公开(公告)号：US09452931B2

公开(公告)日：2016-09-27

申请号：US14076321

申请日：2013-11-11

Applicant: PHILLIPS 66 COMPANY

Inventor： Uchenna P. Paul ,  Bruce B. Randolph ,  Jon M. Nelson ,  Kristi A. Fjare ,  Danielle K. Smith ,  Mark Rumel Cragun ,  Richard D. Sadok

IPC: C01B3/32

CPC classification number: C01B3/323 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1211 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1229

Abstract: A process is described for flowing an oxygenate feed over a catalyst in an adiabatic fixed bed reactor to product a reactor effluent and heat. The reaction inside the adiabatic fixed bed reactor occurs at a reaction temperature from about 200° C. to about 375° C. The reactor effluent is then condensed to separate the liquid products and the gaseous products. A separation step then separates the gaseous products into hydrogen and off-gas.

Abstract translation: 描述了一种将含氧化合物进料在绝热固定床反应器中的催化剂上流动以产生反应器流出物和热量的方法。 绝热固定床反应器中的反应在约200℃至约375℃的反应温度下进行。然后将反应器流出物冷凝以分离液体产物和气态产物。 然后分离步骤将气态产物分离成氢气和废气。

公开(公告)号：US20140069010A1

公开(公告)日：2014-03-13

申请号：US14021540

申请日：2013-09-09

Applicant: Phillips 66 Company

Inventor： Mark A. Hughes ,  Tie-Pan Shi ,  Richard D. Sadok ,  Samuel T. Jones ,  Johnathan T. Gorke ,  Natalie A. Rebacz ,  Liang Zhang ,  Martin L. Perkins

IPC: C10K3/02

CPC classification number: C10K3/02 ,  C10B7/10 ,  C10B49/16 ,  C10B53/02 ,  C10G2/32 ,  C10G3/42 ,  C10G2300/1011 ,  Y02E50/14 ,  Y02E50/32 ,  Y02P20/145 ,  Y02P30/20

Abstract: The present disclosure relates generally to novel biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants with the pyrolysis vapors. In certain embodiments, the present disclosure provides methods and systems to prevent entrainment of particles of char and heat carrier with pyrolysis vapors leaving a reactor, while allowing rapid upgrading of the vapors by catalyst(s) that are held in a an upgrading reactor and protected from contact with the char.

Abstract translation: 本公开一般涉及新的生物质热解方法和系统，其减少焦化和其它污染物与热解蒸气的夹带。 在某些实施方案中，本公开提供了防止夹带具有离开反应器的热解蒸气的炭和热载体颗粒的方法和系统，同时允许通过保持在升级反应器中的催化剂快速升级蒸气并保护 从与char的接触。

公开(公告)号：US20140134099A1

公开(公告)日：2014-05-15

申请号：US14076321

申请日：2013-11-11

Applicant: Phillips 66 Company

Inventor： Uchenna P. Paul ,  Bruce B. Randolph ,  Jon M. Nelson ,  Kristi A. Fjare ,  Danielle K. Smith ,  Mark Rumel Cragun ,  Richard D. Sadok

IPC: C01B3/32

CPC classification number: C01B3/323 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1211 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1229

Abstract: A process is described for flowing an oxygenate feed over a catalyst in an adiabatic fixed bed reactor to product a reactor effluent and heat. The reaction inside the adiabatic fixed bed reactor occurs at a reaction temperature from about 200° C. to about 375° C. The reactor effluent is then condensed to separate the liquid products and the gaseous products. A separation step then separates the gaseous products into hydrogen and off-gas.

Abstract translation: 描述了一种将含氧化合物进料在绝热固定床反应器中的催化剂上流动以产生反应器流出物和热量的方法。 绝热固定床反应器中的反应在约200℃至约375℃的反应温度下进行。然后将反应器流出物冷凝以分离液体产物和气态产物。 然后分离步骤将气态产物分离成氢气和废气。