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公开(公告)号：US4285794A
公开(公告)日：1981-08-25
申请号：US122706
申请日：1980-02-19
CPC分类号： H01M8/04276 , C25B15/06 , H01M2/40
摘要： Shunt currents can be eliminated in electrochemical devices by introducing nulling currents via auxilary electrodes. In electrochemical devices including those having a circulating electrolyte, such electrodes are designed to have a generally annular shape in order to provide a substantially uniform current density profile along a common electrolyte carrying manifold. The uniform current density profile allows for the elimination of these harmful shunt currents with a minimum of power consumption.
摘要翻译： 在电化学装置中可以通过辅助电极引入零电流来消除并联电流。 在包括具有循环电解质的电化学装置中，这样的电极被设计成具有大致环形的形状，以便沿着共同的电解质携带歧管提供基本均匀的电流密度分布。 均匀的电流密度分布允许以最小功耗消除这些有害分流电流。
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公开(公告)号：US4259417A
公开(公告)日：1981-03-31
申请号：US128822
申请日：1980-03-10
CPC分类号： H01M2/1653 , H01M10/365 , H01M6/24 , H01M2300/0002
摘要： The invention features an electrochemical cell having two fluid-containing compartments separated by a nonselective microporous membrane. Select ions which would normally pass through the membrane under the influence of an ionic field, are prevented from passing through the membrane by a polyelectrolyte which has migrated through the compartment fluid to the membrane. The polyelectrolyte acts as an ionic barrier to the passage of select ions, thus effectively increasing the ion-selective capability of the membrane and, hence, the coulombic efficiency of the electrochemical cell.
摘要翻译： 本发明的特征在于电化学电池具有由非选择性微孔膜隔开的两个含有流体的隔室。 通过在离子场的影响下通常通过膜的离子被防止通过已经通过隔室流体迁移到膜的聚电解质通过膜。 聚电解质作为选择离子通过的离子屏障，从而有效地提高了膜的离子选择能力，从而提高了电化学电池的库仑效率。
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公开(公告)号：US4379814A
公开(公告)日：1983-04-12
申请号：US268674
申请日：1981-06-01
CPC分类号： H01M8/246 , H01M10/365 , H01M8/02 , H01M8/0213 , H01M8/0273 , H01M8/0289
摘要： An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.
摘要翻译： 电化学电池结构具有新颖的共挤塑料电极，其具有新颖的整体隔板间隔物。 另外还有一种防泄漏和防冲击的结构，用于防止在发生破裂的情况下溢出腐蚀性物质。
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公开(公告)号：US4346150A
公开(公告)日：1982-08-24
申请号：US268675
申请日：1981-06-01
IPC分类号： C25B9/20 , H01M2/02 , H01M2/18 , H01M4/64 , H01M8/02 , H01M8/24 , H01M10/36 , H01M4/00 , H01M8/00
CPC分类号： H01M8/246 , C25B9/20 , H01M10/365 , H01M2/025 , H01M2/18 , H01M4/64 , H01M8/02 , H01M8/0213 , H01M8/0273 , H01M8/0289
摘要： An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.
摘要翻译： 电化学电池结构具有新颖的共挤塑料电极，其具有新颖的整体隔板间隔物。 另外还有一种防泄漏和防冲击的结构，用于防止在发生破裂的情况下溢出腐蚀性物质。
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5.发明授权Hydrogen production using electrochemical reforming and electrolyte regeneration 有权使用电化学重整和电解质再生的氢气生产公开(公告)号：US08318130B2
公开(公告)日：2012-11-27
申请号：US11922549
申请日：2006-06-23
IPC分类号： C01B3/02
CPC分类号： C01B3/323 , B01J3/04 , B01J8/025 , B01J8/0285 , B01J8/22 , B01J8/222 , B01J8/226 , B01J19/2485 , B01J2208/00203 , B01J2208/00212 , B01J2208/00407 , B01J2208/00415 , B01J2219/00006 , B01J2219/00029 , B01J2219/00033 , B01J2219/0009 , B01J2219/00094 , B01J2219/00135 , C01B2203/86 , C01D7/10 , Y02E60/324 , Y02E60/366 , Y02P30/30
摘要： A process, preferably continuous, for producing hydrogen gas comprising contacting in the liquid phase at least one oxidizable organic substance in the presence of a mixture comprising at least one conductive catalyst and an aqueous alkaline carbonate electrolyte, wherein at least one bicarbonate composition produced by reaction of the electrolyte is regenerated and the at least one oxidizable organic substance comprises a oxygenated hydrocarbon, for example methanol and/or dimethyl ether. In a preferred embodiment the alkaline electrolyte is regenerated using steam. Various advantageous reaction schemes are described, utilizing, e.g., co-current and countercurrent stream flow and alternative tower sequence arrangements.
