公开(公告)号：US20050006042A1

公开(公告)日：2005-01-13

申请号：US10438117

申请日：2003-05-14

申请人： Richard Riehle ,  Anthony Allen ,  Michaela Hofbauer ,  Alfred Haandrikman ,  Ronald Busink ,  Mark Crisp ,  John Hoglen ,  Huai Cheng ,  Francis Carlin ,  John Lapre ,  Harold Jabloner

发明人： Richard Riehle ,  Anthony Allen ,  Michaela Hofbauer ,  Alfred Haandrikman ,  Ronald Busink ,  Mark Crisp ,  John Hoglen ,  Huai Cheng ,  Francis Carlin ,  John Lapre ,  Harold Jabloner

IPC分类号： C08G69/48 ,  C08G73/02 ,  D21H17/52 ,  D21H17/55 ,  D21H17/56 ,  D21H27/08 ,  D21H27/10

CPC分类号： D21H17/55 ,  C08G73/022 ,  C08G73/0286 ,  D21H17/56 ,  D21H27/08 ,  D21H27/10

摘要： Processes for rendering a polyamine-epihalohydrin resin storage stable, including processes that prepare a storage stable resin and/or processes that treat resins. A composition containing a polyamine-epihalohydrin resin which includes CPD-forming species can be treated with at least one agent under conditions to at least one of inhibit, reduce and remove the CPD-forming species to obtain a reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin when stored for 2 weeks at 50° C., and a pH of about 2.5 to 3.5 contains less than about 250 ppm dry basis of CPD. The invention is also directed to a gelation storage stable reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin, when stored at pH 1 for 24 hours at 50° C. and measured at 24 hours, produces less than about 1000 ppm dry basis of CPD. A paper product containing the storage stable polyaminopolyamide-epihalohydrin resin, when corrected for adding at about a 1 wt % addition level of the polyaminopolyamide-epihalohydrin resin, contains less than about 250 ppb of CPD. Moreover, a resin can be prepared starting from a prepolymer having a low acid number or low concentration of acid end groups. The invention is also directed to papers containing the resins.

摘要翻译： 使多胺 - 表卤代醇树脂保存稳定的方法，包括制备储存稳定树脂的方法和/或处理树脂的方法。 包含CPD形成物质的含有多胺 - 表卤醇树脂的组合物可以在至少一种抑制，减少和除去CPD形成物质的条件下用至少一种试剂处理，以获得减少的CPD形成树脂，使得 含有减少的形成CPD的多胺 - 表卤代醇树脂的组合物在50℃下储存2周时，pH约2.5-3.5含有低于约250ppm干基的CPD。 本发明还涉及一种凝胶储存稳定的减少CPD形成树脂，使得含有减少的形成CPD的多胺 - 表卤代醇树脂的组合物在50℃下储存24小时并在24小时时测量时产生 小于约1000ppm的干燥基础的CPD。 含有储存稳定的聚氨基多酰胺 - 表卤代醇树脂的纸产品在校正后加入多氨基聚酰胺 - 表卤代醇树脂的约1重量％时含有小于约250ppb的CPD。 此外，可以从具有低酸值或低浓度酸端基的预聚物开始制备树脂。 本发明还涉及含有树脂的纸张。

公开(公告)号：US20070137821A1

公开(公告)日：2007-06-21

申请号：US11645968

申请日：2006-12-27

申请人： Richard Riehle ,  Anthony Allen ,  Michaela Hofbauer ,  Alfred Haandrikman ,  Ronald Busink ,  Mark Crisp ,  John Hoglen ,  Huai Cheng ,  Francis Carlin ,  John Lapre ,  Harold Jabloner

发明人： Richard Riehle ,  Anthony Allen ,  Michaela Hofbauer ,  Alfred Haandrikman ,  Ronald Busink ,  Mark Crisp ,  John Hoglen ,  Huai Cheng ,  Francis Carlin ,  John Lapre ,  Harold Jabloner

IPC分类号： D21H19/30 ,  C08G69/48

CPC分类号： D21H17/55 ,  C08G73/022 ,  C08G73/0286 ,  D21H17/56 ,  D21H27/08 ,  D21H27/10

摘要： Processes for rendering a polyamine-epihalohydrin resin storage stable, including processes that prepare a storage stable resin and/or processes that treat resins. A composition containing a polyamine-epihalohydrin resin which includes CPD-forming species can be treated with at least one agent under conditions to at least one of inhibit, reduce and remove the CPD-forming species to obtain a reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin when stored for 2 weeks at 50° C., and a pH of about 2.5 to 3.5 contains less than about 250 ppm dry basis of CPD. The invention is also directed to a gelation storage stable reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin, when stored at pH 1 for 24 hours at 50° C. and measured at 24 hours, produces less than about 1000 ppm dry basis of CPD. A paper product containing the storage stable polyaminopolyamide-epihalohydrin resin, when corrected for adding at about a 1 wt % addition level of the polyaminopolyamide-epihalohydrin resin, contains less than about 250 ppb of CPD. Moreover, a resin can be prepared starting from a prepolymer having a low acid number or low concentration of acid end groups. The invention is also directed to papers containing the resins.

摘要翻译： 使多胺 - 表卤代醇树脂保存稳定的方法，包括制备储存稳定树脂的方法和/或处理树脂的方法。 包含CPD形成物质的含有多胺 - 表卤醇树脂的组合物可以在至少一种抑制，减少和除去CPD形成物质的条件下用至少一种试剂处理，以获得减少的CPD形成树脂，使得 含有减少的形成CPD的多胺 - 表卤代醇树脂的组合物在50℃下储存2周时，pH约2.5-3.5含有低于约250ppm干基的CPD。 本发明还涉及一种凝胶储存稳定的减少CPD形成树脂，使得含有减少的形成CPD的多胺 - 表卤代醇树脂的组合物在50℃下储存24小时并在24小时时测量时产生 小于约1000ppm的干燥基础的CPD。 含有储存稳定的聚氨基多酰胺 - 表卤代醇树脂的纸产品在校正后加入多氨基聚酰胺 - 表卤代醇树脂的约1重量％时含有小于约250ppb的CPD。 此外，可以从具有低酸值或低浓度酸端基的预聚物开始制备树脂。 本发明还涉及含有树脂的纸张。