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公开(公告)号：US4579675A
公开(公告)日：1986-04-01
申请号：US550156
申请日：1983-11-09
IPC分类号： C07D207/40 , C07D207/404 , C10M133/16 , C10M133/56
CPC分类号： C07D207/404 , C10M133/16 , C10M133/56 , C10M2215/04 , C10M2215/086 , C10M2215/26 , C10M2215/28 , C10M2217/046 , C10M2217/06
摘要： Described are novel enaminones of the formula: ##STR1## wherein R is a lower alkyl or oxyalkyl group having 1 to 5 carbon atoms, R.sub.1 is an alkyl group having from 1 to 200 carbon atoms or a similar alkyl group substituted by nitrogen, oxygen or other inert substituents; R.sub.2 is hydrogen or an alkyl group having from 1 to 20 carbon atoms; R.sub.3 is an alkyl or substituted alkyl group having from 1 to 20 carbon atoms. These products are prepared by the reaction of a 1,3-dicarbonyl compound and a primary or secondary amine analog.In neat or mixed form, the present compounds are useful as dispersants-detergents in oleaginous compositions.
摘要翻译： 描述了具有下式的新颖的酮：其中R是具有1至5个碳原子的低级烷基或氧烷基，R 1是具有1至200个碳原子的烷基或类似的被氮取代的烷基，氧或 其他惰性取代基; R2是氢或具有1至20个碳原子的烷基; R3是具有1至20个碳原子的烷基或取代的烷基。 这些产物通过1,3-二羰基化合物与伯胺或仲胺类似物的反应制备。 本发明化合物以纯净或混合的形式用作油性组合物中的分散剂 - 洗涤剂。
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公开(公告)号：US4474704A
公开(公告)日：1984-10-02
申请号：US267211
申请日：1981-05-26
申请人： Robert A. Sawicki
发明人： Robert A. Sawicki
CPC分类号： C07C45/30 , C08G83/001
摘要： A novel catalyst, possessing phase transfer properties contains an alumina or silica substrate bearing poly(oxyethylene) or poly(oxypropylene) moieties bonded through a silicon atom to the substrate.
摘要翻译： 具有相转移特性的新型催化剂包含含有通过硅原子键合到基底上的聚（氧乙烯）或聚（氧化丙烯）部分的氧化铝或二氧化硅基质。
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公开(公告)号：US4419255A
公开(公告)日：1983-12-06
申请号：US344321
申请日：1982-02-01
IPC分类号： C10M133/16 , C10M133/46 , C10M133/48 , C10M1/32
CPC分类号： C10M133/48 , C10M133/16 , C10M133/46 , C10M2215/08 , C10M2215/082 , C10M2215/22 , C10M2215/221 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/28 , C10M2215/30 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： Lubricating oil characterized by improved friction reduction contains friction reducing amounts of a keto amide prepared by the reaction of an amine and an unsaturated cyclic keto acid bearing pendant alkyl groups.
摘要翻译： 以改善摩擦减少为特征的润滑油含有通过胺和带不饱和环状酮酸的侧基烷基的反应制备的酮酰胺的摩擦减少量。
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4.发明授权Novel ligand catalyst systems formed by reaction of carbonyl compounds with organosilicon compounds 失效通过羰基化合物与有机硅化合物的反应形成的新型配体催化剂体系
公开(公告)号：US4900705A
公开(公告)日：1990-02-13
申请号：US109566
申请日：1987-10-19
申请人： Robert A. Sawicki , Harry Chafetz
发明人： Robert A. Sawicki , Harry Chafetz
IPC分类号： B01J21/04 , B01J21/06 , B01J21/08 , B01J23/00 , B01J31/02 , B01J31/16 , B01J31/18 , C07F7/18
CPC分类号： B01J23/007 , B01J31/1633 , B01J31/1805 , B01J31/1855 , C07F7/182 , C07F7/1832 , C07F7/1836 , B01J21/04 , B01J21/063 , B01J21/08 , B01J2231/34 , B01J2531/16
摘要： A novel catalyst system useful in preparation of dimethyl carbonate is prepared by complexing a metal salt such as cupric chloride CuCl.sub.2 with a ligand formed by reacting a carbonyl-containing organic compound such as ethyl formate with an organosilicon compound containing alkoxy and amine fucntionality, such as 3-aminopropyltriethoxysilane.
摘要翻译： 通过使诸如氯化铜CuCl 2等金属盐与含羰基的有机化合物如甲酸乙酯与含有烷氧基和胺官能团的有机硅化合物形成的配位体相配合，制备了一种用于制备碳酸二甲酯的催化剂体系， 3-氨基丙基三乙氧基硅烷。
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公开(公告)号：US4729978A
公开(公告)日：1988-03-08
申请号：US45633
申请日：1987-05-04
申请人： Robert A. Sawicki
发明人： Robert A. Sawicki
IPC分类号： B01J27/18 , B01J27/20 , B01J27/182 , C07C57/04
CPC分类号： B01J27/1806 , C07C51/377
摘要： A process for producing an acidic dehydration catalyst to convert lactic acid to acrylic acid. The process comprises impregnating an inert metal oxide carrier with a phosphate salt and buffering the impregnated carrier with a base to a pH sufficient to provide the effective dehydration catalyst.
