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1.发明申请公开(公告)号：US20180371259A1
公开(公告)日：2018-12-27
申请号：US16116602
申请日：2018-08-29
CPC分类号： C09D5/002 , C08G2150/90 , C08K3/36 , C09D5/08 , C09D5/082 , C09D7/61 , C09D7/63 , C09D17/004 , C09D175/04 , C09D175/06
摘要： The present invention provides substantially isocyanate-free multicomponent compositions useful in making rapid dry primer compositions and coatings, the compositions comprising one or more carboxylic acid compounds that contain one of a benzothiazole, benzoxazole, or benzimidazole group, preferably, that contain a benzothiazole group, one or more hydrophobic sulfonic acid catalyst, one or more pigment, extender or filler, one or more a) polycarbamates from alkyd polyol or acrylic polyol and one or more b) a polyaldehydes or the acetal or hemiacetal thereof as a second component. The multicomponent compositions cure quickly at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane coating having improved humidity and corrosion resistance.
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公开(公告)号：US09695335B2
公开(公告)日：2017-07-04
申请号：US14734205
申请日：2015-06-09
发明人： John N. Argyropoulos , Paul Foley , Eric Greyson , Jeff R. Anderson , Gary E. Spilman , Caroline Slone , Nahrain E. Kamber
IPC分类号： C08G63/91 , C09D135/02 , C09D167/08 , C08F22/10 , C08G63/12 , C09J133/06
CPC分类号： C09D167/08 , C08F22/10 , C08G63/12 , C08G63/914 , C08L2312/00 , C09D135/02 , C09J133/066
摘要： The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.
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公开(公告)号：US09079987B2
公开(公告)日：2015-07-14
申请号：US14512650
申请日：2014-10-13
发明人： John N. Argyropoulos , Paul Foley , Eric Greyson , Jeff R. Anderson , Gary E. Spilman , Caroline Slone , Nahrain E. Kamber
IPC分类号： C08G12/02 , C08G14/00 , C08F283/02 , C08G63/12 , C09J133/06 , C08F22/10 , C08G63/91 , C09D135/02 , C09D167/08
CPC分类号： C09D167/08 , C08F22/10 , C08G63/12 , C08G63/914 , C08L2312/00 , C09D135/02 , C09J133/066
摘要： The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.
摘要翻译： 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; （c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US20140221554A1
公开(公告)日：2014-08-07
申请号：US14252117
申请日：2014-04-14
发明人： Eric Greyson , John N. Argyropoulos , Paul Foley , Andrew Swartz , Nahrain E. Kamber , Caroline Slone , Manesh N. Sekharan
IPC分类号： C09D133/14
CPC分类号： C09D133/14 , C08L61/02 , C08L75/14 , C09D175/04
摘要： The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.
摘要翻译： 本发明提供了一种可交联水性组合物，其制备方法，交联组合物及其制备方法。 所述可交联组合物包含：水分散体，其包含： （一杯水; （b）包含至少平均2.0个氨基甲酸酯官能团的聚氨酯; （c）包含至少两个醛基的多醛; （d）酸催化剂; 和（e）任选的一种或多种表面活性剂; 其中所述水性分散体的pH在小于7的范围内; 并且其中所述组合物能够在基本上除去水后在低于80℃的温度范围内交联。
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公开(公告)号：US20130165581A1
公开(公告)日：2013-06-27
申请号：US13727963
申请日：2012-12-27
发明人： John N. Argyropoulos , Paul Foley , Eric Greyson , Jeff R. Anderson , Gary E. Spilman , Caroline Slone , Nahrian E. Kamber
CPC分类号： C09D167/08 , C08F22/10 , C08G63/12 , C08G63/914 , C08L2312/00 , C09D135/02 , C09J133/066
摘要： The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.
摘要翻译： 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; 和（c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US08889818B2
公开(公告)日：2014-11-18
申请号：US13727963
申请日：2012-12-27
发明人： John N. Argyropoulos , Paul Foley , Eric Greyson , Jeff R. Anderson , Gary E. Spilman , Caroline Slone , Nahrain E. Kamber
IPC分类号： C08G12/02 , C08G14/00 , C08F283/02 , C08G63/12 , C09J133/06 , C08F22/10
CPC分类号： C09D167/08 , C08F22/10 , C08G63/12 , C08G63/914 , C08L2312/00 , C09D135/02 , C09J133/066
摘要： The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.
