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1.发明授权Process for the production of water soluble modified rosin ester vehicles for laminating inks 失效用于生产用于层压油墨的水溶性改性松香酯车辆的方法公开(公告)号：US06303676B1
公开(公告)日：2001-10-16
申请号：US09105910
申请日：1998-06-26
IPC分类号： C08J320
CPC分类号： C09D11/10
摘要： A method for the production of an improved water soluble resin binder for laminating printing inks has been discovered. The method comprises esterifying the carboxylated Diels Alder adduct produced from the reaction of rosin and at least one carboxylated dienophile with a sufficient amount of at least one polyol to produce a modified rosin having an acid number greater than 157. The modified rosin is reacted with a sufficient amount of an acrylic copolymer having an acid number greater than 180 under esterification conditions between 175 ° C. and 185 ° C. for a time sufficient to produce a resin binder having an acid number greater than 157. A laminating ink formulation of the invention comprises water, pigment, styrene-acrylic varnish, shellac varnish, alkanol and the improved water soluble resin binder of the invention as described above.
摘要翻译： 已经发现了用于生产用于层压印刷油墨的改进的水溶性树脂粘合剂的方法。 该方法包括将由松香和至少一种羧化亲双烯体的反应产生的羧化狄尔斯lder醛加合物与足够量的至少一种多元醇酯化，得到酸值大于157的改性松香。将改性松香与 足够量的丙烯酸共聚物，在175℃至185℃之间的酯化条件下酸值大于180的丙烯酸共聚物足够长时间以生产酸值大于157的树脂粘合剂。本发明的层压油墨配方 包括如上所述的本发明的水，颜料，苯乙烯 - 丙烯酸清漆，虫胶清漆，链烷醇和改进的水溶性树脂粘合剂。
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2.发明授权Process for the production of water soluble modified rosin ester vehicles for laminating inks 失效用于生产用于层压油墨的水溶性改性松香酯车辆的方法
公开(公告)号：US5965647A
公开(公告)日：1999-10-12
申请号：US105880
申请日：1998-06-26
CPC分类号： C09D11/10
摘要： A method for the production of an improved water soluble resin binder for laminating printing inks has been discovered. The method comprises esterifying the carboxylated Diels Alder adduct produced from the reaction of rosin and at least one carboxylated dienophile with a sufficient amount of at least one polyol to produce-a modified rosin having an acid number greater than 157. The modified rosin is reacted with a sufficient amount of an acrylic copolymer having an acid number greater than 180 under esterification conditions between 175.degree. C. and 185.degree. C. for a time sufficient to produce a resin binder having an acid number greater than 157. A laminating ink formulation of the invention comprises water, pigment, styrene-acrylic varnish, shellac varnish, alkanol and the improved water soluble resin binder of the invention as described above.
摘要翻译： 已经发现了用于生产用于层压印刷油墨的改进的水溶性树脂粘合剂的方法。 该方法包括将由松香和至少一种羧化的亲二烯体反应生成的羧化的狄尔斯lder醛加合物与足够量的至少一种多元醇酯化，得到酸值大于157的改性松香。将改性松香与 足够量的酸值大于180的丙烯酸共聚物在175℃和185℃之间的酯化条件下反应足以产生酸值大于157的树脂粘合剂的时间。 本发明包括如上所述的本发明的水，颜料，苯乙烯 - 丙烯酸清漆，虫胶清漆，链烷醇和改进的水溶性树脂粘合剂。
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公开(公告)号：US5338785A
公开(公告)日：1994-08-16
申请号：US95647
申请日：1993-07-21
申请人： Robert J. Catena , Gastone Artusa , Albert A. Kveglis , Jason J. Bosco , Sonia Barreto , Mathew C. Mathew , Mark D. Schneider
发明人： Robert J. Catena , Gastone Artusa , Albert A. Kveglis , Jason J. Bosco , Sonia Barreto , Mathew C. Mathew , Mark D. Schneider
摘要： A flexible packaging printing ink is formulated from a copolymer of polyethyleneneglycol methacrylate and a polyamide resin, pigment, solvent and cellulose acetate butyrate. The polyamide resin is prepared by condensing a dibasic acid mixture with a diamine mixture. The dibasic acid mixture comprises about 0.5 to 0.8 equivalents of a C.sub.20 -C.sub.44 dibasic acid mixture comprised of about 60 to 100% dimers, 0 to 40% trimers and 0 to 5% monomers, and about 0.2-0.7 equivalents of at least one C.sub.6 -C.sub.12 dibasic acid such as azelaic acid and adipic acid, while the diamine mixture comprises about 0.5-0.8 equivalents of piperazine or a substituted piperazine and the balance comprises at least one C.sub.2 -C.sub.12 alkyl diamine such as ethylene diamine.
