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1.
公开(公告)号:US20140069799A1
公开(公告)日:2014-03-13
申请号:US14023040
申请日:2013-09-10
Applicant: Phillips 66 Company
Inventor: Johnathan T. Gorke , Samuel T. Jones , Mark A. Hughes , J. Scott McQueen , Cory B. Phillips
IPC: C10B43/14
CPC classification number: C10J3/46 , C10B43/14 , C10B49/16 , C10B53/02 , C10B53/08 , C10B57/06 , C10G1/08 , C10G2/32 , C10G2300/1011 , C10L3/08 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: The present disclosure relates generally to novel biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants with the produced pyrolysis vapors.
Abstract translation: 本公开一般涉及新的生物质热解方法和系统,其减少所产生的热解蒸气中的焦炭和其它污染物的夹带。
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公开(公告)号:US20130327627A1
公开(公告)日:2013-12-12
申请号:US13914338
申请日:2013-06-10
Applicant: Phillips 66 Company
Inventor: Daren E. Daugaard , Samuel T. Jones , Alexandru Platon , Kening Gong , Edgar Lotero
IPC: C10G3/00
CPC classification number: C10G3/42 , C10B7/10 , C10B49/16 , C10B49/20 , C10B53/02 , C10B57/06 , C10G1/08 , Y02E50/14 , Y02P20/145 , Y02P30/20
Abstract: The present invention relates generally to the thermal conversion of biomass. Processes are disclosed for converting biomass to condensable vapor intermediates such as pyrolysis oil by means of catalytic pyrolysis in a reactor comprising at least one auger, where the catalyst also comprises a heat carrier. The intermediates produced may be further processed for production of renewable hydrocarbon fuels.
Abstract translation: 本发明一般涉及生物质的热转化。 公开了用于在包括至少一个螺旋钻的反应器中通过催化裂解将生物质转化为可冷凝蒸气中间体(例如热解油)的方法,其中催化剂还包含热载体。 生产的中间体可进一步加工以生产可再生碳氢燃料。
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公开(公告)号:US09908092B2
公开(公告)日:2018-03-06
申请号:US15436029
申请日:2017-02-17
Applicant: PHILLIPS 66 COMPANY
Inventor: Dustin L. Dalluge , Steven E. Lusk , Samuel T. Jones , Johnathan T. Gorke
CPC classification number: B01J8/10 , B01J8/0045 , B01J8/005 , B01J8/082 , B01J8/087 , C10B49/16 , C10B53/02 , C10C5/00 , Y02E50/14 , Y02P20/145
Abstract: The present disclosure relates generally to two-stage biomass pyrolysis systems configured to maximize pyrolysis vapor yield from a lignocellulosic biomass while being conducive to commercial-scale throughput of lignocellulosic biomass. The system includes a reactor first stage comprising at least one auger pyrolyzes a lignocellulosic feedstock at a temperature and residence time that produces pyrolysis vapors derived predominantly from cellulose and hemi-cellulose fractions of the feedstock. A reactor second stage is configured to partially-pyrolyzed feedstock from the reactor first stage at a higher temperature for an additional residence time to produce additional pyrolysis vapors that are predominantly derived from of lignin. Certain embodiments arrange multiple reactor first stages around a single reactor second stage.
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公开(公告)号:US20140073823A1
公开(公告)日:2014-03-13
申请号:US14021021
申请日:2013-09-09
Applicant: Phillips 66 Company
Inventor: Mark A. Hughes , Johnathan T. Gorke , Samuel T. Jones , Tie-Pan Shi , Natalie A. Rebacz , Edgar Lotero
IPC: C10G1/00
CPC classification number: C10J3/52 , C10B49/16 , C10B53/02 , C10G1/002 , C10G1/02 , C10G2/32 , C10G3/42 , C10G3/55 , C10G2300/1011 , C10K1/30 , C10K3/02 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: The present disclosure relates generally to novel biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants with the pyrolysis vapors.
Abstract translation: 本公开一般涉及新的生物质热解方法和系统,其减少焦化和其它污染物与热解蒸气的夹带。
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公开(公告)号:US20140073824A1
公开(公告)日:2014-03-13
申请号:US14023091
申请日:2013-09-10
Applicant: PHILLIPS 66 COMPANY
Inventor: Samuel T. Jones , Jonathan T. Gorke , Mark A. Hughes
IPC: C10G1/00
CPC classification number: C10J3/52 , C10B49/16 , C10B53/02 , C10G1/002 , C10G1/02 , C10G2/32 , C10G3/42 , C10G3/55 , C10G2300/1011 , C10K1/30 , C10K3/02 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: The present disclosure pertains to biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants in the pyrolysis vapors by filtering the vapors in a heated container comprising a moving bed granular filter (MBGF), which in turn, comprises granular heat carrier. The granular heat carrier is heated within the MBGF and fed directly to the pyrolysis reactor, optionally along with filtered solids such as char. In certain embodiments, the MBGF additionally comprises at least one upgrading catalyst that contacts the vapors to produce a hydrocarbon mixture fungible with a petroleum-derived transportation fuel, a hydrocarbon transportation fuel component, or mixtures thereof.
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6.
