中， 在所考虑的区域内的所有未闭合的旁路线中建立冲洗流速的超同步性，所述超同步性由下式定义：S = a + b（nf / nt） 其中常数a为-5至5范围内的常数，b为40至100范围内的常数; 2）如果在所考虑的区域内没有闭路旁路线（换句话说，如果该区域的所有旁路线路都是打开的），则在所述区域的所有冲洗线路中建立流动， 对应于同步加或减8％。

公开(公告)号：US20100258505A1

公开(公告)日：2010-10-14

申请号：US12757101

申请日：2010-04-09

申请人： Xavier DECOODT ,  Gerard Hotier ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

发明人： Xavier DECOODT ,  Gerard Hotier ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

IPC分类号： B01D15/02

CPC分类号： B01D15/1828 ,  C07C7/13 ,  C07C37/82 ,  C07C15/08 ,  C07C9/00 ,  C07C15/073 ,  C07C39/07

摘要： A process for separating a feed F by simulated moving bed adsorption in a SMB device is described, the device comprising external bypass lines Li/i+1 which directly connect two successive plates Pi, Pi+1, the index i being either even or (exclusive of the foregoing) odd, along the whole length of the column, in order to flush said plates, in which each of the bypass lines Li/i+1 comprises automated means for regulating the flow rate in the bypass lines, the degree of opening of said regulating means being defined by the following three rules: a) establishing a flow rate corresponding to an oversynchronicity in the range 15% to 30% in all of the open bypass lines of zone 1; b) establishing a flow rate corresponding to the synchronicity to within plus or minus 8% in all of the open bypass lines of zones 2 and 3; c) establishing a flow rate corresponding to an oversynchronicity in the range 20% to 40% in all of the open bypass lines of zone 4.

摘要翻译： 描述了一种通过SMB器件中的模拟移动床吸附分离进料F的方法，该装置包括直接连接两个连续的板Pi，Pi + 1的外部旁路管线Li / i + 1，索引i为偶数或（ 排除上述情况）奇数，为了冲洗所述板，其中每个旁路管线Li / i + 1包括用于调节旁路管线中的流量的自动装置，其程度 所述调节装置的打开由以下三个规则定义：a）在区域1的所有开放旁路管线中建立对应于15％至30％范围内的超同步性的流量; b）在区域2和3的所有开放旁路管线中建立对应于同步性在±8％以内的流量; c）在区域4的所有开启旁路管线中建立对应于超时间差在20％至40％范围内的流量。

公开(公告)号：US08658848B2

公开(公告)日：2014-02-25

申请号：US13593819

申请日：2012-08-24

申请人： Damien Leinekugel Le Cocq ,  Philibert Leflaive ,  Luc Wolff ,  Gerard Hotier

发明人： Damien Leinekugel Le Cocq ,  Philibert Leflaive ,  Luc Wolff ,  Gerard Hotier

IPC分类号： C07C7/12

CPC分类号： B01D15/1821 ,  C07C7/13 ,  C07C15/08

摘要： A process for the production of para-xylene by simulated counter-current adsorption with high flexibility with respect to a reference run (100%) uses 2 adsorbers each with 12 beds, said adsorbers being able to be connected in accordance with 3 different modes; the flexibility obtained is 50% to 150%.

摘要翻译： 通过相对于参考流程（100％）具有高柔性的模拟逆流吸附生产对二甲苯的方法使用两个具有12个床的吸附器，所述吸附器能够根据3种不同模式连接; 所获得的灵活性为50％至150％。

公开(公告)号：US08049055B2

公开(公告)日：2011-11-01

申请号：US12543091

申请日：2009-08-18

申请人： Xavier Decoodt ,  Gerard Hotier ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

发明人： Xavier Decoodt ,  Gerard Hotier ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

