公开(公告)号：US06844370B2

公开(公告)日：2005-01-18

申请号：US10319805

申请日：2002-12-12

申请人： Rafael Luis Espinoza ,  Tracy Carolyn Bromfield ,  Frederick Gideon Botes ,  Rentia Visagie ,  Keith Henry Lawson ,  Philip Gibson

发明人： Rafael Luis Espinoza ,  Tracy Carolyn Bromfield ,  Frederick Gideon Botes ,  Rentia Visagie ,  Keith Henry Lawson ,  Philip Gibson

IPC分类号： B01J23/00 ,  B01J23/745 ,  B01J23/78 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  B01J37/18 ,  C07C1/04 ,  C10G2/00 ,  C07C27/00

CPC分类号： C10G2/332 ,  B01J23/745 ,  B01J23/78 ,  B01J35/0053 ,  B01J35/10 ,  B01J35/1014 ,  B01J37/031 ,  B01J37/16 ,  B01J37/18 ,  C07C1/0445 ,  C07C2523/745

摘要： According to the present invention there is provided a hydrocarbon synthesis catalyst comprising a precipitated iron product and a catalyst promotor. The catalyst has a surface area of below 60 m2 per gram of catalyst in the reduced form or below 100 m2 per gram of catalyst in the non-reduced form. According to the invention there is also provided a process for preparing the catalyst and the use thereof in the synthesis of hydrocarbons.

摘要翻译： 根据本发明，提供一种包含沉淀铁产物和催化剂促进剂的烃合成催化剂。 该催化剂的表面积小于60m 2 /克催化剂，还原形式或低于100m 2 /克非还原形式的催化剂。 根据本发明，还提供了制备催化剂的方法及其在合成烃中的用途。

公开(公告)号：US07459485B2

公开(公告)日：2008-12-02

申请号：US10511390

申请日：2003-04-15

申请人： Frederick Gideon Botes ,  Tracy Carolyn Bromfield ,  Philip Gibson ,  Rafael Luis Espinoza

发明人： Frederick Gideon Botes ,  Tracy Carolyn Bromfield ,  Philip Gibson ,  Rafael Luis Espinoza

IPC分类号： C07C27/00 ,  C07C27/06

CPC分类号： C10G2/332 ,  B01J23/745 ,  B01J23/78 ,  B01J29/40 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/031 ,  C10G2/334

摘要： This invention relates to a hydrocarbon synthesis process comprising the conversion of a feed of H2 and at least one carbon oxide to hydrocarbons containing at least 30% on a mass basis hydrocarbons with five or more carbon atoms. The conversion is carried out in the presence of an alkali-promoted iron hydrocarbon synthesis catalyst and an acidic catalyst suitable for converting hydrocarbons. The reaction mixture formed during the conversion contains less than 0.02 mol alkali per 100 g iron and the H2:carbon oxide molar ration in the feed of H2 and carbon oxide is at least 2.

摘要翻译： 本发明涉及一种烃合成方法，其包括将H 2和至少一种碳氧化物的原料转化为含有至少30％的烃与基于具有五个或更多个碳原子的烃的烃。 该转化是在碱促进的铁烃合成催化剂和适于转化烃的酸性催化剂的存在下进行的。 在转化过程中形成的反应混合物含有少于0.02摩尔碱/ 100g铁，H2和碳氧化物进料中的H 2：氧化碳摩尔比为至少2。

公开(公告)号：US07655704B2

公开(公告)日：2010-02-02

申请号：US10510836

申请日：2003-04-15

申请人： Frederick Gideon Botes ,  Tracy Carolyn Bromfield

发明人： Frederick Gideon Botes ,  Tracy Carolyn Bromfield

IPC分类号： C07C27/00

CPC分类号： C10G2/332 ,  B01J23/745 ,  B01J23/78 ,  B01J29/40 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/031 ,  C10G2/334

摘要： This invention relates to a high temperature Fischer-Tropsch (HTFT) hydrocarbon synthesis process comprising the conversion of a feed of H2 and at least one carbon oxide to hydrocarbons containing at least 30% on a mass basis hydrocarbons with five or more carbon atoms (hereinafter referred to as C5+ compounds). The conversion is carried out in the presence of an alkali-promoted iron hydrocarbon synthesis catalyst, and the process is characterised therein that the reaction mixture formed during the conversion contains less than 0.02 mol alkali per 100 g iron, and that the H2:carbon oxide molar ratio in the feed of H2 and carbon oxide is at least 2.

摘要翻译： 本发明涉及一种高温费托（HTFT）烃合成方法，其包括将H 2和至少一种碳氧化物的原料转化成基于质量基于至少30％的具有五个或更多个碳原子的烃的烃 称为C5 +化合物）。 转化在碱促进的铁烃合成催化剂的存在下进行，其特征在于转化中形成的反应混合物含有每100g铁少于0.02摩尔的碱，并且H 2：碳氧化物 H 2和CO 2进料中的摩尔比至少为2。