摘要翻译： 一种用于生产氢气的方法，优选是连续的，包括在含有至少一种导电催化剂和碱性碳酸钙水溶液的混合物的存在下，在液相中接触至少一种可氧化有机物质，其中至少一种通过反应生成的碳酸氢盐组合物 的电解质被再生，并且所述至少一种可氧化有机物质包含氧化烃，例如甲醇和/或二甲醚。 在优选的实施方案中，使用蒸汽再生碱性电解质。 描述了各种有利的反应方案，利用例如并流和逆流流和替代的塔序列排列。
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公开(公告)号：US4365009A
公开(公告)日：1982-12-21
申请号：US178993
申请日：1980-08-18
CPC分类号： H01M6/24 , H01M10/365 , H01M2/1653 , H01M2300/0002
摘要： The invention features an electrochemical cell having two fluid-containing compartments separated by a non-selective microporous membrane. Select ions which would normally pass through the membrane under the influence of an ionic field, are prevented from passing through the membrane by a polyelectrolyte which has migrated through the compartment fluid to the membrane. The polyelectrolyte acts as an ionic barrier to the passage of select ions, thus effectively increasing the ion-selective capability of the membrane and, hence, the coulombic efficiency of the electro-chemical cell.
摘要翻译： 本发明的特征在于具有由非选择性微孔膜分离的两个含液体室的电化学电池。 通过在离子场的影响下通常通过膜的离子被防止通过已经通过隔室流体迁移到膜的聚电解质通过膜。 聚电解质作为选择离子通过的离子屏障，从而有效地提高了膜的离子选择能力，从而提高了电化学电池的库仑效率。
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公开(公告)号：US4718997A
公开(公告)日：1988-01-12
申请号：US821758
申请日：1986-01-23
CPC分类号： H01M8/0273 , C25B9/066 , C25B9/18 , H01M10/365 , H01M8/24
摘要： A tunnel protected electrochemical device features channels fluidically communicating between manifold, tunnels and cells. The channels are designed to provide the most efficient use of auxiliary power. The channels have a greater hydraulic pressure drop and electrical resistance than the manifold. This will provide a design with the optimum auxiliary energy requirements.
摘要翻译： 隧道保护的电化学装置具有在歧管，隧道和电池之间流体连通的通道。 通道设计为提供最有效的辅助电源。 通道具有比歧管更大的液压压降和电阻。 这将提供具有最佳辅助能量要求的设计。
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公开(公告)号：US4312735A
公开(公告)日：1982-01-26
申请号：US160143
申请日：1980-06-16
CPC分类号： H01M2/40 , C25B15/06 , H01M8/04276
摘要： Shunt currents can be eliminated in electrochemical devices by introducing nulling currents via auxiliary electrodes. The invention teaches the reduction or elimination of these shunt currents in such devices with minimized power consumption. Shunt current nulling tunnels are provided which interconnect with electrolyte supply channels feeding the cells of the electrochemical device. Power consumption for the shunt current-nulling tunnels is reduced by designing the tunnels to have an increasing electrical resistance towards their mid-portions. Another embodiment of the invention features an increasing electrical resistance towards the mid-portion of the tunnels and a decreasing electrical resistance towards the mid-portion of the manifolds.
摘要翻译： 通过辅助电极引入零电流，可以在电化学装置中消除分流电流。 本发明教导了以最小的功率消耗减少或消除这些器件中的这些并联电流。 提供分流电流零通道，其与供给电化学装置的电池的电解质供应通道相互连接。 通过设计隧道以对其中间部分具有增加的电阻来减小分流电流 - 零通道的功率消耗。 本发明的另一个实施例的特征在于朝着隧道中部的电阻增加，并且朝向歧管中部的电阻减小。
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公开(公告)号：US4396689A
公开(公告)日：1983-08-02
申请号：US268665
申请日：1981-06-01
CPC分类号： C25B13/02 , H01M2/18 , H01M8/0213 , H01M8/0273 , H01M8/0289
摘要： An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.
摘要翻译： 电化学电池结构具有新颖的共挤塑料电极，其具有新颖的整体隔板间隔物。 另外还有一种防泄漏和防冲击的结构，用于防止在发生破裂的情况下溢出腐蚀性物质。
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公开(公告)号：US4279732A
公开(公告)日：1981-07-21
申请号：US122193
申请日：1980-02-19
CPC分类号： H01M2/40 , H01M8/04276
摘要： Shunt currents can be eliminated in electrochemical devices by introducing nulling currents via auxiliary electrodes. In electrochemical devices including those having a circulating electrolyte, such electrodes are designed to have a generally annular shape in order to provide a substantially uniform current density profile along a common electrolyte carrying manifold. The uniform current density profile allows for the elimination of these harmful shunt currents with a minimum of power consumption.
摘要翻译： 通过辅助电极引入零电流，可以在电化学装置中消除分流电流。 在包括具有循环电解质的电化学装置中，这样的电极被设计成具有大致环形的形状，以便沿着共同的电解质携带歧管提供基本均匀的电流密度分布。 均匀的电流密度分布允许以最小功耗消除这些有害分流电流。
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