IPC分类号： C07C7/12

CPC分类号： B01D15/1835 ,  B01D15/1842 ,  C07C7/13 ,  C07C15/08

摘要： Process for separation of a feedstock F by adsorption in a simulated moving bed in an SMB device that comprises a zone 1 for desorption of compounds produced by extraction, a zone 2 for desorption of compounds produced with a raffinate, a zone 3 for adsorption of compounds produced by extraction, and a zone 4 that is located between the draw-off of the raffinate and the supply of the desorbent,whereby the device comprises external bypass lines Li/i+1 directly joining two successive plates Pi, Pi+, that are equipped with non-automated means for adjusting flow rate and closing means, in which the degree of opening of the restriction means of the scavenging flow rate of the bypass lines Li/i+1 is adjusted so as to obtain the best performance of the SMB.

摘要翻译： 在SMB装置的模拟移动床中通过吸附分离原料F的方法，其包括用于解吸由萃取物生产的化合物的区域1，用萃余液生产的化合物解吸区域2，用于吸附化合物的区域3 通过提取产生的区域4和位于萃余液的抽出物和解吸剂的供应之间的区域4，由此该装置包括直接连接两个连续的板Pi，Pi +的外部旁路管线Li / i + 1，其配备 用于调节旁路管线Li / i + 1的清除流量限制装置的开度的调节流量和关闭装置的非自动化装置，以获得SMB的最佳性能。

公开(公告)号：US20110201865A1

公开(公告)日：2011-08-18

申请号：US13059773

申请日：2009-07-29

申请人： Xavier Decoodt ,  Gerard Hotier ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

发明人： Xavier Decoodt ,  Gerard Hotier ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

IPC分类号： C07C7/12 ,  B01D53/08

CPC分类号： B01D15/1835 ,  C07C7/12 ,  C10G25/06 ,  C10G25/12 ,  C10G53/08 ,  C10G2300/1096 ,  C10G2400/02 ,  C10G2400/30 ,  C07C15/08

摘要： A process for separating a feed F by simulated moving bed adsorption in a SMB device comprises at least one zone 1 for desorption of the compounds produced in the extract, a zone 2 for desorption of the compounds produced in the raffinate, a zone 3 for adsorption of the compounds produced in the extract, a zone 4 located between the raffinate withdrawal and the desorbant supply, the device comprising external by-pass lines Li/i+1 directly connecting two successive plates Pi and Pi+1;in which the degree of opening of means for restricting the flushing flow rate of the by-pass lines Li/i+1 are sequentially modified such that: 1) in an operational zone where there is at least one closed by-pass line, a super-synchronicity of the flushing flow rate is established in all of the by-pass lines which are not closed belonging to the zone under consideration, said super-synchronicity being defined by the following formula: S=a+b(nf/nt) in which the constant a is a constant in the range −5 to 5 and b is a constant in the range 40 to 100; 2) if there is no closed by-pass line in the zone under consideration (in other words if all of the by-pass lines of the zone are open), then a flow is established in all of the flushing lines of said zone which corresponds to the synchronicity plus or minus 8%.

摘要翻译： 通过SMB装置中的模拟移动床吸附分离进料F的方法包括至少一个用于解吸萃取物中生成的化合物的区域1，用于解吸萃余液中生成的化合物的区域2，用于吸附的区域3 在提取物中产生的化合物，位于萃余液提取和解吸剂供应之间的区域4，该装置包括直接连接两个连续板Pi和Pi + 1的外部旁路管线Li / i + 1; 其中顺序修改限制旁路线Li / i + 1的冲洗流量的装置的打开程度，使得：1）在存在至少一个封闭旁路线的操作区域中， 在所考虑的区域内的所有未闭合的旁路线中建立冲洗流速的超同步性，所述超同步性由下式定义：S = a + b（nf / nt） 其中常数a为-5至5范围内的常数，b为40至100范围内的常数; 2）如果在所考虑的区域内没有闭路旁路线（换句话说，如果该区域的所有旁路线路都是打开的），则在所述区域的所有冲洗线路中建立流动， 对应于同步加或减8％。