Polymer electrolyte material for lithium battery cells

    公开(公告)号:US11289736B2

    公开(公告)日:2022-03-29

    申请号:US16451782

    申请日:2019-06-25

    申请人: Robert Bosch GmbH

    摘要: Lithium battery electrolyte materials comprising fluorinated phosphonates and having a polymer structure defined by: where R1 is —CF3, —(CF2)nCF3 and n is an integer ranging from 1 to 10, perfluoropolyether (PFPE), polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP), ethylene fluorinated ethylene propylene (EFEP), or polyethylene tetrafluoroethylene (ETFE) and R2 is —(CF2)n and n is an integer ranging from 1 to 10, perfluoropolyether (PFPE), polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP), ethylene fluorinated ethylene propylene (EFEP), or polyethylene tetrafluoroethylene (ETFE).

    Battery having a low counter-ion permeability layer

    公开(公告)号:US10581050B2

    公开(公告)日:2020-03-03

    申请号:US16002089

    申请日:2018-06-07

    申请人: Robert Bosch GmbH

    IPC分类号: H01M4/02 H01M2/16 H01M10/0525

    摘要: An electrode configuration for a battery cell includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a low counter-ion permeability layer interposed between the separator and the positive electrode. The separator has a first permeability to counter-ions, which do not participate in the battery electrode reactions, and the low counter-ion permeability layer has a second permeability to the counter-ions that is less than the first permeability. The separator includes a first salt concentration adjacent to the low counter-ion permeability layer and a second salt concentration adjacent to the negative electrode, and the second salt concentration is greater than the first salt concentration.

    BATTERY HAVING A LOW COUNTER-ION PERMEABILITY LAYER

    公开(公告)号:US20180358598A1

    公开(公告)日:2018-12-13

    申请号:US16002089

    申请日:2018-06-07

    申请人: Robert Bosch GmbH

    IPC分类号: H01M2/16

    摘要: An electrode configuration for a battery cell includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a low counter-ion permeability layer interposed between the separator and the positive electrode. The separator has a first permeability to counter-ions, which do not participate in the battery electrode reactions, and the low counter-ion permeability layer has a second permeability to the counter-ions that is less than the first permeability. The separator includes a first salt concentration adjacent to the low counter-ion permeability layer and a second salt concentration adjacent to the negative electrode, and the second salt concentration is greater than the first salt concentration.