摘要翻译： 一种生产酸性脱水催化剂以将乳酸转化为丙烯酸的方法。 该方法包括用磷酸盐浸渍惰性金属氧化物载体并用碱将该浸渍的载体缓冲至足以提供有效脱水催化剂的pH。
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6.发明授权Carboxyalkylation of aryl-substituted alkyl halides to the corresponding esters 失效将芳基取代的烷基卤化物转化成相应的酯
公开(公告)号：US4575561A
公开(公告)日：1986-03-11
申请号：US479592
申请日：1983-03-28
申请人： Robert A. Sawicki
发明人： Robert A. Sawicki
IPC分类号： C07C69/76
CPC分类号： C07C69/76
摘要： Aryl-substituted acetic acid esters are directly prepared by carbonylation of benzyl halides under one atmosphere of carbon monoxide at ambient temperature in alcohol solvent using as catalyst dicobalt octacarbonyl and a base-alumina as co-reactant.
摘要翻译： 芳基取代的乙酸酯通过羰基化苄基卤化物在环境温度的一氧化碳环境温度下在醇溶剂中羰基化制备，使用作为催化剂的二羰基钴和作为共反应物的碱 - 氧化铝。
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公开(公告)号：US5523509A
公开(公告)日：1996-06-04
申请号：US335319
申请日：1994-11-07
CPC分类号： C07C45/002 , B01J23/34 , B01J23/8892 , C07C1/20 , C07C2529/04
摘要： Synthetic manganese oxide octahedral molecular sieves, e.g., OMS-1 and OMS-2, are employed as acid-base catalysts in a variety of acid-base organic conversion reactions.
摘要翻译： 在各种酸碱有机转化反应中，使用合成的氧化锰八面体分子筛，例如OMS-1和OMS-2作为酸碱催化剂。
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8.发明授权
公开(公告)号：US5198597A
公开(公告)日：1993-03-30
申请号：US738017
申请日：1991-07-30
CPC分类号： C07C5/2791 , C07C5/373 , Y02P20/125
摘要： Normal olefins such as n-butenes and normal alkanes such as n-butane can be coverted to branched olefin species such as isobutylene by skeletal dehydroisomerization over catalysts preferably containing metals selected from Groups IB, IIB, IIIB, IVB, VB, VIB, VIIB, VIII and the rear earth elements which are deposited upon borosilicate zeolites having pore sizes of at least about 5 Angstroms and containing boron in the framework structure thereof. The borosilicates have sufficient acidity to catalyze the skeletal isomerization of both normal alkanes and normal olefins. The catalysts can be used to produce isoolefins for reaction with alcohols in integrated processes to produce alkyl tertiary alkyl ethers such as MTBE.
摘要翻译： 在优选含有选自IB，IIB，IIIB，IVB，VB，VIB，VIIB，VIIB族的金属的催化剂的催化剂上，可以通过骨架脱氢异构化将正丁烯和正丁烷如正丁烷等正构烯烃覆盖至支链烯烃，如异丁烯， VIII和沉积在孔径为至少约5埃的硼硅酸盐沸石上并在其骨架结构中含有硼的后土元素。 硼硅酸盐具有足够的酸度来催化正构烷烃和正构烯烃的骨架异构化。 催化剂可以用于制备用于与醇在一体化方法中反应的异烯烃，以产生烷基叔烷基醚如MTBE。
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公开(公告)号：US5093513A
公开(公告)日：1992-03-03
申请号：US146922
申请日：1988-01-22
申请人： Robert A. Sawicki , Harry Chafetz
发明人： Robert A. Sawicki , Harry Chafetz
CPC分类号： B01J31/1805 , B01J31/1633 , C07C68/005 , B01J2231/34 , B01J2531/16 , B01J29/061
摘要： A lower alkanol, such as methanol is oxycarbonylated with carbon monoxide and oxygen to yield e.g. dimethyl carbonate at 50.degree. C.-125.degree. C. and 300-1500 psig in the presence of as catalyst, a functionalized inorganic oxide substrate (such as silica gel) typically bearing on the surface thereof a ligand of ethyl formate and 3-aminopropyl triethoxy silane--which has been reacted with a metal salt such as CuCl.sub.2.
摘要翻译： 低级烷醇如甲醇用一氧化碳和氧气氧化羰基化，得到例如甲醇。 二甲基碳酸酯在50℃-125℃和300-1500psig的存在下，作为催化剂，通常在其表面上带有甲酸乙酯和3-氨基丙基的配体的官能化无机氧化物底物（例如硅胶） 三乙氧基硅烷 - 已与金属盐如CuCl 2反应。
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10.发明授权Dehydrogenation of N-paraffin to N-olefin employing manganese oxide octahedral molecular sieve as catalyst 失效使用氧化锰八面体分子筛作为催化剂将N-链烷烃脱氢为N-烯烃
公开(公告)号：US5597944A
公开(公告)日：1997-01-28
申请号：US335317
申请日：1994-11-07
CPC分类号： C07C5/3332 , C07C2523/34 , C07C2529/03
摘要： The dehydrogenation of n-parrofins to n-olefins is catalyzed by novel synthetic manganese oxide octahedral molecular sieves such as OMS-1 and OMS-2.
摘要翻译： 新型合成氧化锰八面体分子筛如OMS-1和OMS-2催化正烯烃脱氢为正烯烃。
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