摘要翻译： 柔性包装印刷油墨由聚乙烯二醇甲基丙烯酸酯与聚酰胺树脂，颜料，溶剂和乙酸丁酸纤维素的共聚物配制而成。 通过将二元酸混合物与二胺混合物冷凝来制备聚酰胺树脂。 二元酸混合物包含约0.5至0.8当量的由约60至100％二聚体，0至40％三聚物和0至5％单体组成的C20-C44二元酸混合物和约0.2-0.7当量的至少一种C6 -C12二元酸如壬二酸和己二酸，而二胺混合物包含约0.5-0.8当量的哌嗪或取代的哌嗪，余量包含至少一种C 2 -C 12烷基二胺如乙二胺。
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4.发明授权Process for the production of water soluble modified rosin ester vehicles for laminating inks 失效用于生产用于层压油墨的水溶性改性松香酯车辆的方法
公开(公告)号：US5814701A
公开(公告)日：1998-09-29
申请号：US536014
申请日：1995-09-29
CPC分类号： C09D11/10
摘要： A method for the production of an improved water soluble resin binder for laminating printing inks has been discovered. The method comprises esterifying the carboxylated Diels Alder adduct produced from the reaction of rosin and at least one carboxylated dienophile with a sufficient amount of at least one polyol to produce a modified rosin having an acid number greater than 157. The modified rosin is reacted with a sufficient amount of an acrylic copolymer having an acid number greater than 180 under esterification conditions between 175.degree. C. and 185.degree. C. for a time sufficient to produce a resin binder having an acid number greater than 157. A laminating ink formulation of the invention comprises water, pigment, styrene-acrylic varnish, shellac varnish, alkanol and the improved water soluble resin binder of the invention as described above.
摘要翻译： 已经发现了用于生产用于层压印刷油墨的改进的水溶性树脂粘合剂的方法。 该方法包括将由松香和至少一种羧化亲双烯体的反应产生的羧化狄尔斯lder醛加合物与足够量的至少一种多元醇酯化，得到酸值大于157的改性松香。将改性松香与 足够量的酸值大于180的丙烯酸共聚物在175℃和185℃之间的酯化条件下反应足以产生酸值大于157的树脂粘合剂的时间。本发明的层压油墨配方 包括如上所述的本发明的水，颜料，苯乙烯 - 丙烯酸清漆，虫胶清漆，链烷醇和改进的水溶性树脂粘合剂。
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5.发明授权
公开(公告)号：US5026755A
公开(公告)日：1991-06-25
申请号：US376078
申请日：1989-07-05
IPC分类号： C08F283/04
CPC分类号： C08F283/04
摘要： A water-dispersible graft copolymer of a polyamide and at least one acrylic monomer is prepared by reacting the polyamide with the acrylic monomer(s) in an alcohol solution in the presence of a free radical peroxidic initiator. The graft copolymer is particularly useful as the resin component of a water-based printing ink.