摘要翻译： 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; 和（c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US10131813B2
公开(公告)日：2018-11-20
申请号：US15214907
申请日：2016-07-20
IPC分类号： C08K5/00 , C09D175/12 , C09D5/08
摘要： The present invention provides substantially isocyanate-free multicomponent compositions useful in making rapid dry primer compositions and coatings, the compositions comprising one or more carboxylic acid compounds that contain one of a benzothiazole, benzoxazole, or benzimidazole group, preferably, that contain a benzothiazole group, one or more hydrophobic sulfonic acid catalyst, one or more pigment, extender or filler, one or more a) polycarbamates from alkyd polyol or acrylic polyol and one or more b) a polyaldehydes or the acetal or hemiacetal thereof as a second component. The multicomponent compositions cure quickly at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane coating having improved humidity and corrosion resistance.
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8.发明授权公开(公告)号：US10669429B2
公开(公告)日：2020-06-02
申请号：US16116602
申请日：2018-08-29
IPC分类号： C09D5/00 , C09D5/08 , C09D7/61 , C09D175/06 , C09D7/63 , C09D17/00 , C09D175/04 , C08K3/36
摘要： The present invention provides substantially isocyanate-free multicomponent compositions useful in making rapid dry primer compositions and coatings, the compositions comprising one or more carboxylic acid compounds that contain one of a benzothiazole, benzoxazole, or benzimidazole group, preferably, that contain a benzothiazole group, one or more hydrophobic sulfonic acid catalyst, one or more pigment, extender or filler, one or more a) polycarbamates from alkyd polyol or acrylic polyol and one or more b) a polyaldehydes or the acetal or hemiacetal thereof as a second component. The multicomponent compositions cure quickly at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane coating having improved humidity and corrosion resistance.
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公开(公告)号：US20140369850A1
公开(公告)日：2014-12-18
申请号：US13920341
申请日：2013-06-18
发明人： Paul J. Popa , Ben W. Schaefer , John N. Argyropoulos , Kenneth E. Wohltmann , Sandra Hofmann , Daniel Haile , Paul Foley , YanXiang Li
IPC分类号： C09D133/08 , F03D1/06 , B64C27/46 , F01D5/28
CPC分类号： B64C27/46 , C08G12/46 , C08K5/07 , C09D133/10 , C09D161/20 , F01D5/288 , F05B2280/6011 , F05D2300/43 , Y02E10/721 , Y02T50/672 , C09D133/14 , C08F2220/1825 , C08F220/20 , C08F2220/1858 , C08F220/14 , C08F2220/1875 , C08F220/06
摘要： The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25° C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70° C.
摘要翻译： 本发明提供了可交联的涂料组合物，其制备方法和用其涂布的基材。 可交联涂料组合物包含：（a）多醛，或其缩醛或半缩醛; （b）pKa小于6的酸催化剂; （c）液体介质; （d）包含至少平均2.0个氨基甲酸酯官能团的丙烯酸聚氨酯，其中所述聚氨酯具有小于25℃的玻璃化转变温度（Tg）。 和（e）一种或多种pH值在等于或小于9的范围内的一种或多种填料和/或一种或多种pH值在等于或小于9的范围内的颜料，和/或一种或多种添加剂具有 pH在等于或小于9的范围内，其中所述组合物的固化温度在小于70℃的范围内。
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公开(公告)号：US10144846B2
公开(公告)日：2018-12-04
申请号：US14899659
申请日：2014-06-05
发明人： Paul J. Popa , Ben W. Schaefer , John N. Argyropoulos , Kenneth E. Wohltmann , Sandra Hofmann , Daniel Haile , Yanxiang Li , Paul Foley
IPC分类号： C09D175/14 , C08K3/22 , C08K3/34 , C08K3/36 , C08G12/46 , C09D133/10 , C09D161/20 , F01D5/28
摘要： The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25° C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70° C.
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