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公开(公告)号：US20170067169A1
公开(公告)日：2017-03-09
申请号：US15243281
申请日：2016-08-22
Applicant: PHILLIPS 66 COMPANY
Inventor： David B. Ingram , Bruce B. Randolph , Mitchell E. Loescher , Aalo K. Gupta , Uchenna P. Paul , Chris J. LaFrancois , Neal D. McDaniel , Danielle K. Smith , David M. Bierschenk , Ting He
CPC classification number: C25B3/02 , C25B9/08 , C25B11/0478 , C25B13/04 , C25B15/08
Abstract: The current embodiment describes a process of flowing an oxidant species over the reducing side of an oxygen transport membrane. O2− anions are then continuously transported from the reducing side through the oxygen transport membrane to the oxidizing side where an organic compound is converted to a partially oxidized organic compound on the oxidizing side.
Abstract translation: 目前的实施方案描述了使氧化剂物质在氧传输膜的还原侧上流动的过程。 然后，将阴离子从还原侧通过氧传输膜连续输送到氧化侧，在氧化侧将有机化合物转化为氧化侧的部分氧化的有机化合物。
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公开(公告)号：US20140110271A1
公开(公告)日：2014-04-24
申请号：US14047084
申请日：2013-10-07
Applicant: PHILLIPS 66 COMPANY
Inventor： Mahaprasad Kar , Sourabh Pansare , John T. Gorke , Edgar Lotero , Neal D. McDaniel , Danielle K. Smith , Dennis G. Schultz , Kristi A. Fjare , Bruce B. Randolph , Sikta Patnaik , Uchenna P. Paul , Madhu Anand
CPC classification number: C25B11/0415 , C25B1/02 , C25B11/0473
Abstract: The process describes performing electrolysis on an alkaline oxygenate mixture to produce hydrogen. In this process the electrolysis does not form any significant amounts of oxygen.
Abstract translation: 该方法描述了在碱性含氧化合物混合物上进行电解以产生氢。 在这个过程中，电解不会形成任何显着量的氧气。
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Patent Agency Ranking
3.发明授权Process scheme for catalytic production of renewable hydrogen from oxygenate feedstocks 有权从含氧化合物原料催化生产可再生氢的工艺方案公开(公告)号：US09452931B2
公开(公告)日：2016-09-27
申请号：US14076321
申请日：2013-11-11
Applicant: PHILLIPS 66 COMPANY
Inventor： Uchenna P. Paul , Bruce B. Randolph , Jon M. Nelson , Kristi A. Fjare , Danielle K. Smith , Mark Rumel Cragun , Richard D. Sadok
IPC: C01B3/32
CPC classification number: C01B3/323 , C01B2203/0233 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/1041 , C01B2203/1058 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1211 , C01B2203/1217 , C01B2203/1223 , C01B2203/1229
Abstract: A process is described for flowing an oxygenate feed over a catalyst in an adiabatic fixed bed reactor to product a reactor effluent and heat. The reaction inside the adiabatic fixed bed reactor occurs at a reaction temperature from about 200° C. to about 375° C. The reactor effluent is then condensed to separate the liquid products and the gaseous products. A separation step then separates the gaseous products into hydrogen and off-gas.
Abstract translation: 描述了一种将含氧化合物进料在绝热固定床反应器中的催化剂上流动以产生反应器流出物和热量的方法。 绝热固定床反应器中的反应在约200℃至约375℃的反应温度下进行。然后将反应器流出物冷凝以分离液体产物和气态产物。 然后分离步骤将气态产物分离成氢气和废气。
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公开(公告)号：US09302250B2
公开(公告)日：2016-04-05
申请号：US14071077
申请日：2013-11-04
Applicant: PHILLIPS 66 COMPANY
Inventor： Jimmy A. Faria , Jon M. Nelson , Uchenna P. Paul , Danielle K. Smith
CPC classification number: B01J23/8946 , B01J21/04 , B01J23/755 , B01J23/78 , B01J23/892 , B01J23/894 , B01J35/1019 , B01J35/1061 , C01B3/326 , C01B2203/0283 , C01B2203/043 , Y02P20/145 , Y02P20/52
Abstract: A method of steam reforming where a reaction occurs in which an oxygenated feed contacts a catalyst to produce hydrogen. The catalyst of the reaction comprises a metal/metal promoter on a nickel/transition metal blend catalyst supported on a high-energy lattice metal oxide.
