公开(公告)号：US08790793B2

公开(公告)日：2014-07-29

申请号：US12463250

申请日：2009-05-08

申请人： Noriko Yasukawa ,  Hiroshi Kita ,  Eisaku Katoh ,  Tatsuo Tanaka ,  Shinya Otsu ,  Rie Katakura ,  Hidekane Ozeki ,  Hideo Taka

发明人： Noriko Yasukawa ,  Hiroshi Kita ,  Eisaku Katoh ,  Tatsuo Tanaka ,  Shinya Otsu ,  Rie Katakura ,  Hidekane Ozeki ,  Hideo Taka

IPC分类号： H01L51/50 ,  C09K11/06

CPC分类号： C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/006 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5048 ,  H05B33/14 ,  Y10S428/917

摘要： Provided is an organic electroluminescent element comprising a substrate having thereon an anode, a cathode, and a plurality of organic layers sandwiched between the anode and the cathode, wherein the plurality of organic layers comprise: a light emitting layer containing a phosphorescence emitting compound; and an electron transport layer containing a compound represented by Formula (1), (Ar1)n1-Y1  Formula (1) wherein n1 is an integer of 1 or more; Y1 is a substituent when n1 is 1, and Y1 is a single bond or a linking group of n1 valences when n1 is two or more; Ar1 is a group represented by Formula (A), a plurality of Ar1 may be the same or different with each other when n1 is two or more; and the compound represented by Formula (1) contains at least two condensed aromatic heterocyclic rings each comprising 3 or more rings condensed with each other.

摘要翻译： 本发明提供一种有机电致发光元件，其特征在于，具备在其上具有阳极，阴极以及夹在所述阳极与所述阴极之间的多个有机层的基板，其中，所述多个有机层包括含有磷光发光性化合物的发光层。 和含有式（1）表示的化合物，（Ar1）n1-Y1式（1）的电子传输层，其中n1为1以上的整数， 当n1为1时，Y1为取代基，当n1为2以上时，Y1为单键或n1键连接基; Ar1为式（A）所示的基团，当n1为2以上时，多个Ar1可以相同或不同。 并且由式（1）表示的化合物含有至少两个各自包含3个或更多个彼此稠合的环的稠合芳族杂环。

公开(公告)号：US20110272687A1

公开(公告)日：2011-11-10

申请号：US13145842

申请日：2010-01-21

申请人： Rie Katakura ,  Eisaku Katoh ,  Hideo Taka

发明人： Rie Katakura ,  Eisaku Katoh ,  Hideo Taka

IPC分类号： H01L51/54

CPC分类号： C07D471/04 ,  C07D405/14 ,  C07D409/14 ,  C07D413/14 ,  C07D417/14 ,  C07D421/14 ,  C07D495/04 ,  C07D519/00 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1466 ,  C09K2211/185 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0081 ,  H01L51/5048 ,  H05B33/18 ,  H05B33/20

摘要： Provided is an o organic electroluminescence element comprising an anode, a cathode and a plurality of composing layers including a light emitting layer sandwiched between the anode and the cathode, wherein an electron transport layer containing the compound represented by Formula (1) is included in the composing layers; the light emitting layer contains a phosphorescence emitting organic metal complex; and the cathode or one composing layer adjacent to the cathode contains a metal or a metal compound belonging to Group 1 or Group 2 of the periodic table of elements, provided that the metal exhibits a standard electrode potential larger than −3 V vs. SHE in a system of the metal ion (Mn+)/the metal (M):

摘要翻译： 提供了一种有机电致发光元件，其包括阳极，阴极和包括夹在阳极和阴极之间的发光层的多个组成层，其中包含由式（1）表示的化合物的电子传输层包括在 组成层; 发光层含有磷光发光有机金属络合物; 并且与阴极相邻的阴极或一个组成层包含属于元素周期表第1族或第2族的金属或金属化合物，条件是金属表现出大于-3V的标准电极电势，相对于SHE 金属离子（Mn +）/金属（M）的系统：

