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1.发明授权Lithium dialkylamide and lithium alkylenecycloimide formulations and methods of preparation 失效二烷基胺锂和亚烷基亚环己基亚胺制剂及其制备方法
公开(公告)号：US5923044A
公开(公告)日：1999-07-13
申请号：US856893
申请日：1997-05-15
IPC分类号： C07F1/00 , C09X3/00 , C07C209/90
CPC分类号： C07F1/005
摘要： A process for producing nornally liquid hydrocarbon solutions of lithium dialkylamides and lithium alkylenecycloimides, essentially free of ethers and by-product gaseous alkanes derived from C1-C4 alkyllithium compounds, comprising reacting lithium metal with a C.sub.5 to C.sub.12 secondary amine and an electron carrier compound containing at least five carbon atoms in a normally liquid hydrocarbon solvent.
摘要翻译： 一种用于生产基本上不含C 1 -C 4烷基锂化合物的醚和副产物气态烷烃的二烷基氨基锂和亚烷基环己烷亚胺的轻质液体烃溶液的方法，包括使锂金属与C5至C12仲胺反应，以及含有 在常规烃溶剂中至少有五个碳原子。
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公开(公告)号：US5605872A
公开(公告)日：1997-02-25
申请号：US459585
申请日：1995-06-02
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 制备以下一般结构的单官能胺引发剂的烃溶液的方法：MQnZN（A（R1R2R3））2金属，选自锂，钠和钾，Q是衍生的饱和或不饱和烃基 通过并入选自共轭二烯烃和烯基取代的芳族烃的化合物; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。
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公开(公告)号：US5527753A
公开(公告)日：1996-06-18
申请号：US354998
申请日：1994-12-13
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 制备以下一般结构的单官能胺引发剂的烃溶液的方法：MQnZN（A（R1R2R3））2金属，选自锂，钠和钾，Q是衍生的饱和或不饱和烃基 通过并入选自共轭二烯烃和烯基取代的芳族烃的化合物; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。
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公开(公告)号：US5523364A
公开(公告)日：1996-06-04
申请号：US458198
申请日：1995-06-02
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 制备以下一般结构的单官能胺引发剂的烃溶液的方法：其中M定义为碱金属，其选自锂，钠和钾，Q是饱和或 通过引入选自共轭二烯烃和烯基取代的芳族烃的化合物衍生的不饱和烃基; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。
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公开(公告)号：US5211888A
公开(公告)日：1993-05-18
申请号：US842944
申请日：1992-02-27
申请人： Robert C. Morrison , Randy W. Hall , James A. Schwindeman , Conrad W. Kamienski , John F. Engel
发明人： Robert C. Morrison , Randy W. Hall , James A. Schwindeman , Conrad W. Kamienski , John F. Engel
IPC分类号： B01J31/02 , B01J31/12 , C07B61/00 , C07F1/00 , C07F1/02 , C07F1/04 , C07F1/06 , C07F7/08 , C07F7/12
CPC分类号： C07F7/0896 , C07F1/00 , C07F1/02 , C07F7/122
摘要： A catalytic process for alkylating an alkali metal selected from lithium, sodium and potassium with an alkyl halide containing 3 to 20 carbon atoms comprising conducting the reaction in the presence of a catalytic compound represented by the formula(RR.sup.1 R.sup.2 M.sup.a)yA(R.sup.3)xwherein R, R.sup.1 and R.sup.2 are independently selected from hydrogen, halogen, alkyl, alkenyl, cycloalkyl, and aryl groups, R.sup.3 is independently selected from aryl groups containing 6 to 18 carbon atoms, four to six-membered heterocyclic carbon containing groups containing one to two hetero atoms selected from oxygen, nitrogen, and sulfur; hydroxyalkyl, alkoxyalkyl and monoalkylaminoalkyl and dialkylaminoalkyl groups containing 2 to 13 carbon atoms; M.sup.a is selected from silicon, carbon, germanium, and tin, A is selected from oxygen, sulfur, nitrogen and phosphorus, and x and y independently have values from zero to three.
