High concentration encapsulation by interfacial polycondensation
    4.
    发明授权
    High concentration encapsulation by interfacial polycondensation 失效
    通过界面缩聚进行高浓度封装

    公开(公告)号:US4563212A

    公开(公告)日:1986-01-07

    申请号:US566108

    申请日:1983-12-27

    IPC分类号: A01N25/28 B01J13/16 A01N37/18

    CPC分类号: B01J13/16 A01N25/28

    摘要: This invention relates to a process for encapsulation, and particularly to the production of small or minute capsules constituted by a skin or thin wall of polymeric material e.g., polyurea, polyamide, polysulfonamide, polyester, polycarbonate, or polyurethane, which involves first providing an aqueous solution (continuous phase liquid) containing an emulsifier selected from the group consisting of sulfonated napthalene formaldehyde condensates, sulfonated polystyrenes derivatives and functionalized oligomers. A discontinuous (immiscible or organic) phase liquid containing a water-immiscible material which is the material to be encapsulated, plus a first shell wall component; is dispersed in the aqueous liquid to form an oil-in-water emulsion. The second shell wall component is added to the oil-in-water emulsion whereupon the first shell wall component reacts with the second shell wall component to form a solid polycondensate shell wall about the material to be encapsulated. The capsules formed may be directly used as in the form of an aqueous suspension.

    摘要翻译: 本发明涉及一种封装方法,特别是涉及由聚脲材料(例如聚脲,聚酰胺,聚磺酰胺,聚酯,聚碳酸酯或聚氨酯)聚合物的表皮或薄壁构成的小或微胶囊的生产方法,其首先提供水性 溶液(连续相液体),其含有选自磺化萘甲醛缩合物,磺化聚苯乙烯衍生物和官能化低聚物的乳化剂。 包含作为被包封的材料的水不混溶材料的不连续(不混溶或有机)相液体,以及第一壳壁组分; 分散在水性液体中以形成水包油乳液。 将第二壳壁组分添加到水包油乳液中,于是第一壳壁组分与第二壳壁组分反应以形成围绕待包封材料的固体缩聚物壳壁。 形成的胶囊可以以水性悬浮液的形式直接使用。

    Poly(vinyl phosphonomethylene amino carboxylates) and process for
preparation
    5.
    发明授权
    Poly(vinyl phosphonomethylene amino carboxylates) and process for preparation 失效
    聚(乙烯基膦酰基氨基羧酸酯)及其制备方法

    公开(公告)号:US4243591A

    公开(公告)日:1981-01-06

    申请号:US16859

    申请日:1979-03-02

    申请人: Ralph W. Magin

    发明人: Ralph W. Magin

    摘要: Poly(vinyl phosphonomethylene amino carboxylates) having at least one N-C-P linkage and at least one carboxyl end group per molecule are prepared by reacting a polyvinyl cyclic amide, orthophosphorous acid and formaldehyde in an aqueous acidic mixture at a temperature in excess of about 70.degree. C. The resulting polymeric compounds are useful as metal complexing agents and in water treating to inhibit scale formation and corrosion of metals by oxygen-containing waters.

    摘要翻译: 每分子具有至少一个NCP键和至少一个羧基端基的聚(乙烯基膦酰基氨基羧酸盐)通过使聚乙烯基环酰胺,正磷酸和甲醛在酸性水溶液中在超过约70℃的温度下反应来制备 所得的聚合物可用作金属络合剂,并且在水处理中可用于通过含氧水分抑制金属的结垢和腐蚀。

    Glyphosate herbicidal and plant growth regulant compositions and their
use
    6.
    发明授权
    Glyphosate herbicidal and plant growth regulant compositions and their use 失效
    草甘膦除草剂和植物生长调节剂组合物及其用途