公开(公告)号：US09617255B2

公开(公告)日：2017-04-11

申请号：US13145842

申请日：2010-01-21

申请人： Rie Katakura ,  Eisaku Katoh ,  Hideo Taka

发明人： Rie Katakura ,  Eisaku Katoh ,  Hideo Taka

IPC分类号： H01L51/54 ,  C07D471/04 ,  C07D405/14 ,  C07D409/14 ,  C07D413/14 ,  C07D417/14 ,  C07D421/14 ,  C07D495/04 ,  C07D519/00 ,  C09K11/06 ,  H01L51/00 ,  H05B33/18 ,  H05B33/20 ,  H01L51/50

CPC分类号： C07D471/04 ,  C07D405/14 ,  C07D409/14 ,  C07D413/14 ,  C07D417/14 ,  C07D421/14 ,  C07D495/04 ,  C07D519/00 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1466 ,  C09K2211/185 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0081 ,  H01L51/5048 ,  H05B33/18 ,  H05B33/20

摘要： Provided is an o organic electroluminescence element comprising an anode, a cathode and a plurality of composing layers including a light emitting layer sandwiched between the anode and the cathode, wherein an electron transport layer containing the compound represented by Formula (1) is included in the composing layers; the light emitting layer contains a phosphorescence emitting organic metal complex; and the cathode or one composing layer adjacent to the cathode contains a metal or a metal compound belonging to Group 1 or Group 2 of the periodic table of elements, provided that the metal exhibits a standard electrode potential larger than −3 V vs. SHE in a system of the metal ion (Mn+)/the metal (M):

公开(公告)号：US08951650B2

公开(公告)日：2015-02-10

申请号：US13530719

申请日：2012-06-22

申请人： Noriko Yasukawa ,  Hiroshi Kita ,  Eisaku Katoh ,  Tatsuo Tanaka ,  Shinya Otsu ,  Rie Katakura ,  Hidekane Ozeki ,  Hideo Taka

发明人： Noriko Yasukawa ,  Hiroshi Kita ,  Eisaku Katoh ,  Tatsuo Tanaka ,  Shinya Otsu ,  Rie Katakura ,  Hidekane Ozeki ,  Hideo Taka

IPC分类号： H01L51/50 ,  C09K11/06 ,  H01L51/00 ,  H05B33/14

CPC分类号： C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/006 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5048 ,  H05B33/14 ,  Y10S428/917

摘要： Provided is an organic electroluminescent element comprising a substrate having thereon an anode, a cathode, and a plurality of organic layers sandwiched between the anode and the cathode, wherein the plurality of organic layers comprise: a light emitting layer containing a phosphorescence emitting compound; and an electron transport layer containing a compound represented by Formula (1), (Ar1)n1−Y1  Formula (1) wherein n1 is an integer of 1 or more; Y1 is a substituent when n1 is 1, and Y1 is a single bond or a linking group of n1 valences when n1 is two or more; Ar1 is a group represented by Formula (A), a plurality of Ar1 may be the same or different with each other when n1 is two or more; and the compound represented by Formula (1) contains at least two condensed aromatic heterocyclic rings each comprising 3 or more rings condensed with each other:

摘要翻译： 本发明提供一种有机电致发光元件，其特征在于，具备在其上具有阳极，阴极以及夹在所述阳极与所述阴极之间的多个有机层的基板，其中，所述多个有机层包括含有磷光发光性化合物的发光层。 和含有式（1）表示的化合物，（Ar1）n1-Y1式（1）的电子传输层，其中n1为1以上的整数， 当n1为1时，Y1为取代基，当n1为2以上时，Y1为单键或n1键连接基; Ar1为式（A）所示的基团，当n1为2以上时，多个Ar1可以相同或不同。 并且由式（1）表示的化合物包含至少两个各自包含3个或更多个彼此缩合的环的稠合芳族杂环：

公开(公告)号：US08592057B2

公开(公告)日：2013-11-26

申请号：US13713496

申请日：2012-12-13

申请人： Rie Katakura ,  Shuichi Sugita ,  Eisaku Katoh ,  Motoaki Sugino ,  Rie Fujisawa