公开(公告)号:US20140072480A1
公开(公告)日:2014-03-13
申请号:US14023123
申请日:2013-09-10
Applicant: PHILLIPS 66 COMPANY
Inventor: Samuel T. Jones , Jonathan T. Gorke , Mark A. Hughes
IPC: C10J3/52
CPC classification number: C10J3/52 , C10B49/16 , C10B53/02 , C10G1/002 , C10G1/02 , C10G2/32 , C10G3/42 , C10G3/55 , C10G2300/1011 , C10K1/30 , C10K3/02 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: The present disclosure pertains to biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants in the pyrolysis vapors by filtering the vapors in a heated container comprising a moving bed granular filter (MBGF), which in turn, comprises granular heat carrier. The granular heat carrier is heated within the MBGF and fed directly to the pyrolysis reactor, optionally along with filtered solids such as char. In certain embodiments, the MBGF additionally comprises at least one upgrading catalyst that contacts the vapors to produce a hydrocarbon mixture fungible with a petroleum-derived transportation fuel, a hydrocarbon transportation fuel component, or mixtures thereof.
Abstract translation: 本公开涉及生物质热解方法和系统,其通过在包括移动床颗粒过滤器(MBGF)的加热容器中过滤蒸气来减少热分解蒸汽中的炭和其它污染物的夹带,所述移动床颗粒过滤器(MBGF)又包括颗粒状热载体。 颗粒状热载体在MBGF内被加热,并直接进入热解反应器,任选地与过滤的固体如炭一起进料。 在某些实施方案中,MBGF还包含至少一种与蒸气接触以产生可与石油衍生的运输燃料,烃运输燃料组分或其混合物可替代的烃混合物的升级催化剂。
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公开(公告)号:US20140069010A1
公开(公告)日:2014-03-13
申请号:US14021540
申请日:2013-09-09
Applicant: Phillips 66 Company
Inventor: Mark A. Hughes , Tie-Pan Shi , Richard D. Sadok , Samuel T. Jones , Johnathan T. Gorke , Natalie A. Rebacz , Liang Zhang , Martin L. Perkins
IPC: C10K3/02
CPC classification number: C10K3/02 , C10B7/10 , C10B49/16 , C10B53/02 , C10G2/32 , C10G3/42 , C10G2300/1011 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: The present disclosure relates generally to novel biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants with the pyrolysis vapors. In certain embodiments, the present disclosure provides methods and systems to prevent entrainment of particles of char and heat carrier with pyrolysis vapors leaving a reactor, while allowing rapid upgrading of the vapors by catalyst(s) that are held in a an upgrading reactor and protected from contact with the char.
Abstract translation: 本公开一般涉及新的生物质热解方法和系统,其减少焦化和其它污染物与热解蒸气的夹带。 在某些实施方案中,本公开提供了防止夹带具有离开反应器的热解蒸气的炭和热载体颗粒的方法和系统,同时允许通过保持在升级反应器中的催化剂快速升级蒸气并保护 从与char的接触。
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公开(公告)号:US10174258B2
公开(公告)日:2019-01-08
申请号:US15435990
申请日:2017-02-17
Applicant: PHILLIPS 66 COMPANY
Inventor: Dustin L. Dalluge , Steven E. Lusk , Samuel T. Jones , Johnathan T. Gorke
Abstract: The present disclosure relates generally to a two-stage biomass pyrolysis processes that maximize pyrolysis vapor yield from a lignocellulosic biomass while being conducive to commercial-scale throughput of biomass. A lignocellulosic feedstock is first pyrolyzed in a reactor first stage comprising at least one auger at a temperature and residence time that produces pyrolysis vapors derived predominantly from cellulose and hemi-cellulose fractions of the feedstock. Partially-pyrolyzed feedstock from the reactor first stage is then pyrolyzed in a reactor second stage at a higher temperature for an additional residence time to produce additional pyrolysis vapors that are predominantly derived from lignin. Certain embodiments arrange multiple reactor first stages around a single reactor second stage.
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9.
公开(公告)号:US20140069012A1
公开(公告)日:2014-03-13
申请号:US14023020
申请日:2013-09-10
Applicant: Phillips 66 Company
Inventor: Johnathan T. Gorke , Samuel T. Jones , Mark A. Hughes , J. Scott McQueen , Cory B. Phillips
IPC: C10J3/46
CPC classification number: C10J3/46 , C10B43/14 , C10B49/16 , C10B53/02 , C10B53/08 , C10B57/06 , C10G1/08 , C10G2/32 , C10G2300/1011 , C10L3/08 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: The present disclosure relates generally to novel biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants with the produced pyrolysis vapors.
Abstract translation: 本公开一般涉及新的生物质热解方法和系统,其减少所产生的热解蒸气中的焦炭和其它污染物的夹带。
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10.
公开(公告)号:US20130327626A1
公开(公告)日:2013-12-12
申请号:US13914146
申请日:2013-06-10
Applicant: Phillips 66 Company
Inventor: Daren E. Daugaard , Samuel T. Jones , Alexandru Platon , Kening Gong , Edgar Lotero
IPC: C10G1/02
Abstract: The present invention relates generally to the thermal conversion of biomass. Processes are disclosed for converting algal biomass to condensable vapor intermediates such as pyrolysis oil by means of pyrolysis in a reactor comprising at least one auger. The intermediates may be further processed for production of renewable hydrocarbon fuels. The disclosed processes assist in preventing premature devolatization of algal biomass during pyrolysis, thereby increasing efficiency and commercial feasibility.
Abstract translation: 本发明一般涉及生物质的热转化。 公开了用于在包括至少一个螺旋钻的反应器中通过热解将藻类生物质转化成可冷凝蒸汽中间体(例如热解油)的方法。 可以进一步处理中间体以生产可再生烃燃料。 所公开的方法有助于防止藻类生物质在热解期间的过早脱挥发,从而提高效率和商业可行性。
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