摘要:
A battery health monitor (BHM) that operates as a battery-mountable full-spectrum alternating current (ac) impedance meter that facilitates monitoring a state-of-charge and a state-of-health of a battery. The BHM is used for monitoring one or more electrical parameters, e.g., impedance, of a battery. The BHM includes: a current sink coupled to the first terminal and configured to sink therefrom an oscillatory current so as to cause the battery to produce at a first terminal thereof an oscillatory voltage equal to or less than a dc operating voltage of the battery that would be present at the first terminal in the absence of the oscillatory current; and a voltage sensor configured to sense the oscillatory voltage at the first terminal.
摘要:
An embeddable corrosion rate meter (ECRM) for detecting and measuring corrosion in metal and concrete structures is provided. The system comprises an electrochemical cell with at least one working electrode evenly separated from a counter electrode, wherein a separation distance between electrodes determines an electrolyte medium resistance and the electrolyte medium resistance is less than or equal to a polarization resistance. The system further includes a signal generator connected to a plurality of resistances for creating a plurality of current amplitudes for generating a current source; a first selector for applying a current through each of the plurality of resistances to the working electrode and counter electrode; a second selector for selecting a duration of a current pulse; a voltmeter/A-D converter having an input impedance >109 ohms for measuring polarization of the working electrode; and an external reader-head with a data link and power link connected to a computing device for powering the system and collecting corrosion measurements data.
摘要:
Methods and systems to determine an internal temperature of a rechargeable lithium-ion cell based on a phase shift of the cell. Internal cell temperature may be determined with respect to an internal anode temperature and/or an internal cathode temperature. Internal anode temperature may be determined based on a phase shift of a frequency within a range of approximately 40 Hertz (Hz) to 500 Hz. Internal cathode temperature may be determined based on a phase shift of a frequency of up to approximately 30 Hz. A temperature sensor as disclosed herein may be powered by a monitored cell with relatively little impact on cell charge, may be electrically coupled to cell but housed physically separate from the cell, and/or may monitor multiple cells in a multiplex fashion. A rate of change in phase shift may be used to initiate pre-emptive action, without determining corresponding temperatures.
摘要:
Methods and systems to determine an internal temperature of a rechargeable lithium-ion cell based on a phase shift of the cell. Internal cell temperature may be determined with respect to an internal anode temperature and/or an internal cathode temperature. Internal anode temperature may be determined based on a phase shift of a frequency within a range of approximately 40 Hertz (Hz) to 500 Hz. Internal cathode temperature may be determined based on a phase shift of a frequency of up to approximately 30 Hz. A temperature sensor as disclosed herein may be powered by a monitored cell with relatively little impact on cell charge, may be electrically coupled to cell but housed physically separate from the cell, and/or may monitor multiple cells in a multiplex fashion. A rate of change in phase shift may be used to initiate pre-emptive action, without determining corresponding temperatures.
摘要:
Provided are methods of producing an electrode capable of binding an analyte thereto comprising: providing a substrate capable of binding a dithiol molecule thereto; electrochemically treating the substrate using cyclic voltammetry to provide a treated substrate having a fractal dimension of greater than about 2; and contacting the treated substrate with dithiol molecules to produce an electrode having dithiol groups attached thereto and capable of binding an analyte to be detected thereto. Also provided are methods of accumulating and detecting analytes using the electrodes produced via the methods of the present invention.
摘要:
A method for inhibiting corrosion, e.g., pitting corrosion, of alloys is provided. Particularly, the method comprises contacting at least a portion of a surface of the alloy with an aqueous solution comprising a salt of one or more rare earth elements selected from the group consisting of yttrium, gadolinium, cerium, europium, terbium, samarium, neodymium, praseodymium, lanthanum, holmium, ytterbium, dysprosium and erbium; and establishing a voltage differential between an anode comprising the alloy and a cathode in the solution at an effective level and for a sufficient period of time wherein a rare earth element oxide-containing coating is formed on the surface of the alloy to inhibit corrosion thereof.
摘要:
A methanol-air fuel cell consisting of a stack of sub-fuel cells, each sub-fuel cell comprising a proton conducting polymer membrane, with each membrane having an array of 1-cm2-anode unit cells on one side and an array of cathode unit cells on the other. A thin polymer film, with openings for the unit cells and plated with pre-patterned lines of electrical leads, is placed on each side of the membrane to collect the current from each unit cell. A polymer fuel-feed plate is placed on the thin polymer film on each side of the membrane to feed methanol and oxygen to the electrodes.
摘要:
Numerical techniques such as the finite element method (FEM) are used to model the current and voltage distribution in concrete structures such as bridges. The geometric arrangement of groundbeds and the ideal locations for the electrical contacts vis-a-vis the geometry of the bridge and the rebars can thereby be predicted and a cathodic protection (CP) system for the bridge designed. A magnetic sensor is used to sense the magnetic field generated by the CP current, and a voltmeter or an oscilloscope to measure the output of the magnetic sensor. A current interrupter is also used to interrupt the CP current at the source. The current is mapped by placing the magnetic sensor on or above the concrete surface. By moving the sensor from one location to another, the current is mapped over the entire structure. To achieve uniform distribution over the entire structure, an “expert” CP system controlled by a variety of current and environmental sensors and a dedicated microprocessor is described.
摘要:
The invention is directed to an apparatus and method for locating objects in a body through the mapping and imaging of the conductivity profiles of such objects by applying a force to the object and/or body and measuring certain characteristics of the body responsive to the application of force. In accordance with a preferred embodiment, the force applied to the object and body is in the form of an electrical voltage or current such that electrical potentials, currents, and magnetic fields are generated throughout the subsurface site. The voltage, current, or magnetic field is then measured at the surface or the boundary of the body. An estimate of subsurface conductivity is then made and a conductivity profile generated by minimizing a loss function. Preferably, the loss function is in the form of the sum square of the differences between measurement values and a set of computed values based on a gradient approximation technique. In a preferred embodiment, the approximation technique is a simultaneous perturbation stochastic approximation (SPSA). To characterize the object within the body, a conductivity profile is then constructed using a numerical technique such as a finite element method (FEM) to compute the potentials or magnetic fields along with the experimental values measured at the boundary of the site. The characterization of the object includes its location, size, and conductivity.
摘要:
A battery health monitor (BHM) that operates as a battery-mountable full-spectrum alternating current (ac) impedance meter that facilitates monitoring a state-of-charge and a state-of-health of a battery. The BHM is used for monitoring one or more electrical parameters, e.g., impedance, of a battery. The BHM includes: a current sink coupled to the first terminal and configured to sink therefrom an oscillatory current so as to cause the battery to produce at a first terminal thereof an oscillatory voltage equal to or less than a dc operating voltage of the battery that would be present at the first terminal in the absence of the oscillatory current; and a voltage sensor configured to sense the oscillatory voltage at the first terminal.