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公开(公告)号：US20090171059A1
公开(公告)日：2009-07-02
申请号：US11968622
申请日：2008-01-02
IPC分类号： C08G18/70
CPC分类号： C08G18/758 , C08G18/10 , C08G18/12 , C08G18/4277 , C08G18/4854 , C08G18/5024 , C08G18/6685 , C08G18/664 , C08G18/6677 , C08G18/6674 , C08G18/6651 , C08G18/324
摘要： The present invention teaches a new process to produce novel, hard, optically clear, impact-resistant polyurethane polymers that are characterized by excellent thermo mechanical properties and chemical resistance, and the polymers made as a result of such a process.The polyurethanes are made by reacting a) a prepolymer made by reacting a polyisocyanate with a primary amine-terminated polyether with an amine functionality of about 2 and a molecular weight of >1000, and in which the free —NCO content of the resulting prepolymer is >18% by weight; with b) (i) a polyol having an average hydroxyl functionality greater than 2 and an average hydroxyl equivalent weight of from about 400 to about 1,000, and (ii) a curing agent that has isocyanate reactive groups, a functionality of 2 to 3 and a molecular weight of
摘要翻译： 本发明教导了一种新的制造新颖的，硬的，光学透明的耐冲击聚氨酯聚合物的新方法，其特征在于优异的热机械性能和耐化学性，以及由于这种方法制成的聚合物。 聚氨酯通过使a）通过使多异氰酸酯与胺官能度为约2，分子量> 1000的伯胺封端的聚醚反应制备的预聚物制备，其中所得预聚物的游离-NCO含量为 > 18重量％ 其中b）（i）平均羟基官能度大于2且平均羟基当量为约400至约1,000的多元醇，和（ii）具有异氰酸酯反应性基团，官能度为2至3的固化剂和 分子量<400。 更优选地，预聚物通过使脂环族多异氰酸酯与2000至4000分子量的伯胺封端的聚醚二胺反应制得，多元醇是分子量为约540至900的聚酯多元醇三醇，或聚醚二醇与 分子量在约650和2000之间，并且固化剂是二羟基己糖醇，芳族二胺或环己烷二甲醇。
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公开(公告)号：US4883906A
公开(公告)日：1989-11-28
申请号：US125139
申请日：1987-11-25
IPC分类号： C07C67/343 , B01D20060101 , B01J20060101 , B01J23/04 , B01J31/02 , C07B61/00 , C07C67/44 , C07C67/54 , C07C69/28
CPC分类号： C07C67/44
摘要： A process for producing and refining trisubstituted glycol monoesters, e.g., 2,2,4-trimethyl-1,3-pentanediol monoester. The improvement resides in immediately distilling the crude condensation product mixture as it leaves the reactor before it has cooled or had any contact with added water.
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公开(公告)号：US20090171060A1
公开(公告)日：2009-07-02
申请号：US11971843
申请日：2008-01-09
IPC分类号： C08G18/00
CPC分类号： C08G18/758 , C08G18/10 , C08G18/12 , C08G18/3212 , C08G18/3218 , C08G18/4277 , C08G18/4854 , C08G18/5024 , C08G2120/00 , C08G18/6674 , C08G18/6651 , C08G18/6685 , C08G18/324
摘要： The present invention teaches a new process to produce novel, hard, optically clear, impact-resistant polyurethane polymers that are characterized by excellent thermo mechanical properties and chemical resistance, and the polymers made as a result of such a process.The polyurethanes are made by reactinga) a prepolymer made by reacting a polyisocyanate with a primary amine-terminated polyether with an amine functionality of about 2 and a molecular weight of >1000, and in which the free —NCO content of the resulting prepolymer is >18% by weight; withb) (i) a polyol having an average hydroxyl functionality greater than or equal to 2 and an average hydroxyl equivalent weight of from about 300 to about 1,000, and (ii) a curing agent that has isocyanate reactive groups, a functionality of 2 to 3 and a molecular weight of
