公开(公告)号：US20170197930A1

公开(公告)日：2017-07-13

申请号：US15404996

申请日：2017-01-12

Applicant: Rennovia Inc. ,  Stora Enso Oyj

Inventor： Valery Sokolovskii ,  Vincent J. Murphy ,  Thomas R. Boussie ,  Gary M. Diamond ,  Eric L. Dias ,  Guang Zhu ,  James M. Longmire ,  Stanley Herrmann ,  Staffan Torssell ,  Mayya Lavrenko

IPC: C07D307/68 ,  B01J8/02

CPC classification number: C07D307/68 ,  B01J8/02 ,  B01J2208/00893 ,  Y02P20/582

Abstract: The present disclosure provides processes for the production of 2-5-furandicarboxylic acid (FDCA) and intermediates thereof by the chemocatalytic conversion of a furanic oxidation substrate. The present disclosure further provides processes for preparing derivatives of FDCA and FDCA-based polymers. In addition, the present disclosure provides crystalline preparations of FDCA, as well as processes for making the same.

公开(公告)号：US20170015642A1

公开(公告)日：2017-01-19

申请号：US15132178

申请日：2016-04-18

Applicant: RENNOVIA, INC.

Inventor： Valery Sokolovskii ,  Eric L. Dias ,  Hong X. Jiang ,  James M. Longmire ,  Vincent J. Murphy ,  Christopher Paul Dunckley ,  Gary M. Diamond ,  Thomas R. Boussie ,  James A.W. Shoemaker ,  Liza Lopez Soto

IPC: C07D307/46 ,  B01D61/14 ,  C07D307/42

CPC classification number: C07D307/46 ,  B01D61/027 ,  B01D61/145 ,  B01D61/362 ,  B01D61/58 ,  B01D2311/04 ,  B01D2311/06 ,  B01D2311/2623 ,  B01D2311/2626 ,  B01D2311/263 ,  B01D2311/2649 ,  B01D2311/2669 ,  C07D307/42 ,  C07D307/50

Abstract: The present invention relates generally to processes for converting fructose-containing feedstocks to a product comprising 5-(hydroxymethyl)furfural (HMF) and water in the presence of water, solvent and an acid catalyst. In some embodiments, the conversion of fructose to HMF is controlled at a partial conversion endpoint characterized by a yield of HMF from fructose that does not exceed about 80 mol %. In these and other embodiments, the processes provide separation techniques for separating and recovering the product, unconverted fructose, solvent and acid catalyst to enable the effective recovery and reutilization of reaction components.

Abstract translation: 本发明一般涉及在水，溶剂和酸催化剂存在下将含果糖的原料转化成包含5-（羟甲基）糠醛（HMF）和水的产物的方法。 在一些实施方案中，将果糖转化成HMF是在部分转化终点处控制的，其特征在于果糖的HMF的产率不超过约80mol％。 在这些和其它实施方案中，该方法提供了用于分离和回收产物，未转化的果糖，溶剂和酸催化剂的分离技术，以使得能够有效地回收和再利用反应组分。