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公开(公告)号：US5550203A
公开(公告)日：1996-08-27
申请号：US460305
申请日：1995-06-02
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures:M--Q.sub.n --Z--N(A(R.sup.1 R.sup.2 R.sup.3)).sub.2or ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 制备以下一般结构的单官能胺引发剂的烃溶液的方法：选自锂，钠和钾的M-Qn-ZN（A（R1R2R3））2金属，Q是饱和或 通过引入选自共轭二烯烃和烯基取代的芳族烃的化合物衍生的不饱和烃基; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表Ⅳa的元素，R 1，R 2和R 3独立地选自氢，取代的烷基，环烷基，芳基或取代的芳基，m是0至7的整数，n是整数 1至5个，通过该方法制备的单官能胺引发剂，在聚合过程中使用引发剂和通过聚合方法制备的聚合物。
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公开(公告)号：US5340507A
公开(公告)日：1994-08-23
申请号：US035998
申请日：1993-03-23
申请人： Robert C. Morrison , Randy W. Hall , James A. Schwindeman , Conrad W. Kamienski , John F. Engel
发明人： Robert C. Morrison , Randy W. Hall , James A. Schwindeman , Conrad W. Kamienski , John F. Engel
IPC分类号： B01J31/02 , B01J31/12 , C07B61/00 , C07F1/00 , C07F1/02 , C07F1/04 , C07F1/06 , C07F7/08 , C07F7/12
CPC分类号： C07F1/00 , C07F1/02 , C07F7/0896 , C07F7/122
摘要： A catalytic process for alkylating an alkali metal selected from lithium, sodium and potassium with an alkyl halide containing 3 to 20 carbon atoms comprising conducting the reaction in the presence of a catalytic compound represented by the formula(RR.sup.1 R.sup.2 M.sup.a).sub.y A(R.sup.3).sub.xwherein R, R.sup.1 and R.sup.2 are independently selected from hydrogen, halogen, alkyl, alkenyl, cycloalkyl, and aryl groups, R.sup.3 is independently selected from alkyl groups containing 1 to 10 carbon atoms, alkylene groups containing 2 to 5 carbon atoms, aryl groups containing 6 to 18 carbon atoms, four to six-membered heterocyclic carbon containing groups containing one to two hetero atoms selected from oxygen, nitrogen, and sulfur; hydroxyalkyl, alkoxyalkyl and monoalkylaminoalkyl and dialkylaminoalkyl groups containing 2 to 13 carbon atoms; M.sup.a is selected from silicon, carbon, germanium, and tin, A is selected from oxygen, sulfur, nitrogen and phosphorus, and x and y independently have values from zero to three.
摘要翻译： 一种用含有3-20个碳原子的烷基卤烷基化选自锂，钠和钾的碱金属的催化方法，包括在由式（RR1R2Ma）yA（R3）x表示的催化化合物存在下进行反应，其中R R 1和R 2独立地选自氢，卤素，烷基，烯基，环烷基和芳基，R 3独立地选自含有1至10个碳原子的烷基，含2至5个碳原子的亚烷基，含6至 18个碳原子，含有1至2个选自氧，氮和硫的杂原子的含有4至6元杂环碳的基团; 羟基烷基，烷氧基烷基和单烷基氨基烷基和含有2至13个碳原子的二烷基氨基烷基; Ma选自硅，碳，锗和锡，A选自氧，硫，氮和磷，x和y独立地具有从零到三的值。
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公开(公告)号：US5332533A
公开(公告)日：1994-07-26
申请号：US87582
申请日：1993-07-06
申请人： James A. Schwindeman , Robert C. Morrison , B. Troy Dover , John F. Engel , Conrad W. Kamienski , Randy W. Hall , Douglas E. Sutton
发明人： James A. Schwindeman , Robert C. Morrison , B. Troy Dover , John F. Engel , Conrad W. Kamienski , Randy W. Hall , Douglas E. Sutton
IPC分类号： C07F1/02
CPC分类号： C07F1/02
摘要： A high temperature process for producing alkyllithium compounds in high yields of at least 90% and high purity comprising reacting, in a liquid hydrocarbon solvent, an alkyl halide containing 3 to 16 carbon atoms and mixtures thereof with lithium metal particles of less than 300 microns in size at a temperature between 35.degree. and 125.degree. C. and recovering the alkyllithium compound.
