-
公开(公告)号:US20100116134A1
公开(公告)日:2010-05-13
申请号:US12529198
申请日:2008-03-10
CPC分类号: B01J20/183 , B01D53/0462 , B01D53/047 , B01D2253/108 , B01D2253/304 , B01D2257/102 , B01D2257/104 , B01J20/186 , B01J20/28004 , B01J20/28011 , B01J20/28014 , B01J20/28016 , B01J20/2803 , Y10S95/902
摘要: High rate and high crush-strength adsorbent particles and collections of such particles, and particularly LiLSX particles, are provided. A binder is employed in the form of a colloidal solution during the method of manufacture. Suitable binders include various silica binders. The particles are made using the steps of mixing, agglomeration, calcination and in the case of certain adsorbents such as LiX and LiLSX, ion exchange and activation. When the adsorption rate is expressed in the form SCRR/εp (mmol mm2/g s), desirable collections of adsorbent particles can have values of at least 4.0 for the highly-exchanged Li (at least 90% Li exchanged) form of the collection of particles and can further be characterized by particles having average crush strengths of at least 0.9 lbf for particles having an average diameter of at least about 1.0 mm.
摘要翻译: 提供了高速率和高压缩强度的吸附剂颗粒和这种颗粒的集合,特别是LiLSX颗粒。 粘合剂在制造方法中以胶体溶液的形式使用。 合适的粘合剂包括各种二氧化硅粘合剂。 使用混合,附聚,煅烧的步骤,在某些吸附剂如LiX和LiLSX的情况下,进行离子交换和活化来制备颗粒。 当吸附速率以SCRR / e(pmol / mm 2 / gs)的形式表达时,对于高交换Li(至少90%Li交换)形式的吸附剂颗粒的理想集合可以具有至少4.0的值 收集颗粒,并且可以进一步表征为具有平均直径为至少约1.0mm的颗粒的平均抗压强度为至少0.9lbf的颗粒。
-
公开(公告)号:US08969229B2
公开(公告)日:2015-03-03
申请号:US12445685
申请日:2007-10-22
IPC分类号: B01J35/10 , B01J29/06 , B01J29/18 , B01J20/12 , B01J20/30 , B01D53/02 , B01D53/04 , B01D53/047 , B01J20/18 , B01J20/28
CPC分类号: B01J20/305 , B01D53/02 , B01D53/04 , B01D53/047 , B01D2253/108 , B01D2253/30 , B01J20/12 , B01J20/183 , B01J20/186 , B01J20/28019 , B01J20/2803 , B01J20/28085 , B01J20/3042
摘要: The present invention generally relates to high rate adsorbents and a method for their manufacture involving the steps of component mixing, extrusion, spheronization and calcination. The component mixing can involve both dry mixing in addition to wet mixing of an adsorbent with a binder, if required, and a fluid such as water. The paste so formed from the mixing stage is extruded to produce pellets which are optionally converted to beads by spheronization using in one embodiment, a marumerizer. The product is harvested and calcined to set any binder or binders used and/or burn out any additives or processing aids. This basic manufacturing scheme can be augmented by extra processing steps including ion exchange and activation to alter the composition of the adsorbents, as required.
摘要翻译: 本发明一般涉及高速吸附剂及其制造方法,包括组分混合,挤出,滚圆和煅烧的步骤。 除了吸附剂与粘合剂的湿混合之外,如果需要,以及诸如水的流体,组分混合可以包括干混合。 将从混合阶段形成的浆料被挤出以产生颗粒,其通过在一个实施方案中使用丸算机,通过滚圆法任选地转化为珠粒。 收获产品并煅烧以设置所使用的任何粘合剂或粘合剂和/或燃烧任何添加剂或加工助剂。 可以根据需要通过额外的加工步骤来增加该基本制造方案,包括离子交换和活化以改变吸附剂的组成。
-
公开(公告)号:US08123835B2
公开(公告)日:2012-02-28
申请号:US12529198
申请日:2008-03-10
CPC分类号: B01J20/183 , B01D53/0462 , B01D53/047 , B01D2253/108 , B01D2253/304 , B01D2257/102 , B01D2257/104 , B01J20/186 , B01J20/28004 , B01J20/28011 , B01J20/28014 , B01J20/28016 , B01J20/2803 , Y10S95/902
摘要: High rate and high crush-strength adsorbent particles and collections of such particles, and particularly LiLSX particles, are provided. A binder is employed in the form of a colloidal solution during the method of manufacture. Suitable binders include various silica binders. The particles are made using the steps of mixing, agglomeration, calcination and in the case of certain adsorbents such as LiX and LiLSX, ion exchange and activation. When the adsorption rate is expressed in the form SCRR/εp (mmol mm2/g s), desirable collections of adsorbent particles can have values of at least 4.0 for the highly-exchanged Li (at least 90% Li exchanged) form of the collection of particles and can further be characterized by particles having average crush strengths of at least 0.9 lbf for particles having an average diameter of at least about 1.0 mm.
