公开(公告)号：US4281102A

公开(公告)日：1981-07-28

申请号：US92141

申请日：1979-11-07

申请人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch ,  Terry L. St. Clair ,  John M. Butler

发明人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch ,  Terry L. St. Clair ,  John M. Butler

IPC分类号： C08G73/10 ,  C08G12/00 ,  C08G16/00

CPC分类号： C08G73/1007 ,  C08G73/1042 ,  Y10T428/31721

摘要： An improvement of addition polyimides wherein an essentially solventless, high viscosity laminating resin is synthesized from low-cost liquid monomers. The improved process takes advantage of a reactive, liquid plasticizer such as monoethylphthalate (MEP) which is used in lieu of an alcohol solvent, and helps solve a major problem of maintaining good prepreg tack and drape, or the ability of the prepreg to adhere to adjacent plies and conform to a desired shape during the layup process. This improvement results in both longer life of the polymer prepreg and the processing of low-void laminates and appears to be applicable to all addition polyimide systems.

摘要翻译： 加成聚酰亚胺的改进，其中由低成本液体单体合成基本上无溶剂的高粘度层压树脂。 改进的方法利用反应性液体增塑剂，例如用于代替醇溶剂的邻苯二甲酸单乙酯（MEP），并且有助于解决保持良好的预浸料粘性和悬垂性的主要问题，或预浸料粘附于 相邻层并且在铺层过程中符合期望的形状。 这种改进导致聚合物预浸料坯的寿命更长和低空隙层压板的加工，并且似乎适用于所有加成聚酰亚胺体系。

公开(公告)号：US4284461A

公开(公告)日：1981-08-18

申请号：US92142

申请日：1979-11-07

申请人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch ,  Anne K. St. Clair ,  Larry T. Taylor ,  Terry L. St. Clair

发明人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch ,  Anne K. St. Clair ,  Larry T. Taylor ,  Terry L. St. Clair

IPC分类号： C08K5/00 ,  H05K3/38 ,  C08G69/28

CPC分类号： C08K5/0091 ,  H05K3/386

摘要： A method for preparing an aluminum ion-filled polyimide adhesive wherein a meta-oriented aromatic diamine is reacted with an aromatic dianhydride and an aluminum compound in the presence of a water or lower alkanol miscible ether solvent to produce an intermediate polyamic acid; and thereafter converting the polyamic acid to the thermally stable, metal ion-filled polyimide by heating in the temperature range of 300.degree. C. to produce a flexible, high temperature adhesive.

摘要翻译： 一种制备铝离子填充的聚酰亚胺粘合剂的方法，其中将间位取向的芳族二胺与芳族二酐和铝化合物在水或低级链烷醇可混溶的醚溶剂的存在下反应以产生中间体聚酰胺酸; 然后通过在300℃的温度范围内加热将聚酰胺酸转化成热稳定的金属离子填充的聚酰亚胺，以产生柔性的高温粘合剂。

公开(公告)号：US07507784B2

公开(公告)日：2009-03-24

申请号：US11124508

申请日：2005-04-29

申请人： Theodorus J. Dingemans ,  Erik S. Weiser ,  Terry L. St. Clair

发明人： Theodorus J. Dingemans ,  Erik S. Weiser ,  Terry L. St. Clair

IPC分类号： C08G73/00 ,  C08G65/40 ,  C09K19/06 ,  C09K19/12

CPC分类号： C09K19/3823 ,  C08G63/60 ,  C08G63/6854 ,  C08G69/44 ,  C08G73/16 ,  C09K19/3804

摘要： Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,000 grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase. They are highly processable by a variety of melt process shape forming and blending techniques. Once processed and shaped, the end-capped liquid crystal oligomers were heated to further polymerize and form liquid crystalline thermosets (LCT). The fully cured products are rubbers above their glass transition temperatures.

摘要翻译： 主链热致液晶酯，酯 - 酰亚胺和酯 - 酰胺由AA，BB和AB型单体材料制备，并用苯乙炔，苯基马来酰亚胺或纳二酰胺反应性端基封端。 封端的液晶低聚物是热致变性的，并且优选分子量在约1000-15,000克/摩尔的范围内。 封端的液晶低聚物具有宽的液晶熔融范围，并且在可接近的温度下表现出高的熔体稳定性和非常低的熔体粘度。 封端的液晶低聚物在熔融相中稳定长达一个小时。 它们通过各种熔体加工形状和混合技术可高度加工。 一旦加工和成形，加热封端的液晶低聚物进一步聚合并形成液晶热固性塑料（LCT）。 完全固化的产品是高于其玻璃化转变温度的橡胶。

