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公开(公告)号:US10804565B2
公开(公告)日:2020-10-13
申请号:US16049911
申请日:2018-07-31
发明人: Sondra Hellstrom , David Abram , Michael Aubrey , Jeffrey Long , Katherine Harry , John F. Christensen , Hany Eitouni , Jordan Axelson
IPC分类号: H01M10/056 , H01M10/0565 , H01M10/0525
摘要: Solid electrolytes have a favorable combination of properties such as high conductivity, high transference number, optimum processability, and low brittleness. A composite electrolyte includes some amount of a class of network polymer electrolytes with high transference number and high room temperature conductivity, and an additional polymeric component to contribute mechanical integrity and/or processability. The solid electrolytes can include a network polymer having linked nodes composed of a tetrahedral arylborate composition and a linear polymer combined with the network polymer as a composite. The solid electrolytes can be used in thin films and in solid-state batteries.
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公开(公告)号:US20190051938A1
公开(公告)日:2019-02-14
申请号:US16049911
申请日:2018-07-31
发明人: Sondra Hellstrom , David Abram , Michael Aubrey , Jeffrey Long , Katherine Harry , John F. Christensen , Hany Eitouni , Jordan Axelson
IPC分类号: H01M10/0565 , H01M10/0525
摘要: Solid electrolytes have a favorable combination of properties such as high conductivity, high transference number, optimum processability, and low brittleness. A composite electrolyte includes some amount of a class of network polymer electrolytes with high transference number and high room temperature conductivity, and an additional polymeric component to contribute mechanical integrity and/or processability. The solid electrolytes can include a network polymer having linked nodes composed of a tetrahedral arylborate composition and a linear polymer combined with the network polymer as a composite. The solid electrolytes can be used in thin films and in solid-state batteries.
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公开(公告)号:US11289736B2
公开(公告)日:2022-03-29
申请号:US16451782
申请日:2019-06-25
申请人: Robert Bosch GmbH
发明人: Jin Yang , Hany Eitouni , Jonathan Mailoa
IPC分类号: H01M10/0565 , H01M10/052 , C08G79/04
摘要: Lithium battery electrolyte materials comprising fluorinated phosphonates and having a polymer structure defined by: where R1 is —CF3, —(CF2)nCF3 and n is an integer ranging from 1 to 10, perfluoropolyether (PFPE), polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP), ethylene fluorinated ethylene propylene (EFEP), or polyethylene tetrafluoroethylene (ETFE) and R2 is —(CF2)n and n is an integer ranging from 1 to 10, perfluoropolyether (PFPE), polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP), ethylene fluorinated ethylene propylene (EFEP), or polyethylene tetrafluoroethylene (ETFE).
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公开(公告)号:US20180159182A1
公开(公告)日:2018-06-07
申请号:US15833417
申请日:2017-12-06
申请人: Robert Bosch GmbH
IPC分类号: H01M10/42 , H01M4/36 , H01M4/525 , H01M4/505 , H01M10/0525 , H01M10/0565
摘要: A cathode active material including a lithium intercalation material; a coating including an oxide, phosphate, or borate; and a moiety capable of forming a bond with the coating.
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公开(公告)号:US10957904B2
公开(公告)日:2021-03-23
申请号:US16430920
申请日:2019-06-04
申请人: Robert Bosch GmbH
发明人: Russell Pratt , Yan Li , Xiaoliang Wang , Hany Eitouni
IPC分类号: H01M4/36 , H01M4/62 , H01M10/0525 , H01M10/0565 , C08F30/02 , H01M4/02
摘要: A solid state battery cathode material includes a first polymer of the general formula where R is naught, C1-C4 alkyl, C1-C4 perfluoroalkyl, or C1-C4 alkanone; X is naught, O, S, or NR1; and R1, R2 are H, C1-C8 alkyl, C2-C4 cycloalkyl, C1-C8 perfluoroalkyl, aryl, phenyl, or 1,2-phenylene.
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公开(公告)号:US11189852B2
公开(公告)日:2021-11-30
申请号:US16554098
申请日:2019-08-28
申请人: Robert Bosch GmbH
发明人: Natasha Teran , Malar Azagarsamy , Hany Eitouni
IPC分类号: H01M8/10 , C08G63/16 , C08L53/00 , C08L67/02 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1018
摘要: Polymer-based electrolyte materials that may be used as proton exchange membranes in proton exchange membrane fuel cells are described. The disclosed polymer electrolyte materials can be generally defined by a general 1,3-dicarbonyl repeat unit that may include various side chain and main chain constituents changing the acidity of the C—H proton(s) located between the carbonyl groups. Accordingly, by varying such side-chain and main-chain constituents, the proton-conduction properties the disclosed proton exchange membranes can be manipulated, and methods of producing the same. Methods of producing such polymer electrolyte materials are also disclosed.
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公开(公告)号:US10581050B2
公开(公告)日:2020-03-03
申请号:US16002089
申请日:2018-06-07
申请人: Robert Bosch GmbH
IPC分类号: H01M4/02 , H01M2/16 , H01M10/0525
摘要: An electrode configuration for a battery cell includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a low counter-ion permeability layer interposed between the separator and the positive electrode. The separator has a first permeability to counter-ions, which do not participate in the battery electrode reactions, and the low counter-ion permeability layer has a second permeability to the counter-ions that is less than the first permeability. The separator includes a first salt concentration adjacent to the low counter-ion permeability layer and a second salt concentration adjacent to the negative electrode, and the second salt concentration is greater than the first salt concentration.
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公开(公告)号:US20180358598A1
公开(公告)日:2018-12-13
申请号:US16002089
申请日:2018-06-07
申请人: Robert Bosch GmbH
IPC分类号: H01M2/16
CPC分类号: H01M2/1686 , H01M2/1646 , H01M2/1653 , H01M2/1673 , H01M10/0525
摘要: An electrode configuration for a battery cell includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a low counter-ion permeability layer interposed between the separator and the positive electrode. The separator has a first permeability to counter-ions, which do not participate in the battery electrode reactions, and the low counter-ion permeability layer has a second permeability to the counter-ions that is less than the first permeability. The separator includes a first salt concentration adjacent to the low counter-ion permeability layer and a second salt concentration adjacent to the negative electrode, and the second salt concentration is greater than the first salt concentration.
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