摘要翻译: 提供了高速率和高压缩强度的吸附剂颗粒和这种颗粒的集合,特别是LiLSX颗粒。 粘合剂在制造方法中以胶体溶液的形式使用。 合适的粘合剂包括各种二氧化硅粘合剂。 使用混合,附聚,煅烧的步骤,在某些吸附剂如LiX和LiLSX的情况下,进行离子交换和活化来制备颗粒。 当吸附速率以SCRR / e(pmol / mm 2 / gs)的形式表达时,对于高交换Li(至少90%Li交换)形式的吸附剂颗粒的理想集合可以具有至少4.0的值 收集颗粒,并且可以进一步表征为具有平均直径为至少约1.0mm的颗粒的平均抗压强度为至少0.9lbf的颗粒。
-
公开(公告)号:US20130340615A1
公开(公告)日:2013-12-26
申请号:US13923096
申请日:2013-06-20
申请人: Philip Alexander Barrett , Steven John Pontonio , Persefoni Kechagia , Neil Andrew Stephenson , Kerry C. Weston
发明人: Philip Alexander Barrett , Steven John Pontonio , Persefoni Kechagia , Neil Andrew Stephenson , Kerry C. Weston
IPC分类号: B01J20/26
CPC分类号: B01D53/0476 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/108 , B01D2253/1085 , B01D2253/11 , B01D2257/102 , B01J20/18 , B01J20/183 , B01J20/26 , B01J20/28004 , B01J20/28011 , B01J20/2803 , B01J20/28085
摘要: Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N2 adsorption rates and capacities when used in air separation processes.
-
公开(公告)号:US20140094359A1
公开(公告)日:2014-04-03
申请号:US12445685
申请日:2007-10-22
CPC分类号: B01J20/305 , B01D53/02 , B01D53/04 , B01D53/047 , B01D2253/108 , B01D2253/30 , B01J20/12 , B01J20/183 , B01J20/186 , B01J20/28019 , B01J20/2803 , B01J20/28085 , B01J20/3042
摘要: The present invention generally relates to high rate adsorbents and a method for their manufacture involving the steps of component mixing, extrusion, spheronization and calcination. The component mixing can involve both dry mixing in addition to wet mixing of an adsorbent with a binder, if required, and a fluid such as water. The paste so formed from the mixing stage is extruded to produce pellets which are optionally converted to beads by spheronization using in one embodiment, a marumerizer. The product is harvested and calcined to set any binder or binders used and/or burn out any additives or processing aids. This basic manufacturing scheme can be augmented by extra processing steps including ion exchange and activation to alter the composition of the adsorbents, as required.
摘要翻译: 本发明一般涉及高速吸附剂及其制造方法,包括组分混合,挤出,滚圆和煅烧的步骤。 除了吸附剂与粘合剂的湿混合之外,如果需要,以及诸如水的流体,组分混合可以包括干混合。 将从混合阶段形成的浆料被挤出以产生颗粒,其通过在一个实施方案中使用丸算机,通过滚圆法任选地转化为珠粒。 收获产品并煅烧以设置所使用的任何粘合剂或粘合剂和/或燃烧任何添加剂或加工助剂。 可以根据需要通过额外的加工步骤来增加该基本制造方案,包括离子交换和活化以改变吸附剂的组成。
-
公开(公告)号:US09486732B2
公开(公告)日:2016-11-08
申请号:US14703999
申请日:2015-05-05
申请人: Philip Alexander Barrett , Steven John Pontonio , Persefoni Kechagia , Neil Andrew Stephenson , Kerry C. Weston
发明人: Philip Alexander Barrett , Steven John Pontonio , Persefoni Kechagia , Neil Andrew Stephenson , Kerry C. Weston
IPC分类号: B01J20/02 , B01D53/04 , B01D53/047 , B01J20/28 , B01J20/18
CPC分类号: B01D53/0476 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/108 , B01D2253/1085 , B01D2253/11 , B01D2257/102 , B01J20/18 , B01J20/183 , B01J20/26 , B01J20/28004 , B01J20/28011 , B01J20/2803 , B01J20/28085
摘要: Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N2 adsorption rates and capacities when used in air separation processes.
-
公开(公告)号:US20150231553A1
公开(公告)日:2015-08-20
申请号:US14703999
申请日:2015-05-05
申请人: Philip Alexander Barrett , Steven John Pontonio , Persefoni Kechagia , Neil Andrew Stephenson , Kerry C. Weston
发明人: Philip Alexander Barrett , Steven John Pontonio , Persefoni Kechagia , Neil Andrew Stephenson , Kerry C. Weston
IPC分类号: B01D53/047 , B01D53/04
CPC分类号: B01D53/0476 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/108 , B01D2253/1085 , B01D2253/11 , B01D2257/102 , B01J20/18 , B01J20/183 , B01J20/26 , B01J20/28004 , B01J20/28011 , B01J20/2803 , B01J20/28085
摘要: Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N2 adsorption rates and capacities when used in air separation processes.
