摘要:
The invention relates to fuel cell systems and associated methods of operation where an electrochemical cell such as a fuel cell is used as an electrochemical hydrogen separator to separate hydrogen from a process stream (e.g., reformate or synthesis gas), or as an electrochemical hydrogen expander to inject hydrogen into a process stream. In one aspect, the invention provides a method of operating a fuel cell system, including the following steps: flowing hydrogen from a hydrogen supply conduit through a fuel cell to provide an electric current to a load coupled to the fuel cell; actuating an electrochemical hydrogen separator in a first mode of operation of the system to transfer hydrogen from the hydrogen supply conduit to a hydrogen storage vessel; and actuating an electrochemical hydrogen expander in a second mode of operation of the system to transfer hydrogen from the hydrogen storage vessel to the fuel cell.
摘要:
The invention provides a fuel cell system, including a fuel cell having an anode chamber and a cathode chamber, wherein the anode chamber is in fluid communication with a hydrogen reservoir, and wherein the cathode chamber has an inlet and an outlet. The cathode chamber comprises non-intersecting flow channels, and the non-intersecting flow channels provide fluid communication between the cathode inlet and outlet. The fuel cell has a first connection to an electrical load, wherein the first connection comprises a first diode adapted to prevent current flow to the fuel cell. A blower is in fluid communication with the cathode inlet. The blower has an electronic connection to a controller, and the blower is adapted to vary a flow of oxygen through the cathode chamber according to a control signal received from the controller. The system includes a battery having a second connection to the electrical load, the second connection being in parallel with the first connection of the fuel cell to the load, and the second connection comprising a second diode adapted to prevent current flow to the battery. The controller maintains the flow of oxygen such that an output power capacity of the fuel cell is limited by the amount of oxygen flowed through the fuel cell.
摘要:
The invention provides an anode gas diffusion layer for a fuel cell and methods for preparation and use thereof. In particular, a hydrophilic anode gas diffusion layer promotes water transfer through the fuel cell. As an example, in one aspect, the invention provides a fuel cell system, including a fuel cell with an anode gas diffusion layer. The anode gas diffusion layer has a contact angle with water less than 140null (e.g., in some cases less than 120null or less than 100null). In another aspect, the invention provides a gas diffusion layer for a hydrogen electrode of a PEM fuel cell that includes a carbon fiber media having a water contact angle of less than 140null.
摘要:
The invention relates to fuel cell systems and associated methods of operation where an electrochemical cell such as a fuel cell is used as an electrochemical hydrogen separator to separate hydrogen from a process stream (e.g., reformate or synthesis gas), or as an electrochemical hydrogen expander to inject hydrogen into a process stream. In one aspect, the invention provides a method of operating a fuel cell system, including the following steps: flowing hydrogen from a hydrogen supply conduit through a fuel cell to provide an electric current to a load coupled to the fuel cell; actuating an electrochemical hydrogen separator in a first mode of operation of the system to transfer hydrogen from the hydrogen supply conduit to a hydrogen storage vessel; and actuating an electrochemical hydrogen expander in a second mode of operation of the system to transfer hydrogen from the hydrogen storage vessel to the fuel cell.