发明人： Rie Katakura ,  Shuichi Sugita ,  Eisaku Katoh ,  Motoaki Sugino ,  Rie Fujisawa

IPC分类号： H01L51/54 ,  C07D407/10 ,  C07D409/10 ,  C07D471/04 ,  C07F15/00

CPC分类号： H01L51/0073 ,  C07D403/10 ,  C07D405/04 ,  C07D405/10 ,  C07D405/14 ,  C07D409/04 ,  C07D409/10 ,  C07D409/14 ,  C07D471/04 ,  C07D471/14 ,  C07D495/04 ,  C07D519/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/004 ,  H01L51/0043 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016

摘要： Disclosed is an organic electroluminescence element comprising an anode, a cathode and a plurality of organic compound layers between the anode and the cathode, provided that one of the organic compound layers is a light emitting layer containing a phosphorescence emitting compound, wherein at least one of the organic compound layers contains a compound represented by Formula (2): wherein, X represents O or S; three of Y1 to Y4 each are a group represented by Formula (2A), and one of Y1 to Y4 is a hydrogen atom. Formula (2A) is: Ar1L1n1* wherein, L1 represents a divalent linking group derived from an aromatic hydrocarbon ring or an aromatic heterocycle; n1 represents an integer of 0 to 3, provided that when n1 is 2 or 3, a plurality of L1s may be the same or different; “*” indicates a linking position with Formula (2).

摘要翻译： 公开了一种有机电致发光元件，其包括在阳极和阴极之间的阳极，阴极和多个有机化合物层，条件是有机化合物层之一是含有磷光发射化合物的发光层，其中至少一个 有机化合物层含有由式（2）表示的化合物：其中，X表示O或S; Y 1〜Y 4中的3个为式（2A）所示的基团，Y 1〜Y 4中的一个为氢原子。 式（2A）为：Ar1L1n1 *其中，L1表示衍生自芳族烃环或芳香族杂环的二价连接基团; n1表示0〜3的整数，条件是当n1为2或3时，多个L1可以相同或不同; “*”表示与式（2）的连接位置。

公开(公告)号：US08367224B2

公开(公告)日：2013-02-05

申请号：US12752252

申请日：2010-04-01

申请人： Rie Katakura ,  Shuichi Sugita ,  Eisaku Katoh ,  Motoaki Sugino ,  Rie Fujisawa

发明人： Rie Katakura ,  Shuichi Sugita ,  Eisaku Katoh ,  Motoaki Sugino ,  Rie Fujisawa

IPC分类号： H01L51/54 ,  C07D407/10 ,  C07D409/10 ,  C07D471/04 ,  C07F15/00

CPC分类号： H01L51/0073 ,  C07D403/10 ,  C07D405/04 ,  C07D405/10 ,  C07D405/14 ,  C07D409/04 ,  C07D409/10 ,  C07D409/14 ,  C07D471/04 ,  C07D471/14 ,  C07D495/04 ,  C07D519/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/004 ,  H01L51/0043 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016

摘要： Disclosed is an organic electroluminescence element comprising an anode, a cathode and a plurality of organic compound layers between the anode and the cathode, provided that one of the organic compound layers is a light emitting layer containing a phosphorescence emitting compound, wherein at least one of the organic compound layers contains a compound represented by Formula (1), wherein, X represents O or S; Y1 to Y3 each represents a hydrogen atom, a substituent or a group represented by Formula (A) disclosed in the specification, provided that at least two of Y1 to Y3 are groups represented by Formula (A), not all of Y1 to Y3 are the same group, and at least one of the groups represented by Formula (A) has Ar of a carbazolyl group, or an azacarbazolyl group containing 2 to 5 nitrogen atoms.

