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    Oil suspension concentrates based on a cyclohexenone oxime ether lithium salt and the use thereof as plant protection agents
    1.
    发明授权
    Oil suspension concentrates based on a cyclohexenone oxime ether lithium salt and the use thereof as plant protection agents 失效
    基于环己烯酮肟醚锂盐的油悬浮浓缩物及其作为植物保护剂的用途

    公开(公告)号：US06831041B2

    公开(公告)日：2004-12-14

    申请号：US10380120

    申请日：2003-03-11

    申请人： Reiner Kober ,  Rainer Berghaus ,  Thomas Kröhl ,  Hans Ziegler ,  Volker Maywald

    发明人： Reiner Kober ,  Rainer Berghaus ,  Thomas Kröhl ,  Hans Ziegler ,  Volker Maywald

    IPC分类号： A01N4318

    CPC分类号： A01N43/18 ,  A01N59/08 ,  A01N43/42 ,  A01N25/30 ,  A01N25/22 ,  A01N25/04 ,  A01N25/02 ,  A01N2300/00

    摘要： The present invention relates to oil suspension concentrates based on 2-{1-[2-(4-chlorophenoxy)propoxyimino]butyl}-3-hydroxy-5-(tetrahydrothiopyran-3-yl)cyclohex-2-enone lithium salt and certain formulation auxiliaries and to the use of the oil suspension concentrates as crop protection compositions and in particular as rice herbicides. Preferred formulation auxiliaries are mono- and/or dicarboxylic esters, for example fluid fatty acid esters, anionic surfactants of the sulfonate type, for example alkyl- and alkylarylsulfonates and also sulfosuccinates, and nonionic surfactants of the type of the nonethoxylated or ethoxylated carboxylic acids and esters of mono- or polyfunctional alcohols, for example ethoxylated fatty acids and polyoxyethylene sorbitan fatty acid esters. The oil suspension concentrates described herein are storage-stable and have excellent use properties.

    摘要翻译： 本发明涉及基于2- {1- [2-（4-氯苯氧基）丙氧基亚氨基]丁基} -3-羟基-5-（四氢噻喃-3-基）环己-2-烯酮锂盐的油悬液浓缩物和某些 制剂助剂以及油悬浮浓缩物作为作物保护组合物的用途，特别是作为水稻除草剂。 优选的制剂助剂是单酯和/或二羧酸酯，例如流化脂肪酸酯，磺酸盐型阴离子表面活性剂，例如烷基 - 和烷基芳基磺酸盐，以及磺基琥珀酸盐，以及非乙氧基化或乙氧基化羧酸类型的非离子表面活性剂， 单官能或多官能醇的酯，例如乙氧基化脂肪酸和聚氧乙烯脱水山梨糖醇脂肪酸酯。本文所述的油悬浮浓缩物是储存稳定的并且具有优异的使用性质。

    Cyclohexenone oxime ether/(glyphosates/gluphosinates) suspension concentrates
    5.
    发明授权
    Cyclohexenone oxime ether/(glyphosates/gluphosinates) suspension concentrates 有权
    环己烯酮肟醚/（草甘膦/草甘膦）悬浮浓缩物

    公开(公告)号：US06383987B1

    公开(公告)日：2002-05-07

    申请号：US09868072

    申请日：2001-08-02

    申请人： Jürgen von der Heyde ,  Reiner Kober ,  Matthias Bratz ,  Rainer Berghaus ,  Karl-Friedrich Jäger ,  Jürgen Fries ,  Adolf Parg

    发明人： Jürgen von der Heyde ,  Reiner Kober ,  Matthias Bratz ,  Rainer Berghaus ,  Karl-Friedrich Jäger ,  Jürgen Fries ,  Adolf Parg

    IPC分类号： A01N4380

    CPC分类号： A01N57/20 ,  A01N2300/00

    摘要： A substantially water-free formulation of crop protection agents, comprising essentially a) a cyclohexenone oxime ether of the formula I  where R1=ethyl, propyl; R2=hydrogen or an equivalent of an agriculturally useful cation; R3=2-(thioethyl)propyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-(methylthio)cyclopropyl, 5-(isopropyl)isoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl; R4, R5=H, CH3, CO—OCH3; Alk=CH2CH2, CH2CH(CH3), CH2CH═CH, CH2CH═C(Cl), CH2CH2CH═CH; R6=H, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy, dihalophenoxy; b) N-phosphonamethylglycine, or an ester or salt thereof, DL-homoalanin-4-yl(methyl)phosphinic acid or its ammonium salt; c) from 20 to 80% by weight of an aprotic or weakly protic solvent in which the components a) and b) are suspended; d) if desired emulsifiers, surfactants, surface-active and/or activity-enhancing auxiliaries, is described.