摘要翻译: 用于吸附和分离过程的吸附剂组合物使用硅氧烷衍生的粘合剂制备。 吸附剂组合物由与硅氧烷衍生的结合剂和任选的少量粘土粘合剂结合的微晶硅铝酸盐颗粒制成,以形成附聚的微晶颗粒,并煅烧以使与硅氧烷衍生的粘合剂相关的有机组分挥发。 附聚微晶颗粒在低粘合剂浓度下具有优异的孔结构和优异的抗压强度,并且当用于空气分离过程时表现出增强的N 2吸附速率和容量。
-
公开(公告)号:US09050582B2
公开(公告)日:2015-06-09
申请号:US13923096
申请日:2013-06-20
申请人: Philip Alexander Barrett , Steven John Pontonio , Persefoni Kechagia , Neil Andrew Stephenson , Kerry C. Weston
发明人: Philip Alexander Barrett , Steven John Pontonio , Persefoni Kechagia , Neil Andrew Stephenson , Kerry C. Weston
CPC分类号: B01D53/0476 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/108 , B01D2253/1085 , B01D2253/11 , B01D2257/102 , B01J20/18 , B01J20/183 , B01J20/26 , B01J20/28004 , B01J20/28011 , B01J20/2803 , B01J20/28085
摘要: Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N2 adsorption rates and capacities when used in air separation processes.
摘要翻译: 用于吸附和分离过程的吸附剂组合物使用硅氧烷衍生的粘合剂制备。 吸附剂组合物由与硅氧烷衍生的结合剂和任选的少量粘土粘合剂结合的微晶硅铝酸盐颗粒制成,以形成附聚的微晶颗粒,并煅烧以使与硅氧烷衍生的粘合剂相关的有机组分挥发。 附聚微晶颗粒在低粘合剂浓度下具有优异的孔结构和优异的抗压强度,并且当用于空气分离过程时表现出增强的N 2吸附速率和容量。
-
9.
公开(公告)号:US08657924B2
公开(公告)日:2014-02-25
申请号:US13206773
申请日:2011-08-10
CPC分类号: B01J20/183 , B01D53/02 , B01D53/0462 , B01D53/0476 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/1085 , B01D2253/1124 , B01D2253/25 , B01D2257/504 , B01D2257/80 , B01D2259/4145 , B01D2259/416 , B01J20/0225 , B01J20/0229 , B01J20/0255 , B01J20/06 , B01J2220/42 , Y02C10/08
摘要: The present invention relates generally to a composite adsorbent comprising at least a zeolite-containing CO2 removal adsorbent and 10% or more of a metal oxide having a heat capacity of at least 20 cal/mol-° K (83.7 J/(mol·K). The composite is preferably used in a multi-layered adsorption system in a cyclic adsorption process. The adsorption system comprises two or more layers wherein the first layer is at least a water vapor removal adsorbent, such as activated alumina, and the second layer is the novel composite adsorbent. The adsorption system is preferably used in a PSA prepurification process prior to cryogenic air separation.
摘要翻译: 本发明一般涉及至少包含含沸石的CO 2去除吸附剂和10%或更多的具有至少20cal / mol- K(83.7J /(mol·K)的热容的金属氧化物的复合吸附剂 ),该复合材料优选用于循环吸附工艺中的多层吸附体系中,该吸附体系包含两层或多层,其中第一层至少为水蒸汽去除吸附剂,例如活性氧化铝,第二层 是新型复合吸附剂,吸附系统优选用于低温空气分离前的PSA预纯化工艺。
-
10.
公开(公告)号:US20130036904A1
公开(公告)日:2013-02-14
申请号:US13206773
申请日:2011-08-10
IPC分类号: B01D53/04 , B01D53/047
CPC分类号: B01J20/183 , B01D53/02 , B01D53/0462 , B01D53/0476 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/1085 , B01D2253/1124 , B01D2253/25 , B01D2257/504 , B01D2257/80 , B01D2259/4145 , B01D2259/416 , B01J20/0225 , B01J20/0229 , B01J20/0255 , B01J20/06 , B01J2220/42 , Y02C10/08
摘要: The present invention relates generally to a composite adsorbent comprising at least a zeolite-containing CO2 removal adsorbent and 10% or more of a metal oxide having a heat capacity of at least 20 cal/mol-° K (83.7 J/(mol·K). The composite is preferably used in a multi-layered adsorption system in a cyclic adsorption process. The adsorption system comprises two or more layers wherein the first layer is at least a water vapor removal adsorbent, such as activated alumina, and the second layer is the novel composite adsorbent. The adsorption system is preferably used in a PSA prepurification process prior to cryogenic air separation.
摘要翻译: 本发明一般涉及至少包含含沸石的CO 2去除吸附剂和10%或更多的具有至少20cal / mol- K(83.7J /(mol·K)的热容的金属氧化物的复合吸附剂 ),该复合材料优选用于循环吸附工艺中的多层吸附体系中,该吸附体系包含两层或多层,其中第一层至少为水蒸汽去除吸附剂,例如活性氧化铝,第二层 是新型复合吸附剂,吸附系统优选用于低温空气分离前的PSA预纯化工艺。
-
-
-
-
-
-
-
-
-