摘要翻译： 本发明教导了一种新的制造新颖的，硬的，光学透明的耐冲击聚氨酯聚合物的新方法，其特征在于优异的热机械性能和耐化学性，以及由于这种方法制成的聚合物。 聚氨酯通过使a）通过使多异氰酸酯与胺官能度为约2，分子量> 1000的伯胺封端的聚醚反应制备的预聚物制备，其中所得预聚物的游离-NCO含量为 > 18重量％ 其中b）（i）平均羟基官能度大于或等于2且平均羟基当量重量为约300至约1,000的多元醇，和（ii）具有异氰酸酯反应性基团的官能度为2 至3，分子量<400。 更优选地，预聚物通过使脂环族多异氰酸酯与2000至约2500分子量的伯胺封端的聚醚二胺反应制得，多元醇是分子量为约540至900的聚酯多元醇三醇或聚醚二醇 分子量为约650和2000之间的聚酯多元醇二元醇或分子量高达2,000的聚酯多元醇二醇，固化剂为二羟基己糖醇，芳族二胺，含芳族环的二醇或环己烷二甲醇。
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4.发明授权Supercritical ratio control system utilizing a sonic flow venturi and an air-driven positive displacement pump 失效利用声流文丘里管和空气驱动容积式泵的超临界比控制系统
公开(公告)号：US5304390A
公开(公告)日：1994-04-19
申请号：US906705
申请日：1992-06-30
CPC分类号： B01F15/0412 , B05B12/1418 , B05B7/32 , B05D1/025 , B05D2401/90 , Y10T137/0329 , Y10T137/0368
摘要： A process for delivering a predetermined ratio of a compressible fluid and a non-compressible fluid which comprises the measurement of only the flowrate of the compressible fluid, the activation of an air-driven positive displacement pump at appropriate times, the pumping of a non-compressible fluid with the air-driven pump, mixing the supercritical fluid and non-compressible fluid and depositing the mixture onto a substrate.
摘要翻译： 一种用于输送可压缩流体和不可压缩流体的预定比率的方法，其包括仅测量可压缩流体的流量，在适当时间激活空气驱动的容积式泵， 可空气驱动泵的可压缩流体，混合超临界流体和不可压缩流体并将混合物沉积到基底上。
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公开(公告)号：US4882107A
公开(公告)日：1989-11-21
申请号：US276162
申请日：1988-11-23
IPC分类号： B05D1/02 , B29C33/58 , B29C33/60 , B29K75/00 , B29K105/04
CPC分类号： B29C33/58 , B05D1/025 , B29C33/60 , B05D2401/90 , Y10S264/83
摘要： A process which comprises (i) the generation of release surfaces by application to predetermined areas of a solid surface of a solution, suspension or dispersion of a release agent and a supercritical fluid that vaporizes from the release agent, (ii) the deposition of a mass onto the release surface containing the release agent, and (iii) the separation of the mass or a product derived from the mass from such surface covered by the release agent. Novel apparatus for carrying out the process are described.
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公开(公告)号：US06265456B1
公开(公告)日：2001-07-24
申请号：US09417539
申请日：1999-10-13
IPC分类号： C08J904
CPC分类号： C08J9/0061 , C08G77/38 , C08G77/46 , C08J2375/04 , C08J2491/00
摘要： An improved process is provided for the preparation of siloxane-oxyalkylene and siloxane-alkyl copolymer compositions via a hydrosilation reaction in the presence of high boiling point natural vegetable oils as the reaction solvent. The reaction solvent need not be removed from the block copolymer product, and indeed is beneficial to remain with the copolymer particularly when the copolymer is used as a surfactant for polyurethane foam formulations. Soybean oil and linseed oil are the preferred high boiling natural oil solvents when the copolymer product is to be used in the preparation of the surfactants for polyurethane foams. High resiliency polyurethane foam prepared with these natural oils present in the surfactant preparation afforded improved compression sets, wet compression sets and humid aged compression sets. Additionally, the use of the surfactants made with natural oils as a reaction solvent or consequently surfactants post diluted with natural oils when employed in the preparation of polyurethane foam afforded foams with greatly reduced amounts of “glass fogging”.