公开(公告)号：US5189127A

公开(公告)日：1993-02-23

申请号：US801867

申请日：1991-12-03

申请人： Margaret K. Gerber ,  Terry L. St. Clair

发明人： Margaret K. Gerber ,  Terry L. St. Clair

IPC分类号： C08F38/00 ,  C08F290/06 ,  C08G73/10

CPC分类号： C08F290/06 ,  C08F38/00 ,  C08G73/101 ,  C08G73/1071

摘要： The compound N-(3-ethynylphenyl)maleimide (NEPMI) was used to prepare thermally stable, glassy polyimides which did not exhibit glass transition temperatures below 500.degree. C. NEPMI was blended with the maleimide of methylene dianiline (BMI) and heated to form the polyimide. NEPMI was also mixed with Thermid 600.RTM., a commercially available bisethynyl oligomeric material, and heated to form a thermally stable, glassy polyimide. Lastly, NEPMI was blended with both BMI and Thermid 600.RTM. to form thermally stable, glassy polyimides.

摘要翻译： 使用化合物N-（3-乙炔基苯基）马来酰亚胺（NEPMI）制备热稳定的玻璃化聚酰亚胺，其不显示低于500℃的玻璃化转变温度。将NEPMI与亚甲基二苯胺（BMI）的马来酰亚胺共混并加热形成 聚酰亚胺。 NEPMI也与市售的双乙炔基低聚物材料Thermid 600 TM混合，并加热形成热稳定的玻璃状聚酰亚胺。 最后，NEPMI与BMI和Thermid 600 TM混合以形成热稳定的玻璃状聚酰亚胺。

公开(公告)号：US5147966A

公开(公告)日：1992-09-15

申请号：US560717

申请日：1990-07-31

申请人： Terry L. St. Clair ,  Donald J. Progar

发明人： Terry L. St. Clair ,  Donald J. Progar

IPC分类号： C08G73/10

CPC分类号： C08G73/1032 ,  C08G73/1014 ,  C08G73/1017 ,  C08G73/1071 ,  Y10T428/2913 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/31721

摘要： The invention is a novel polyimide prepared from 3,4'-oxydianiline (3,4'-ODA) and 4,4'-oxydiphthalic anhydride (ODPA), in 2-methoxyethyl ether (diglyme). The polymer has been prepared in ultra high molecular weight and in a controlled molecular weight form which has a 2.5 percent offset is stoichiometry (excess diamine) with a 5.0 percent level of phthalic anhydride as an endcap. This controlled molecular weight form allows for greatly improved processing of the polymer for moldings, adhesive bonding, and composite fabrication. The higher molecular weight version affords tougher films and coatings. The overall polymer structure groups in the dianhydride, the diamine, and a metal linkage in the diamine affords adequate flow properties for making this polymer useful as a molding powder, adhesive, and matrix resin.

摘要翻译： 本发明是由3,4-氧代二苯胺（3,4'-ODA）和4,4'-氧联二邻苯二甲酸酐（ODPA）在2-甲氧基乙醚（二甘醇二甲醚）中制备的新型聚酰亚胺。 聚合物已经以超高分子量和受控的分子量形式制备，其具有2.5％的偏移量是化学计量（过量二胺），5.0％邻苯二甲酸酐作为端帽。 这种受控的分子量形式允许用于模制品，粘合剂粘合和复合材料制造的聚合物的大大改进的处理。 更高的分子量版本提供更坚韧的膜和涂层。 在二酐中的整体聚合物结构基团，二胺和二胺中的金属键提供了足够的流动性能，用于使该聚合物用作成型粉末，粘合剂和基质树脂。

公开(公告)号：US5093453A

公开(公告)日：1992-03-03

申请号：US449210

申请日：1989-12-12

申请人： Anne K. St. Clair ,  Terry L. St. Clair ,  J. Richard Pratt

发明人： Anne K. St. Clair ,  Terry L. St. Clair ,  J. Richard Pratt

IPC分类号： C08G73/10

CPC分类号： C08G73/106

摘要： A high-temperature stable, optically transparent, low dielectric aromatic polyimide is prepared by chemically combining equimolar quantities of an aromatic dianhydride reactant and an aromatic diamine reactant, which are selected so that one reactant contains at least one Si(CH.sub.3).sub.2 group in its molecular structure, and the other reactant contains at least one --CH.sub.3 group in its molecular structure. The reactants are chemically combined in a solvent medium to form a solution of a high molecular weight polyamic acid, which is then converted to the corresponding polyimide.