    公开(公告)号:US5858921A

    公开(公告)日:1999-01-12

    申请号:US672832

    申请日:1996-06-28

    IPC分类号: A01N57/20 A01N25/30 A01N57/02

    CPC分类号: A01N57/20

    摘要: Glyphosate formulations which are effective even when employed at dosages below the dosage currently recommended for post-emergent herbicidal or plant growth regulant use are described. They are formulated as water solutions or powders or granules of (a) one or more agriculturally acceptable salts of glyphosate, e.g., amine, ammonium, alkali metal, alkylsulfonium, alkylphosphonium, sulfonylamine, and/or aminoguanidine salts of glyphosate; (b) at least one water-soluble long chain aliphatic hydrocarbyl dimethyl amine oxide in which the hydrocarbyl group is a linear or substantially linear saturated or olefinically unsaturated aliphatic group having in the range of about 8 to about 22 carbon atoms; and (c) at least one water-soluble quaternary ammonium halide having in the range of about 8 to about 40 carbon atoms in the molecule.

    摘要翻译: 描述了即使在低于目前推荐用于芽后除草或植物生长调节剂使用的剂量的剂量下使用的草甘膦制剂。 它们被配制成(a)草甘膦的一种或多种农业上可接受的盐,例如胺,铵,碱金属,烷基锍,烷基鏻,磺酰胺和/或草甘膦的氨基胍盐的水溶液或粉末或颗粒; (b)至少一种水溶性长链脂族烃基二甲基氧化胺,其中烃基是具有约8至约22个碳原子的直链或基本上线性的饱和或烯属不饱和脂族基团; 和(c)至少一种在分子中具有约8至约40个碳原子范围的水溶性季铵卤化物。

    Herbicidal and plant growth regulant compositions and their use
    7.
    发明授权
    Herbicidal and plant growth regulant compositions and their use 失效
    除草和植物生长调节剂组成及其用途

    公开(公告)号:US5783516A

    公开(公告)日:1998-07-21

    申请号:US672777

    申请日:1996-06-28

    IPC分类号: A01N57/20 A01N25/32 A01N57/02

    CPC分类号: A01N57/20

    摘要: Glyphosate formulations which are effective even when employed at dosages below the dosage currently recommended for post-emergent herbicidal or plant growth regulant use are described. They are formulated as water solutions or powders or granules of (a) one or more agriculturally acceptable salts of glyphosate, and (b) one or more particular types of quaternary ammonium compounds. The quaternary ammonium compound(s) are water-soluble compounds represented by the formula: R.sup.1 R.sup.2 R.sup.3 R.sup.4 N.sup..sym. X.sup..crclbar. wherein R.sup.1 is an aryloxyalkyl group having from 7 to about 16 carbon atoms, R.sup.2 is an alkyl group having in the range of about 10 to about 18 carbon atoms, R.sup.3 is a methyl or ethyl group, R.sup.4 is, independently, a methyl or ethyl group, or an alkyl group having in the range of about 10 to about 18, and X is a chlorine or bromine atom.

    摘要翻译: 描述了即使在低于目前推荐用于芽后除草或植物生长调节剂使用的剂量的剂量下使用的草甘膦制剂。 它们被配制成(a)一种或多种农业上可接受的草甘膦盐的水溶液或粉末或颗粒,和(b)一种或多种特定类型的季铵化合物。 季铵化合物是由下式表示的水溶性化合物:R1R2R3R4N(+)X( - )其中R1是具有7至约16个碳原子的芳氧基烷基,R2是烷基的范围为 约10至约18个碳原子,R 3是甲基或乙基,R 4独立地是甲基或乙基,或在约10至约18的范围内的烷基,X是氯或溴原子 。

    Glyphosate compositions comprising polyethoxylated monohydric primary
alcohols
    8.
    发明授权
    Glyphosate compositions comprising polyethoxylated monohydric primary alcohols 失效
    含有聚乙氧基化一元伯醇的草甘膦组合物