摘要翻译： 公开了一种有机电致发光元件，其包括在阳极和阴极之间的阳极，阴极和多个有机化合物层，条件是有机化合物层之一是含有磷光发射化合物的发光层，其中至少一个 有机化合物层含有由式（1）表示的化合物，其中X表示O或S; Y1至Y3各自表示说明书中公开的氢原子，取代基或取代基或由式（A）表示的基团，条件是Y 1至Y 3中的至少两个为由式（A）表示的基团，并不全部为Y1至Y3 相同的基团，和由式（A）表示的基团中的至少一个具有咔唑基的Ar或含有2至5个氮原子的氮杂环唑基。

公开(公告)号：US09090819B2

公开(公告)日：2015-07-28

申请号：US13378120

申请日：2010-04-28

申请人： Shuichi Sugita ,  Eisaku Katoh ,  Motoaki Sugino ,  Rie Katakura

发明人： Shuichi Sugita ,  Eisaku Katoh ,  Motoaki Sugino ,  Rie Katakura

IPC分类号： H01L51/50 ,  C09K11/06 ,  C07D471/04 ,  C07D471/14 ,  C07D519/00 ,  H01L51/00 ,  H05B33/14

CPC分类号： C09K11/06 ,  C07D471/04 ,  C07D471/14 ,  C07D519/00 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/1466 ,  C09K2211/185 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L2251/308 ,  H05B33/14

摘要： Disclosed is an organic electroluminescent element which is characterized in that constituent layers including at least a phosphorescent light-emitting layer are provided between a pair of electrodes, and at least one of the constituent layers contains a compound represented by general formula (1). (In the formula, A1, A2 and A3 each represents a substituent; n1 and n2 each represents an integer of 0-3; X1 and X2 each represents an oxygen atom, a sulfur atom, an alkylene group, an imino group, a carbonyl group, a sulfoxide group or a sulfonyl group, or alternatively X2 represents a bonding hand; and Z1, Z2, Z3 and Z4 each represents an optionally substituted aromatic heterocyclic ring or an aromatic hydrocarbon ring, provided that all of the Z1, Z2, Z3 and Z4 are not aromatic hydrocarbon rings at the same time.)

摘要翻译： 公开了一种有机电致发光元件，其特征在于，在一对电极之间设置至少包含磷光发光层的构成层，至少一个构成层含有通式（1）表示的化合物。 （式中，A1，A2，A3各自表示取代基，n1和n2分别表示0-3的整数，X1，X2各自表示氧原子，硫原子，亚烷基，亚氨基，羰基 基团，亚砜基或磺酰基，或者X2表示键合键; Z1，Z2，Z3和Z4各自表示任选取代的芳香族杂环或芳香族烃环，条件是所有的Z1，Z2，Z3 和Z4不是芳烃环。）

公开(公告)号：US20120037889A1

公开(公告)日：2012-02-16

申请号：US13132685

申请日：2009-12-03

申请人： Tatsuo Tanaka ,  Hiroshi Kita ,  Eisaku Katoh ,  Rie Katakura

发明人： Tatsuo Tanaka ,  Hiroshi Kita ,  Eisaku Katoh ,  Rie Katakura

IPC分类号： H01L51/54

CPC分类号： C07F15/0033 ,  C08G61/12 ,  C08G2261/3162 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1044 ,  C09K2211/1416 ,  C09K2211/1425 ,  C09K2211/1433 ,  C09K2211/145 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/185 ,  H01L51/004 ,  H01L51/0043 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/10 ,  Y02B20/181

摘要： Provided is an organic electroluminescence element having an anode, a cathode and an organic compound layer sandwiched between the anode and the cathode, provided that the organic compound layer containing at least a phosphorescence dopant and a polymer which contains a partial structure represented by Formula (1), and a terminal end of the polymer is end-capped, wherein the phosphorescence dopant is a metal complex containing a ligand composed of a 5 or six membered aromatic hydrocarbon ring or a 5 or six membered aromatic heterocyclic group which is bonded to a five membered nitrogen containing aromatic heterocyclic group: Formula (1)

摘要翻译： 提供一种有机电致发光元件，其具有阳极，阴极和夹在阳极和阴极之间的有机化合物层，条件是含有至少磷光掺杂剂的有机化合物层和含有由式（1）表示的部分结构的聚合物 ），并且聚合物的末端被封端，其中磷光掺杂剂是含有由5或6元芳族烃环或5或6元芳族杂环基组成的配体的金属络合物，其结合到五 含氮芳族杂环基：式（1）