摘要翻译： 用于以高产率生产烷基锂化合物的高温方法为至少90％和高纯度，包括在液体烃溶剂中将含有3至16个碳原子的烷基卤及其与小于300微米的锂金属颗粒的混合物反应 在35〜125℃的温度下回收烷基锂化合物。
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9.发明授权Contaminant free organometallic amide compositions and processes for making same 失效污染物游离有机金属酰胺组合物及其制备方法
公开(公告)号：US6060617A
公开(公告)日：2000-05-09
申请号：US670348
申请日：1996-06-25
申请人： Randy W. Hall , Bobby J. McElroy , James A. Schwindeman , Conrad W. Kamienski , Terry L. Rathman , Robert C. Morrison
发明人： Randy W. Hall , Bobby J. McElroy , James A. Schwindeman , Conrad W. Kamienski , Terry L. Rathman , Robert C. Morrison
IPC分类号： C07C211/65 , C07F7/10
CPC分类号： C07F7/10 , C07C211/65
摘要： Organometallic amide compositions and processes for preparing the same, for example, by: reacting an alkali metal, alkali metal hydride, or alkali metal amide with a substituted amine in the absence of an electron carrier; reacting an alkali metal with a substituted amine in the presence of an electron carrier in a hydrocarbon solvent; distilling a composition which includes an alkali metal amide and a reduced electron carrier to recover the alkali metal amide; reacting an alkali metal with a substituted amine in the presence of an alkyl halide; and reacting a substituted amine capable of reacting with an alkali metal to form a hydrocarbon insoluble alkali metal amide with an alkali metal in the presence of a substituted amine capable of reacting with an alkali metal to form a hydrocarbon soluble alkali metal amide.
摘要翻译： 有机金属酰胺组合物及其制备方法，例如：在不存在电子载体的情况下使碱金属，碱金属氢化物或碱金属氨化物与取代的胺反应; 在电子载体存在下在烃溶剂中使碱金属与取代的胺反应; 蒸馏包含碱金属氨化物和还原电子载体以回收碱金属胺的组合物; 在烷基卤存在下使碱金属与取代的胺反应; 并使能够与碱金属反应的取代的胺与能够与碱金属反应形成烃溶性碱金属氨化物的取代胺存在下与碱金属形成不溶于烃的碱金属胺。
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10.发明授权Functionalized polymer produced with functionalized initiators by anionic polymerization 失效通过阴离子聚合用官能化引发剂制备的官能化聚合物
公开(公告)号：US5792815A
公开(公告)日：1998-08-11
申请号：US878691
申请日：1997-06-19
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M--Z--O--C(R.sup.1 R.sup.2 R.sup.3) wherein M is an alkali metal; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, aryl or substituted aryl groups, and their employment as initiators in the anionic polymerization of olefin containing monomers in an inert, hydrocarbon solvent comprising reacting an omega-protected-1-haloalkyl with lithium metal dispersion having a particle size between 10 and 300 millimicrons in size, at a temperature between 35.degree. and 130.degree. C. in an alkane solvent containing 5 to 10 carbon atoms.
摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Z-O-C（R 1 R 2 R 3）其中M为碱金属; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; 并且R 1，R 2和R 3独立地选自氢，烷基，取代的烷基，芳基或取代的芳基，并且它们用作惰性烃溶剂中含烯烃单体的阴离子聚合中的引发剂，包括使ω-保护的 - 在具有5至10个碳原子的烷烃溶剂中，在35至130℃之间的温度下，具有尺寸在10-300毫微米之间的锂金属分散体的1-卤代烷基。
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