Abstract translation: 发生反应的蒸汽重整方法，其中含氧进料与催化剂接触以产生氢气。 反应的催化剂包含负载在高能晶格金属氧化物上的镍/过渡金属共混物催化剂上的金属/金属助催化剂。
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公开(公告)号：US20140134098A1
公开(公告)日：2014-05-15
申请号：US14071077
申请日：2013-11-04
Applicant: Phillips 66 Company
Inventor： Jimmy A. Faria , Jon M. Nelson , Uchenna P. Paul , Danielle K. Smith
CPC classification number: B01J23/8946 , B01J21/04 , B01J23/755 , B01J23/78 , B01J23/892 , B01J23/894 , B01J35/1019 , B01J35/1061 , C01B3/326 , C01B2203/0283 , C01B2203/043 , Y02P20/145 , Y02P20/52
Abstract: A method of steam reforming where a reaction occurs in which an oxygenated feed contacts a catalyst to produce hydrogen. The catalyst of the reaction comprises a metal/metal promoter on a nickel/transition metal blend catalyst supported on a high-energy lattice metal oxide.
Abstract translation: 发生反应的蒸汽重整方法，其中含氧进料与催化剂接触以产生氢气。 反应的催化剂包含负载在高能晶格金属氧化物上的镍/过渡金属共混物催化剂上的金属/金属助催化剂。
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公开(公告)号：US20140224663A1
公开(公告)日：2014-08-14
申请号：US14173929
申请日：2014-02-06
Applicant: PHILLIPS 66 COMPANY
Inventor： Mahaprasad Kar , Neal D. McDaniel , Danielle K. Smith , Dennis G. Schultz , Bruce B. Randolph
IPC: C25D21/18
CPC classification number: C25D21/02 , C25B11/0442 , C25D3/02 , C25D3/12 , C25D3/20 , C25D3/42 , C25D3/48 , C25D3/50 , C25D3/56 , C25D3/562 , C25D3/567 , C25D3/62 , C25D5/003 , C25D5/18
Abstract: The method begins by forming a solution comprising catalyst precursors, electrolyte and a solvent. Electrodes are inserted into the solution comprising an anode electrode and a cathode electrode. Electrochemical deposition then occurs wherein a current is passed between the electrodes. In this method at least one additional step of: i) heating the solution prior to and during the electrochemical deposition; ii) increasing the concentration of the catalyst precursors in the solution to greater than 0.1 millimolar; iii) performing the electrochemical deposition by a pulsed current; and iv) adding chemical promoters to the solution.
Abstract translation: 该方法开始于形成包含催化剂前体，电解质和溶剂的溶液。 将电极插入包括阳极电极和阴极电极的溶液中。 然后发生电化学沉积，其中电流在电极之间通过。 在该方法中，至少一个附加步骤：i）在电化学沉积之前和期间加热溶液; ii）将溶液中的催化剂前体的浓度增加至大于0.1毫摩尔; iii）通过脉冲电流进行电化学沉积; 和iv）向溶液中加入化学促进剂。
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7.发明申请公开(公告)号：US20140134099A1
公开(公告)日：2014-05-15
申请号：US14076321
申请日：2013-11-11
Applicant: Phillips 66 Company
Inventor： Uchenna P. Paul , Bruce B. Randolph , Jon M. Nelson , Kristi A. Fjare , Danielle K. Smith , Mark Rumel Cragun , Richard D. Sadok
IPC: C01B3/32
CPC classification number: C01B3/323 , C01B2203/0233 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/1041 , C01B2203/1058 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1211 , C01B2203/1217 , C01B2203/1223 , C01B2203/1229
Abstract: A process is described for flowing an oxygenate feed over a catalyst in an adiabatic fixed bed reactor to product a reactor effluent and heat. The reaction inside the adiabatic fixed bed reactor occurs at a reaction temperature from about 200° C. to about 375° C. The reactor effluent is then condensed to separate the liquid products and the gaseous products. A separation step then separates the gaseous products into hydrogen and off-gas.
Abstract translation: 描述了一种将含氧化合物进料在绝热固定床反应器中的催化剂上流动以产生反应器流出物和热量的方法。 绝热固定床反应器中的反应在约200℃至约375℃的反应温度下进行。然后将反应器流出物冷凝以分离液体产物和气态产物。 然后分离步骤将气态产物分离成氢气和废气。
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