公开(公告)号：US20120085997A1

公开(公告)日：2012-04-12

申请号：US13378120

申请日：2010-04-28

申请人： Shuichi Sugita ,  Eisaku Katoh ,  Motoaki Sugino ,  Rie Katakura

发明人： Shuichi Sugita ,  Eisaku Katoh ,  Motoaki Sugino ,  Rie Katakura

IPC分类号： H01L51/54 ,  C07D487/04 ,  C07D471/04

CPC分类号： C09K11/06 ,  C07D471/04 ,  C07D471/14 ,  C07D519/00 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/1466 ,  C09K2211/185 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L2251/308 ,  H05B33/14

摘要： Disclosed is an organic electroluminescent element which is characterized in that constituent layers including at least a phosphorescent light-emitting layer are provided between a pair of electrodes, and at least one of the constituent layers contains a compound represented by general formula (1). (In the formula, A1, A2 and A3 each represents a substituent; n1 and n2 each represents an integer of 0-3; X1 and X2 each represents an oxygen atom, a sulfur atom, an alkylene group, an imino group, a carbonyl group, a sulfoxide group or a sulfonyl group, or alternatively X2 represents a bonding hand; and Z1, Z2, Z3 and Z4 each represents an optionally substituted aromatic heterocyclic ring or an aromatic hydrocarbon ring, provided that all of the Z1, Z2, Z3 and Z4 are not aromatic hydrocarbon rings at the same time.)

摘要翻译： 公开了一种有机电致发光元件，其特征在于，在一对电极之间设置至少包含磷光发光层的构成层，至少一个构成层含有通式（1）表示的化合物。 （式中，A1，A2，A3各自表示取代基，n1和n2分别表示0-3的整数，X1，X2各自表示氧原子，硫原子，亚烷基，亚氨基，羰基 基团，亚砜基或磺酰基，或者X2表示键合键; Z1，Z2，Z3和Z4各自表示任选取代的芳香族杂环或芳香族烃环，条件是所有的Z1，Z2，Z3 和Z4不是芳烃环。）

公开(公告)号：US08920942B2

公开(公告)日：2014-12-30

申请号：US12293736

申请日：2007-03-20

申请人： Shinya Otsu ,  Hiroshi Kita ,  Eisaku Katoh

发明人： Shinya Otsu ,  Hiroshi Kita ,  Eisaku Katoh

IPC分类号： H01L51/54 ,  C09K11/06 ,  H01L51/50 ,  H01L51/00 ,  H05B33/14

CPC分类号： H01L51/5012 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1018 ,  C09K2211/1029 ,  C09K2211/1037 ,  C09K2211/1044 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L51/5036 ,  H01L2251/552 ,  H05B33/14 ,  Y10S428/917

摘要： Disclosed is an organic electroluminescent element having high luminous efficiency and long life. Also disclosed are a display device and an illuminating device respectively using such an organic electroluminescent element. Specifically disclosed is an organic electroluminescent element comprising an electrode and at least one or more organic layers on a substrate. This organic electroluminescent element is characterized in that at least one of the organic layers is a light-emitting layer containing a phosphorescent compound and a host compound, the phosphorescent compound has a HOMO of −5.15 to −3.50 eV and a LUMO of from −1.25 to +1.00 eV, and the host compound has a 0-0 band of the phosphorescence spectrum at not more than 460 nm and a glass transition temperature of not less than 60° C.

摘要翻译： 公开了具有高发光效率和长寿命的有机电致发光元件。 还公开了分别使用这种有机电致发光元件的显示装置和照明装置。 具体公开了一种有机电致发光元件，其包括电极和在基板上的至少一个或多个有机层。 该有机电致发光元件的特征在于，至少一个有机层是含有磷光化合物和主体化合物的发光层，磷光化合物的HOMO为-5.15〜-3.50eV，LUMO为-1.25 至+1.00eV，并且主体化合物具有不大于460nm的磷光光谱的0-0带，并且玻璃化转变温度不低于60℃。