    公开(公告)号:US5710104A

    公开(公告)日:1998-01-20

    申请号:US628567

    申请日:1996-04-03

    IPC分类号: A01N57/20 A01N25/30 A01N57/02

    CPC分类号: A01N57/20

    摘要: Glyphosate formulations which are effective even when employed at dosages below the dosage currently recommended for post-emergent herbicidal or plant growth regulant use are described. They are formulated as water solutions or powders or granules of (a) one or more agriculturally acceptable amine, alkali metal, alkylsulfonium, alkylphosphonium, sulfonylamine, and/or aminoguanidine salts of glyphosate; and (b) one or more water-soluble polyethoxylated monohydric primary alcohol having a .beta.-branched alkyl group which has a total of at least about 10 carbon atoms and at least about 3 carbon atoms in the branch on the .beta.-carbon atom or agriculturally acceptable salt or ester thereof.

    摘要翻译: 描述了即使在低于目前推荐用于芽后除草或植物生长调节剂使用的剂量的剂量下使用的草甘膦制剂。 它们配制成(a)草甘膦的一种或多种农业上可接受的胺,碱金属,烷基锍,烷基鏻,磺酰胺和/或氨基胍盐的水溶液或粉末或颗粒; 和(b)一种或多种具有β-支化烷基的水溶性聚乙氧基化的一元伯醇,其在β-碳原子上的分支中或在农业上总共具有至少约10个碳原子和至少约3个碳原子 可接受的盐或酯。

    Herbicidal and plant growth regulant compositions and their use
    10.
    发明授权
    Herbicidal and plant growth regulant compositions and their use 失效
    除草和植物生长调节剂组成及其用途

    公开(公告)号:US5700760A

    公开(公告)日:1997-12-23

    申请号:US627853

    申请日:1996-04-03

    IPC分类号: A01N57/20 A01N57/04

    CPC分类号: A01N57/20

    摘要: Glyphosate formulations which are effective even when employed at dosages below the dosage currently recommended for post-emergent herbicidal or plant growth regulant use are described. They are formulated as water solutions or as powders or granules of (a) one or more agriculturally acceptable amine, alkali metal, alkylsulfonium, alkylphosphonium, sulfonylamine, and/or aminoguanidine salts of glyphosate as the only herbicide or plant growth regulant used in forming said composition; and (b) a trihydrocarbyl amine oxide surfactant as the only surface active component used in forming said composition. The amine oxide is (i) a single alkyl dimethyl amine oxide in which the alkyl group is a linear alkyl group having in the range of 10 to 14 carbon atoms, or (ii) a combination of two alkyl dimethyl amine oxides of (i), or (iii) a combination of at least one alkyl dimethyl amine oxide in which the alkyl group is a linear alkyl group having in the range of 10 to 14 carbon atoms and at least one dialkyl methyl amine oxide in which the alkyl groups are linear alkyl groups each having in the range of 8 to 12 carbon atoms. Optionally, one or more agriculturally acceptable substances none of which is a herbicide, or a plant growth regulant or a surfactant can be included in the formulation.

    摘要翻译: 描述了即使在低于目前推荐用于芽后除草或植物生长调节剂使用的剂量的剂量下使用的草甘膦制剂。 它们被配制成水溶液或粉末或颗粒,其为(a)草甘膦的一种或多种农业上可接受的胺,碱金属,烷基锍,烷基鏻,磺酰胺和/或氨基胍盐,作为用于形成所述 组成; 和(b)作为用于形成所述组合物的唯一表面活性组分的三烃基氧化胺表面活性剂。 氧化胺是(i)单烷基二甲基氧化胺,其中烷基是具有10至14个碳原子的直链烷基,或(ii)两个烷基二甲基氧化胺的组合,(i) ,或(iii)至少一种烷基二甲基氧化胺的组合,其中烷基是具有10至14个碳原子的直链烷基和至少一个其中烷基是直链的二烷基甲基氧化胺 各自具有8至12个碳原子的烷基。 任选地,一种或多种农业上可接受的物质,其中不包括除草剂,或植物生长调节剂或表面活性剂可以包括在制剂中。