    摘要翻译： 基本上无水的作物保护剂制剂，其基本上包括式I的环己烯酮肟醚，其中R 1 =乙基，丙基; R 2 =氢或相当于农业上可用的阳离子; R 3 = 2-（硫代乙基）丙基，四氢噻喃 吡啶-3-基，四氢噻喃-4-基，四氢吡喃-3-基，四氢吡喃-4-基，1-（甲硫基）环丙基，5-（异丙基）异恶唑-3-基，2,5-二甲基吡唑-3-基 ，2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R4，R5 = H，CH3，CO-OCH3; Alk = CH2CH2，CH2CH（CH3），CH2CH = CH，CH2CH = C（ Cl），CH 2 CH 2 CH = CH; R 6 = H，苯基，卤代苯基，二卤代苯氧基，苯氧基，卤代苯氧基，二卤苯氧基; b）N-膦酰基甲基甘氨酸或其酯或盐，DL-高拉蛋白-4-基（甲基）次膦酸或其 铵盐; c）20至80重量％的非质子或弱质子溶剂，其中组分a）和b）悬浮; d）如果需要，乳化剂，表面活性剂，表面活性剂和/或活性增强助剂， 被描述。

    Agrotechnical formulation
    9.
    发明授权
    Agrotechnical formulation 失效
    农业制剂

    公开(公告)号：US06683030B2

    公开(公告)日：2004-01-27

    申请号：US10221201

    申请日：2002-09-10

    申请人： Reiner Kober ,  Matthias Bratz ,  Rainer Berghaus ,  Boris Breitscheidel

    发明人： Reiner Kober ,  Matthias Bratz ,  Rainer Berghaus ,  Boris Breitscheidel

    IPC分类号： A01N2502

    CPC分类号： A01N25/04 ,  A01N25/02 ,  A01N43/653 ,  A01N37/08 ,  A01N2300/00

    摘要： The present invention relates to an agrotechnical formulation which comprises, in each case based on the total weight of the formulation: a) 20 to 99.9% by weight of at least one cyclohexanepolycarboxylic ester of the formula I  in which R1 is C1-C10-alkyl or C3-C8-cycloalkyl; m is 0, 1, 2 or 3; and n is 2, 3 or 4; and R is H or C1-C30-alkyl, where at least one radical R is C1-C30-alkyl; b) 0 to 70% by weight of water; c) 0.1 to 60% by weight of at least one adjuvant and/or additive; and d) 0 to 70% by weight of at least one active ingredient for plant treatment.

    摘要翻译： 本发明涉及一种农业技术制剂，其在每种情况下基于制剂的总重量：a）20-99.9重量％的至少一种式Iin的环己烷多羧酸，其中R 1是C 1 -C 10 - 烷基或C 3 -C 8 - 环烷基; m为0,1,2或3; andn是2,3或4; 且R为H或C 1 -C 30烷基，其中至少一个基团R为C 1 -C 30 - 烷基; b）0至70重量％的水; c）0.1至60重量％的至少一种佐剂和/或 添加剂; andd）0至70重量％的用于植物处理的至少一种活性成分。

    Stable solid formulations of cyclohexenone oxime ether herbicides
    10.
    发明授权
    Stable solid formulations of cyclohexenone oxime ether herbicides 失效
    环己烯酮肟醚除草剂稳定的固体制剂

    公开(公告)号：US5981440A

    公开(公告)日：1999-11-09

    申请号：US913779

    申请日：1997-09-23

    申请人： Matthias Bratz ,  Karl-Friedrich Jager ,  Rainer Berghaus ,  Hans Ziegler

    发明人： Matthias Bratz ,  Karl-Friedrich Jager ,  Rainer Berghaus ,  Hans Ziegler

    IPC分类号： A01N25/12 ,  A01N25/22 ,  A01N35/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/76 ,  A01N43/56 ,  A01N37/00 ,  A01N43/02

    CPC分类号： A01N35/10 ,  A01N25/12 ,  A01N43/16 ,  A01N43/18

    摘要： Crop protection active compound formulations, comprising a cyclohexenone oxime ether of the general formula I ##STR1## where the radicals R.sup.1 -R.sup.6 have the following meanings: R.sup.1 is ethyl or propyl;R.sup.2 is hydrogen or an equivalent of an agriculturally utilizable cation;R.sup.3 is 2-thioethylpropyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-methylthiocyclopropyl, 5-isopropylisoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl;R.sup.4 and R.sup.5 independently of one another are hydrogen, methyl or methoxycarbonyl;Alk is CH.sub.2 CH.sub.2, CH.sub.2 CH(CH.sub.3), CH.sub.2 CH.dbd.CH, CH.sub.2 CH.dbd.C(Cl) or CH.sub.2 CH.sub.2 CH.dbd.CH;R.sup.6 is hydrogen, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy or dihalophenoxy;and a water-soluble basic salt of an acid having a pK.sub.a of greater than 5, alkali metal hydroxides and alkali metal carbonates being excluded, their preparation and use as herbicides are described.

    摘要翻译： PCT No.PCT / EP96 / 01046 Sec。 371日期1997年9月23日 102（e）1997年9月23日PCT 1996年3月12日PCT公布。 公开号WO96 / 29869 日期1996年10月3日保护活性化合物制剂，其包含通式I的环己烯酮肟醚，其中基团R 1 -R 6具有以下含义：R 1是乙基或丙基; R2是氢或相当于农业上可用的阳离子; R 3是2-硫代乙基丙基，四氢噻喃-3-基，四氢噻喃-4-基，四氢吡喃-3-基，四氢吡喃-4-基，1-甲硫基环丙基，5-异丙基异恶唑-3-基，2,5-二甲基吡唑-3-基， 2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R 4和R 5彼此独立地是氢，甲基或甲氧基羰基; Alk是CH 2 CH 2，CH 2 CH（CH 3），CH 2 CH = CH，CH 2 CH = C（Cl）或CH 2 CH 2 CH = CH; R6是氢，苯基，卤代苯基，二卤代苯基，苯氧基，卤代苯氧基或二卤代苯氧基; 和pKa大于5的酸的水溶性碱性盐，不包括碱金属氢氧化物和碱金属碳酸盐，它们作为除草剂的制备和用途被描述。