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公开(公告)号：US5491276A
公开(公告)日：1996-02-13
申请号：US202866
申请日：1994-02-25
IPC分类号： C07C5/27
CPC分类号： C07C5/2775 , C07C2529/06 , C07C2529/86 , C07C2529/87 , C07C2529/88 , Y02P20/125
摘要： The conversion of normal olefins such as n-butylenes can be converted to branched olefin species such as isobutylene by skeletal isomerization over zeolite-based catalysts having pore sizes of at least about 4.5 Angstroms and a pore structure characterized by intersecting 10-MR and 8 MR channels. The zeolite-based catalysts have sufficient acidity to catalyze the skeletal isomerization of normal olefins. The catalysts can be used to produce isoolefins for reaction with alcohols in integrated processes to produce alkyl tertiary alkyl ethers such as MTBE.
摘要翻译： 普通烯烃如正丁烯的转化可以通过骨架异构化转化为支链烯烃物质，例如孔径为至少约4.5埃的沸石基催化剂和以10-MR和8MR相交为特征的孔结构 频道 沸石基催化剂具有足够的酸度来催化正构烯烃的骨架异构化。 催化剂可以用于制备用于与醇在一体化方法中反应的异烯烃，以产生烷基叔烷基醚如MTBE。
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2.发明授权Treated bound ferrierite zeolites for skeletal isomerization of n-olefins to iso-olefins 失效用于骨架异构化正烯烃到异烯烃的结合镁碱沸石沸石
公开(公告)号：US5523510A
公开(公告)日：1996-06-04
申请号：US112920
申请日：1993-08-30
CPC分类号： B01J37/10 , B01J29/65 , C07C5/2775 , B01J2229/36
摘要： A process of converting linear olefins to branched olefins by a skeletal isomerization reaction wherein said reaction is carried out at a temperature of between about 300.degree. C. and about 650.degree. C., under a pressure of between about 0.1 and about 100 atmospheres and a space velocity of said linear olefins of between about 0.1 and about 40 WHSV in the presence of a steamed then acid washed zeolite ferrierite catalyst.
摘要翻译： 通过骨架异构化反应将线性烯烃转化为支链烯烃的方法，其中所述反应在约300℃至约650℃的温度下，在约0.1至约100大气压的压力下进行， 所述直链烯烃的空速在约0.1至约40WHSV之间，在蒸的酸洗沸沸石镁碱沸石催化剂存在下。
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3.发明授权Skeletal isomerization of n-olefins to iso-olefins on binded ferrierite zeolites 失效在结合的镁碱沸石沸石上正构烯烃异构化成异烯烃
公开(公告)号：US5510560A
公开(公告)日：1996-04-23
申请号：US112921
申请日：1993-08-30
CPC分类号： C07C5/2775 , C07C2529/06
摘要： The method of converting n-butylenes to isobutylene by a skeletal isomrization reaction wherein said reaction is carried out at a temperature of between 300.degree. C. and 650.degree. C., under a pressure of between 0.1 and 100 atmospheres and a space velocity of said n-butylenes of between 0.1 and 40 WHSV using a cagalyst comprising a zeolite binder selected frm the group consisting of alumina, silica, silica-alumina, clay and a combination thereof, said catalyst having a pore size of at least about 4.5 angstroms and the pore size structure is characteried by intersecting 10-member ring and 8-member ring channels.
摘要翻译： 通过骨架均化反应将正丁烯转化为异丁烯的方法，其中所述反应在约100℃至100℃之间的压力下在300℃和650℃之间的温度下进行，所述反应在所述 使用包含选自由氧化铝，二氧化硅，二氧化硅 - 氧化铝，粘土及其组合组成的组的沸石粘合剂的囊状物的0.1至40WHSV的正丁烯，所述催化剂的孔径至少为约4.5埃， 孔径结构的特征是10个环和8个环通道相交。
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4.发明授权
公开(公告)号：US5198597A
公开(公告)日：1993-03-30
申请号：US738017
申请日：1991-07-30
CPC分类号： C07C5/2791 , C07C5/373 , Y02P20/125
摘要： Normal olefins such as n-butenes and normal alkanes such as n-butane can be coverted to branched olefin species such as isobutylene by skeletal dehydroisomerization over catalysts preferably containing metals selected from Groups IB, IIB, IIIB, IVB, VB, VIB, VIIB, VIII and the rear earth elements which are deposited upon borosilicate zeolites having pore sizes of at least about 5 Angstroms and containing boron in the framework structure thereof. The borosilicates have sufficient acidity to catalyze the skeletal isomerization of both normal alkanes and normal olefins. The catalysts can be used to produce isoolefins for reaction with alcohols in integrated processes to produce alkyl tertiary alkyl ethers such as MTBE.
摘要翻译： 在优选含有选自IB，IIB，IIIB，IVB，VB，VIB，VIIB，VIIB族的金属的催化剂的催化剂上，可以通过骨架脱氢异构化将正丁烯和正丁烷如正丁烷等正构烯烃覆盖至支链烯烃，如异丁烯， VIII和沉积在孔径为至少约5埃的硼硅酸盐沸石上并在其骨架结构中含有硼的后土元素。 硼硅酸盐具有足够的酸度来催化正构烷烃和正构烯烃的骨架异构化。 催化剂可以用于制备用于与醇在一体化方法中反应的异烯烃，以产生烷基叔烷基醚如MTBE。
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公开(公告)号：US5182247A
公开(公告)日：1993-01-26
申请号：US653217
申请日：1991-02-11
IPC分类号： B01J27/053 , C07C5/27
CPC分类号： B01J27/053 , C07C5/2781
摘要： Normal olefins such as n-butene can be converted to branched species by skeletal isomerization over catalysts containing solid acids prepared by sulfating catalyst precursors containing hydrous metal oxides--e.g., aluminas, silica-aluminas or clays treated with sulfuric acid, metal sulfates, sulfur trioxide or organic sulfates. The catalyst precursors are sulfated sufficiently to produce the desired skeletal isomerization without substantial cracking under suitable isomerization conditions.
摘要翻译： 通过骨架异构化，可以通过骨架异构化将正链烯烃转化成支链物质，所述催化剂含有通过硫酸化含有水合金属氧化物的催化剂前体制备的固体酸，例如氧化铝，二氧化硅 - 氧化铝或硫酸处理的粘土，金属硫酸盐，三氧化硫 或有机硫酸盐。 催化剂前体被充分硫酸化以在合适的异构化条件下产生所需的骨架异构化而没有实质的裂解。
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