公开(公告)号：US20140369850A1

公开(公告)日：2014-12-18

申请号：US13920341

申请日：2013-06-18

Applicant: ROHM AND HAAS COMPANY ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： Paul J. Popa ,  Ben W. Schaefer ,  John N. Argyropoulos ,  Kenneth E. Wohltmann ,  Sandra Hofmann ,  Daniel Haile ,  Paul Foley ,  YanXiang Li

IPC: C09D133/08 ,  F03D1/06 ,  B64C27/46 ,  F01D5/28

CPC classification number: B64C27/46 ,  C08G12/46 ,  C08K5/07 ,  C09D133/10 ,  C09D161/20 ,  F01D5/288 ,  F05B2280/6011 ,  F05D2300/43 ,  Y02E10/721 ,  Y02T50/672 ,  C09D133/14 ,  C08F2220/1825 ,  C08F220/20 ,  C08F2220/1858 ,  C08F220/14 ,  C08F2220/1875 ,  C08F220/06

Abstract: The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25° C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70° C.

Abstract translation: 本发明提供了可交联的涂料组合物，其制备方法和用其涂布的基材。 可交联涂料组合物包含：（a）多醛，或其缩醛或半缩醛; （b）pKa小于6的酸催化剂; （c）液体介质; （d）包含至少平均2.0个氨基甲酸酯官能团的丙烯酸聚氨酯，其中所述聚氨酯具有小于25℃的玻璃化转变温度（Tg）。 和（e）一种或多种pH值在等于或小于9的范围内的一种或多种填料和/或一种或多种pH值在等于或小于9的范围内的颜料，和/或一种或多种添加剂具有 pH在等于或小于9的范围内，其中所述组合物的固化温度在小于70℃的范围内。

公开(公告)号：US20130172472A1

公开(公告)日：2013-07-04

申请号：US13728037

申请日：2012-12-27

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Eric Greyson ,  John N. Argyropouls ,  Paul Foley ,  Andrew Swartz ,  Nahrain E. Kamber ,  Caroline Slone ,  Manesh N. Sekharan

IPC: C08L75/14 ,  C08L61/02

CPC classification number: C09D133/14 ,  C08L61/02 ,  C08L75/14 ,  C09D175/04

Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.

Abstract translation: 本发明提供了一种可交联水性组合物，其制备方法，交联组合物及其制备方法。 所述可交联组合物包含：水分散体，其包含： （一杯水; （b）包含至少平均2.0个氨基甲酸酯官能团的聚氨酯; （c）包含至少两个醛基的多醛; （d）酸催化剂; 和（e）任选的一种或多种表面活性剂; 其中所述水性分散体的pH值在小于7的范围内; 并且其中所述组合物能够在基本除去水后在低于80℃的温度范围内交联。

公开(公告)号：US09695335B2

公开(公告)日：2017-07-04

申请号：US14734205

申请日：2015-06-09

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： John N. Argyropoulos ,  Paul Foley ,  Eric Greyson ,  Jeff R. Anderson ,  Gary E. Spilman ,  Caroline Slone ,  Nahrain E. Kamber

IPC: C08G63/91 ,  C09D135/02 ,  C09D167/08 ,  C08F22/10 ,  C08G63/12 ,  C09J133/06

CPC classification number: C09D167/08 ,  C08F22/10 ,  C08G63/12 ,  C08G63/914 ,  C08L2312/00 ,  C09D135/02 ,  C09J133/066

Abstract: The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.

公开(公告)号：US09079987B2

公开(公告)日：2015-07-14

申请号：US14512650

申请日：2014-10-13

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： John N. Argyropoulos ,  Paul Foley ,  Eric Greyson ,  Jeff R. Anderson ,  Gary E. Spilman ,  Caroline Slone ,  Nahrain E. Kamber

IPC: C08G12/02 ,  C08G14/00 ,  C08F283/02 ,  C08G63/12 ,  C09J133/06 ,  C08F22/10 ,  C08G63/91 ,  C09D135/02 ,  C09D167/08

CPC classification number: C09D167/08 ,  C08F22/10 ,  C08G63/12 ,  C08G63/914 ,  C08L2312/00 ,  C09D135/02 ,  C09J133/066

Abstract: The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.

Abstract translation: 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; （c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。

公开(公告)号：US20140221554A1

公开(公告)日：2014-08-07

申请号：US14252117

申请日：2014-04-14

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Eric Greyson ,  John N. Argyropoulos ,  Paul Foley ,  Andrew Swartz ,  Nahrain E. Kamber ,  Caroline Slone ,  Manesh N. Sekharan

IPC: C09D133/14

CPC classification number: C09D133/14 ,  C08L61/02 ,  C08L75/14 ,  C09D175/04

Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.

