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    Versatile horology component
    1.
    发明授权
    Versatile horology component 有权

    公开(公告)号：US11531305B2

    公开(公告)日：2022-12-20

    申请号：US16448971

    申请日：2019-06-21

    Applicant: ROLEX SA

    Inventor： Detlef Berner ,  Pierre Di Luna ,  Romain Girod ,  Alexandre Oliveira ,  Ollivier Pujol ,  Alexandra Roulet

    IPC: G04G9/00 ,  G04G11/00 ,  G04G17/08

    Abstract: A horology component (1) for a timepiece, including a first portion (10) and a second portion (20), the first portion (10) comprising one part that is at least partially transparent and at least partially superposed on top of the second portion (20), this second portion (20) taking the form of a massive portion comprising a material capable of emitting at least one emission light wave if excited by at least one excitation light wave, and the at least partially transparent part of the first portion allowing an emission light wave emitted by the second portion (20) to be transmitted at least partially toward the outside of the horology component so that the horology component exhibits at least a first appearance by day and at least one different second appearance by night where the first portion (10) is backlit by an emission light wave emitted by the second portion (20).

    Novel Long Decay Phosphors
    2.
    发明申请
    Novel Long Decay Phosphors 有权
    新型长衰减荧光粉

    公开(公告)号：US20130207040A1

    公开(公告)日：2013-08-15

    申请号：US13759104

    申请日：2013-02-05

    Applicant: Rolex SA

    Inventor： Detlef Berner ,  Hans U. Güdel ,  Isabelle Rigot ,  Romain Girod ,  Christoph Kenzelmann

    IPC: C09K11/77

    CPC classification number: C09K11/7792

    Abstract: The present invention relates to long decay phosphors comprising rare earth activated strontium aluminates and methods for producing them. The phosphors comprise a matrix of the formula Sr4Al14O25 comprising europium as an activator and a further rare earth element as a co-activator, wherein the molar ratio of Al/Sr in the starting materials is in the range of 3.1 to less than 3.5 and the ratio of Eu/Sr is in the range of 0.0015 to 0.01. The process for the preparation of a phosphor comprises the steps of milling the starting materials for the synthesis of the phosphor, the starting materials comprising a boron compound selected from boric acid, boric oxide or a borate salt in an amount such that the B/Sr molar ratio is between 0.1 and to 0.3, treating the milled composition with heat, grinding the block material which is obtained through the heat treatment, ball-milling the crushed material, sieving the material, and washing the material with an aqueous solution.

    Abstract translation: 本发明涉及包含稀土活化的锶铝酸盐的长衰减磷光体及其制备方法。 磷光体包含式Sr4Al14O25的基质，其包含作为活化剂的铕和作为助活化剂的另外的稀土元素，其中原料中Al / Sr的摩尔比在3.1至小于3.5的范围内， Eu / Sr的比例在0.0015〜0.01的范围内。 制备荧光体的方法包括以下步骤：研磨用于合成荧光体的原料，所述起始材料包含选自硼酸，氧化硼或硼酸盐的硼化合物，其量使得B / Sr 摩尔比在0.1和0.3之间，用热处理研磨的组合物，研磨通过热处理获得的块材料，球磨研磨破碎的材料，筛分材料，并用水溶液洗涤材料。

    VERSATILE HOROLOGY COMPONENT
    5.
    发明申请
    VERSATILE HOROLOGY COMPONENT 审中-公开

    公开(公告)号：US20190391535A1

    公开(公告)日：2019-12-26

    申请号：US16448971

    申请日：2019-06-21

    Applicant: ROLEX SA

    Inventor： Detlef Berner ,  Pierre Di Luna ,  Romain Girod ,  Alexandre Oliveira ,  Ollivier Pujol ,  Alexandra Roulet

    IPC: G04G9/00 ,  G04G11/00 ,  G04G17/08

    Abstract: A horology component (1) for a timepiece, including a first portion (10) and a second portion (20), the first portion (10) comprising one part that is at least partially transparent and at least partially superposed on top of the second portion (20), this second portion (20) taking the form of a massive portion comprising a material capable of emitting at least one emission light wave if excited by at least one excitation light wave, and the at least partially transparent part of the first portion allowing an emission light wave emitted by the second portion (20) to be transmitted at least partially toward the outside of the horology component so that the horology component exhibits at least a first appearance by day and at least one different second appearance by night where the first portion (10) is backlit by an emission light wave emitted by the second portion (20).

    Long decay phosphors
    7.
    发明授权
    Long decay phosphors 有权
    长衰减荧光粉

    公开(公告)号：US09394480B2

    公开(公告)日：2016-07-19

    申请号：US13759104

    申请日：2013-02-05

    Applicant: Rolex SA

    Inventor： Detlef Berner ,  Hans U. Güdel ,  Isabelle Rigot ,  Romain Girod ,  Christoph Kenzelmann

    IPC: C09K11/77

    CPC classification number: C09K11/7792

    Abstract: The present invention relates to long decay phosphors comprising rare earth activated strontium aluminates and methods for producing them. The phosphors comprise a matrix of the formula Sr4Al14O25 comprising europium as an activator and a further rare earth element as a co-activator, wherein the molar ratio of Al/Sr in the starting materials is in the range of 3.1 to less than 3.5 and the ratio of Eu/Sr is in the range of 0.0015 to 0.01. The process for the preparation of a phosphor comprises the steps of milling the starting materials for the synthesis of the phosphor, the starting materials comprising a boron compound selected from boric acid, boric oxide or a borate salt in an amount such that the B/Sr molar ratio is between 0.1 and to 0.3, treating the milled composition with heat, grinding the block material which is obtained through the heat treatment, ball-milling the crushed material, sieving the material, and washing the material with an aqueous solution.

    Abstract translation: 本发明涉及包含稀土活化的锶铝酸盐的长衰减磷光体及其制备方法。 磷光体包含式Sr4Al14O25的基质，其包含作为活化剂的铕和作为助活化剂的另外的稀土元素，其中原料中Al / Sr的摩尔比在3.1至小于3.5的范围内， Eu / Sr的比例在0.0015〜0.01的范围内。 制备荧光体的方法包括以下步骤：研磨用于合成荧光体的原料，所述起始材料包含选自硼酸，氧化硼或硼酸盐的硼化合物，其量使得B / Sr 摩尔比在0.1和0.3之间，用热处理研磨的组合物，研磨通过热处理获得的块材料，球磨研磨破碎的材料，筛分材料，并用水溶液洗涤材料。

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