摘要翻译： 通过化学组合等摩尔量的芳族二酐反应物和芳族二胺反应物来制备高温稳定的光学透明低介电芳族聚酰亚胺，其选择为使得一种反应物在其中含有至少一个Si（CH 3）2基团 分子结构，另一反应物在其分子结构中含有至少一个-CH 3基团。 将反应物在溶剂介质中化学组合以形成高分子量聚酰胺酸的溶液，然后将其转化为相应的聚酰亚胺。

公开(公告)号：US5004575A

公开(公告)日：1991-04-02

申请号：US262268

申请日：1988-10-21

申请人： Norman J. Johnston ,  Terry L. St. Clair ,  Robert M. Baucom ,  John R. Gleason

发明人： Norman J. Johnston ,  Terry L. St. Clair ,  Robert M. Baucom ,  John R. Gleason

IPC分类号： C08J5/24

CPC分类号： C08J5/24 ,  C08J2379/08

摘要： Composite materials with matrices of tough, thermoplastic aromatic polyimides are obtained by blending semi-crystalline polyimide powders with polyamic acid solutions to form slurries, which are used in turn to prepare prepregs, the consolidation of which into finished composites is characterized by excellent melt flow during processing.

摘要翻译： 通过将半结晶聚酰亚胺粉末与聚酰胺酸溶液混合以形成浆料来获得具有韧性，热塑性芳族聚酰亚胺基质的复合材料，其依次用于制备预浸料，其固化成成品复合材料的特征在于优异的熔体流动 处理。

公开(公告)号：US4937317A

公开(公告)日：1990-06-26

申请号：US266045

申请日：1988-11-02

申请人： J. Richard Pratt ,  Terry L. St. Clair ,  Donald J. Progar

发明人： J. Richard Pratt ,  Terry L. St. Clair ,  Donald J. Progar

IPC分类号： C08G73/10 ,  C09D179/08 ,  C09J179/08

CPC分类号： C09D179/08 ,  C08G73/1067 ,  C09J179/08

摘要： A high temperature polyimide composition prepared by reacting 4,4'-isophthaloyldiphthalic anhydride with metaphenylenediamine is employed to prepare matrix resins, adhesives, films, coatings, moldings, and laminates.

摘要翻译： 使用通过使4,4'-间苯二酰二邻苯二甲酸酐与间苯二胺反应制备的高温聚酰亚胺组合物来制备基质树脂，粘合剂，薄膜，涂料，模制品和层压材料。

公开(公告)号：US4431792A

公开(公告)日：1984-02-14

申请号：US447371

申请日：1982-12-07

申请人： Terry L. St. Clair ,  James F. Wolfe ,  Thomas D. Greenwood

发明人： Terry L. St. Clair ,  James F. Wolfe ,  Thomas D. Greenwood

IPC分类号： C08G69/28 ,  C08G69/32

CPC分类号： C08G69/28

摘要： The compounds are of the class of aromatic polyamides useful as matrix resins in the manufacture of composites or laminate fabrication. The process for preparing this thermoplastic-thermoset polyamide system involves incorporating a latent crosslinking moiety along the backbone of the polyamide to improve the temperature range of fabrication thereof wherein the resin softens at a relatively low temperature (.congruent.154.degree. C.) and subsequently "sets-up" or undergoes crosslinking when subjected to higher temperature (.congruent.280.degree. C.).

摘要翻译： 这些化合物是在复合材料或层压制造的制造中用作基质树脂的芳族聚酰胺类。 制备该热塑性热固性聚酰胺体系的方法包括在聚酰胺的主链上引入潜在交联部分以改善其制造的温度范围，其中树脂在相对较低的温度（约154℃）下软化，然后“ -up“或经受更高温度（280℃）时的交联。

公开(公告)号：US07964698B2

公开(公告)日：2011-06-21

申请号：US11935036

申请日：2007-11-05

申请人： Erik S. Weiser ,  Theodorus J. Dingemans ,  Terry L. St. Clair ,  Jeffrey A. Hinkley

发明人： Erik S. Weiser ,  Theodorus J. Dingemans ,  Terry L. St. Clair ,  Jeffrey A. Hinkley

IPC分类号： C08G73/10

CPC分类号： C08G73/1071 ,  C08J5/24 ,  C08J2379/08 ,  C08L79/08 ,  C09K19/3814 ,  C09K19/3823

摘要： The benefits of liquid crystal polymers and polyetherimides are combined in an all-aromatic thermoplastic liquid crystalline polyetherimide. Because of the unique molecular structure, all-aromatic thermotropic liquid crystal polymers exhibit outstanding processing properties, excellent barrier properties, low solubilities and low coefficients of thermal expansion in the processing direction. These characteristics are combined with the strength, thermal, and radiation stability of polyetherimides.

摘要翻译： 液晶聚合物和聚醚酰亚胺的优点在全芳族热塑性液晶聚醚酰亚胺中组合。 由于独特的分子结构，全芳族热致液晶聚合物具有出色的加工性能，优异的阻隔性能，低溶解度和低加工方向的热膨胀系数。 这些特性与聚醚酰亚胺的强度，热和辐射稳定性相结合。