Abstract translation: 本发明提供了一种可交联水性组合物，其制备方法，交联组合物及其制备方法。 所述可交联组合物包含：水分散体，其包含： （一杯水; （b）包含至少平均2.0个氨基甲酸酯官能团的聚氨酯; （c）包含至少两个醛基的多醛; （d）酸催化剂; 和（e）任选的一种或多种表面活性剂; 其中所述水性分散体的pH在小于7的范围内; 并且其中所述组合物能够在基本上除去水后在低于80℃的温度范围内交联。

公开(公告)号：US20130165581A1

公开(公告)日：2013-06-27

申请号：US13727963

申请日：2012-12-27

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： John N. Argyropoulos ,  Paul Foley ,  Eric Greyson ,  Jeff R. Anderson ,  Gary E. Spilman ,  Caroline Slone ,  Nahrian E. Kamber

IPC: C08F22/10 ,  C08G63/12

CPC classification number: C09D167/08 ,  C08F22/10 ,  C08G63/12 ,  C08G63/914 ,  C08L2312/00 ,  C09D135/02 ,  C09J133/066

Abstract: The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.

Abstract translation: 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; 和（c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。

公开(公告)号：US08889818B2

公开(公告)日：2014-11-18

申请号：US13727963

申请日：2012-12-27

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： John N. Argyropoulos ,  Paul Foley ,  Eric Greyson ,  Jeff R. Anderson ,  Gary E. Spilman ,  Caroline Slone ,  Nahrain E. Kamber

IPC: C08G12/02 ,  C08G14/00 ,  C08F283/02 ,  C08G63/12 ,  C09J133/06 ,  C08F22/10

CPC classification number: C09D167/08 ,  C08F22/10 ,  C08G63/12 ,  C08G63/914 ,  C08L2312/00 ,  C09D135/02 ,  C09J133/066

Abstract: The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.

Abstract translation: 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; 和（c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。

公开(公告)号：US10144846B2

公开(公告)日：2018-12-04

申请号：US14899659

申请日：2014-06-05

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Paul J. Popa ,  Ben W. Schaefer ,  John N. Argyropoulos ,  Kenneth E. Wohltmann ,  Sandra Hofmann ,  Daniel Haile ,  Yanxiang Li ,  Paul Foley

IPC: C09D175/14 ,  C08K3/22 ,  C08K3/34 ,  C08K3/36 ,  C08G12/46 ,  C09D133/10 ,  C09D161/20 ,  F01D5/28

Abstract: The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25° C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70° C.

公开(公告)号：US09604721B2

公开(公告)日：2017-03-28

申请号：US13920341

申请日：2013-06-18

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Paul J. Popa ,  Ben W. Schaefer ,  John N. Argyropoulos ,  Kenneth Everett Wohltmann ,  Sandra Hofmann ,  Daniel Haile ,  Yanxiang Li ,  Paul Foley

IPC: B64C27/46 ,  F01D5/28 ,  C08G12/46 ,  C09D161/20 ,  C08K5/07 ,  C09D133/10

CPC classification number: B64C27/46 ,  C08G12/46 ,  C08K5/07 ,  C09D133/10 ,  C09D161/20 ,  F01D5/288 ,  F05B2280/6011 ,  F05D2300/43 ,  Y02E10/721 ,  Y02T50/672 ,  C09D133/14 ,  C08F2220/1825 ,  C08F220/20 ,  C08F2220/1858 ,  C08F220/14 ,  C08F2220/1875 ,  C08F220/06

Abstract: The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25° C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70° C.

公开(公告)号：US09115292B2

公开(公告)日：2015-08-25

申请号：US14252117

申请日：2014-04-14

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Eric Greyson ,  John N. Argyropoulos ,  Paul Foley ,  Andrew Swartz ,  Nahrain E. Kamber ,  Caroline Slone ,  Manesh N. Sekharan

IPC: C08G63/91 ,  C09D135/02 ,  C09D167/08 ,  C08F22/10 ,  C08G63/12 ,  C09D133/14 ,  C08L75/14 ,  C08L61/02 ,  C09D175/04

CPC classification number: C09D133/14 ,  C08L61/02 ,  C08L75/14 ,  C09D175/04

Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.

Abstract translation: 本发明提供了一种可交联水性组合物，其制备方法，交联组合物及其制备方法。 所述可交联组合物包含：水分散体，其包含： （一杯水; （b）包含至少平均2.0个氨基甲酸酯官能团的聚氨酯; （c）包含至少两个醛基的多醛; （d）酸催化剂; 和（e）任选的一种或多种表面活性剂; 其中所述水性分散体的pH在小于7的范围内; 并且其中所述组合物能够在基本上除去水后在低于80℃的温度范围内交联。