公开(公告)号：US20050131235A1

公开(公告)日：2005-06-16

申请号：US10731440

申请日：2003-12-10

申请人： Ashutosh Agarwal ,  Pradeep Verma ,  Kumar Singh ,  Praphulla Joshi ,  Gopal Chaphekar ,  Prashant Niphadkar ,  Rajiv Kumar

发明人： Ashutosh Agarwal ,  Pradeep Verma ,  Kumar Singh ,  Praphulla Joshi ,  Gopal Chaphekar ,  Prashant Niphadkar ,  Rajiv Kumar

IPC分类号： C07D213/10 ,  C07D213/08 ,  C07D213/14

CPC分类号： C07D213/10

摘要： The present invention relates to a single step new catalytic process for the production of pyridine and picolines from a mixture of carbonyl compound and ammonia in the presence of zeolite catalyst with MFI topology containing Si and Zr and/or Sn as zeolite constituents in gas phase. The catalyst is preferably loaded with other metal ions such as lead, nickel, thallium or their mixture for increased yield. Present invention provides the novel use of above mentioned zeolite catalysts for the production of picolines for the first time, with improved yield of desired products picolines.

摘要翻译： 本发明涉及在气相中含有Si和Zr和/或Sn作为沸石成分的MFI拓扑结构的沸石催化剂存在下由羰基化合物和氨的混合物制备吡啶和吡啶类的单步新催化方法。 催化剂优选负载其它金属离子如铅，镍，铊或它们的混合物以提高产率。 本发明提供了上述沸石催化剂首次用于生产吡啶甲酸的新颖应用，并提高了所需产物吡啶的产率。

公开(公告)号：US20050209457A1

公开(公告)日：2005-09-22

申请号：US10806061

申请日：2004-03-22

申请人： Rajiv Kumar ,  Praphulla Joshi ,  Gopal Chaphekar ,  Prashant Niphadkar ,  Ashutosh Agarwal ,  Pradeep Verma ,  Kumar Singh

发明人： Rajiv Kumar ,  Praphulla Joshi ,  Gopal Chaphekar ,  Prashant Niphadkar ,  Ashutosh Agarwal ,  Pradeep Verma ,  Kumar Singh

IPC分类号： B01J29/89 ,  C07D213/06 ,  C07D213/08 ,  C07D213/09 ,  C07D213/10

CPC分类号： C07D213/08 ,  B01J29/89 ,  B01J2229/12 ,  B01J2229/32 ,  C07D213/10

摘要： An process for the preparation of pyridine and/or picolines is disclosed. The process comprises contacting a mixture of carbonyl compound with ammonia in the presence of surface-passivated titanium-silicate catalyst in gas phase at a temperature ranging between 300-500° C., at gas space velocity in the range of 300 to 3000 h−1 and at a pressure ranging between 1 to 10 atmosphere, condensing and separating the products by conventional methods and if desired, further purifying the product using well known conventional methods.

摘要翻译： 公开了制备吡啶和/或吡啶甲酸的方法。 该方法包括在表面钝化的钛硅酸盐催化剂存在下，在300-300℃的温度范围内，在300-500℃的温度范围内，使羰基化合物与氨的混合物在气相中接触， SUP> -1，并且在1至10个大气压的范围内，通过常规方法冷凝和分离产物，如果需要，使用公知的常规方法进一步纯化产物。