摘要翻译： 提供了一种改进的方法，用于在作为反应溶剂的高沸点天然植物油存在下，通过氢硅化反应制备硅氧烷 - 氧化烯和硅烷 - 烷基共聚物组合物。 反应溶剂不需要从嵌段共聚物产物中除去，实际上有利于保留共聚物，特别是当该共聚物用作聚氨酯泡沫制剂的表面活性剂时。 当共聚物产品用于制备用于聚氨酯泡沫的表面活性剂时，大豆油和亚麻籽油是优选的高沸点天然油溶剂。 使用表面活性剂制剂中存在的这些天然油制备的高弹性聚氨酯泡沫可提供改进的压缩套，湿压缩套和湿老化压缩套。 另外，当用于制备聚氨酯泡沫时，用天然油制成的表面活性剂作为反应溶剂或随后用天然油稀释后的表面活性剂的使用提供了大量减少量的“玻璃雾化”的泡沫体。
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公开(公告)号：US06071977A
公开(公告)日：2000-06-06
申请号：US742192
申请日：1996-10-31
IPC分类号： C08J9/02 , C08F283/12 , C08G18/83 , C08G77/06 , C08G77/12 , C08G77/38 , C08G77/46 , C08J9/00 , C08L83/05 , C08J9/04
CPC分类号： C08J9/0061 , C08G77/38 , C08G77/46 , C08J2375/04 , C08J2491/00
摘要： An improved process is provided for the preparation of siloxane-oxyalkylene and siloxane-alkyl copolymer compositions via a hydrosilation reaction in the presence of high boiling point natural vegetable oils as the reaction solvent. The reaction solvent need not be removed from the block copolymer product, and indeed is beneficial to remain with the copolymer particularly when the copolymer is used as a surfactant for polyurethane foam formulations. Soybean oil and linseed oil are the preferred high boiling natural oil solvents when the copolymer product is to be used in the preparation of the surfactants for polyurethane foams. High resiliency polyurethane foam prepared with these natural oils present in the surfactant preparation afforded improved compression sets, wet compression sets and humid aged compression sets. Additionally, the use of the surfactants made with natural oils as a reaction solvent or consequently surfactants post diluted with natural oils when employed in the preparation of polyurethane foam afforded foams with greatly reduced amounts of "glass fogging".
摘要翻译： 提供了一种改进的方法，用于在作为反应溶剂的高沸点天然植物油存在下，通过氢硅化反应制备硅氧烷 - 氧化烯和硅烷 - 烷基共聚物组合物。 反应溶剂不需要从嵌段共聚物产物中除去，实际上有利于保留共聚物，特别是当该共聚物用作聚氨酯泡沫制剂的表面活性剂时。 当共聚物产品用于制备用于聚氨酯泡沫的表面活性剂时，大豆油和亚麻籽油是优选的高沸点天然油溶剂。 使用表面活性剂制剂中存在的这些天然油制备的高弹性聚氨酯泡沫可提供改进的压缩套，湿压缩套和湿老化压缩套。 另外，当用于制备聚氨酯泡沫时，用天然油制成的表面活性剂作为反应溶剂或随后用天然油稀释后的表面活性剂的使用提供了大量减少量的“玻璃雾化”的泡沫体。
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公开(公告)号：US4541836A
公开(公告)日：1985-09-17
申请号：US448280
申请日：1982-12-09
申请人： Edmond J. Derderian
发明人： Edmond J. Derderian
CPC分类号： C10L1/023
摘要： A phase-stable aqueous gasoline/ethanol fuel composition containing an additional alcohol selected from the group consisting of n-butanol, 2-butanol, iso-butanol, 2-methyl-1-butanol, 3-methyl-1-butanol, n-pentanol, and mixtures thereof, as well as a method for producing said fuel composition.
摘要翻译： 含有选自正丁醇，2-丁醇，异丁醇，2-甲基-1-丁醇，3-甲基-1-丁醇，正丁醇，正丁醇，正丁醇， 戊醇及其混合物，以及生产所述燃料组合物的方法。
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