摘要翻译： 聚酰胺和至少一种丙烯酸单体的水分散性接枝共聚物是通过在自由基过氧化物引发剂的存在下在醇溶液中使聚酰胺与丙烯酸类单体反应来制备的。 接枝共聚物特别可用作水性印刷油墨的树脂成分。
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公开(公告)号：US5124412A
公开(公告)日：1992-06-23
申请号：US614543
申请日：1990-11-16
IPC分类号： B01F17/52 , B01J13/00 , C08G69/26 , C08G69/34 , C08G69/36 , C08G69/48 , C09C3/10 , C09D11/00 , C09D11/02 , C09D17/00
CPC分类号： C09D11/03 , C08G69/34 , C08G69/48 , C09D17/002
摘要： A carboxy acid-terminated polyamide is reacted with an alkylene glycol, a polyalkylene glycol, nitrogen base or an alkanol amine (followed by an alkanoic acid) to provide a block copolymer. These block copolymers are especially useful as pigment dispersants, i.e. for preparing solvent-based packaging inks (i.e. packaging gravure and flexographic inks).
摘要翻译： 将羧酸封端的聚酰胺与亚烷基二醇，聚亚烷基二醇，氮碱或链烷醇（随后是链烷酸）反应，得到嵌段共聚物。 这些嵌段共聚物特别可用作颜料分散剂，即用于制备基于溶剂的包装油墨（即包装凹版和柔性版油墨）。
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公开(公告)号：US5877259A
公开(公告)日：1999-03-02
申请号：US950118
申请日：1997-10-14
IPC分类号： C08F287/00 , C08L51/00 , C08L53/00 , C09J151/00 , C09J153/00 , C08K5/09
CPC分类号： C09J151/006 , C08F287/00 , C08L51/006 , C08L53/00 , C09J153/00
摘要： A heat-sealable adhesive for dissimilar substrates is disclosed comprising an organic solvent suspension of a graft copolymer of an A-B-A terblock copolymeric rubber, olefin copolymer and olefin terpolymer. Processing conditions are improved over known adhesive preparation conditions.
摘要翻译： 公开了一种用于不同基材的可热封的粘合剂，其包括A-B-A三嵌段共聚橡胶，烯烃共聚物和烯烃三元共聚物的接枝共聚物的有机溶剂悬浮液。 处理条件比已知的粘合剂制备条件得到改善。
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公开(公告)号：US5349021A
公开(公告)日：1994-09-20
申请号：US71802
申请日：1993-06-02
申请人： John M. Rooney , Narendra M. Patel , Albert A. Kveglis , Robert J. Catena , Leonard Di Leo , Selcuk Avci
发明人： John M. Rooney , Narendra M. Patel , Albert A. Kveglis , Robert J. Catena , Leonard Di Leo , Selcuk Avci
CPC分类号： C09D11/102
摘要： A thermosetting printing ink composition comprising a functional copolymer of a thermosettable polyester and a polysiloxane, a pigment, a crosslinking agent and a curing catalyst which may be a strong acid or a metal salt thereof. The composition desirably also includes a reactive diluent such as a glycol, glycol ether or alcohol. The compositions are especially useful for imprinting metal containers such as beer and soda cans.
摘要翻译： 一种热固性印刷油墨组合物，其包含可热可聚酯和聚硅氧烷的功能性共聚物，颜料，交联剂和可以是强酸或其金属盐的固化催化剂。 组合物理想地还包括反应性稀释剂，例如二醇，二醇醚或醇。 该组合物特别适用于印刷金属容器如啤酒和苏打罐。
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公开(公告)号：US4870139A
公开(公告)日：1989-09-26
申请号：US166143
申请日：1988-03-10
IPC分类号： C08F283/04
CPC分类号： C08F283/04
摘要： A water-dispersible graft copolymer of a polyamide and at least one acrylic monomer is prepared by reacting the polyamide with the acrylic monomer(s) in an alcohol solution in the presence of a free radical peroxidic initiator. The graft copolymer is particularly useful as the resin component of a water-based printing ink.
摘要翻译： 聚酰胺和至少一种丙烯酸单体的水分散性接枝共聚物是通过在自由基过氧化物引发剂的存在下在醇溶液中使聚酰胺与丙烯酸类单体反应来制备的。 接枝共聚物特别可用作水性印刷油墨的树脂成分。
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公开(公告)号：US4971626A
公开(公告)日：1990-11-20
申请号：US406985
申请日：1989-09-14
IPC分类号： C07D233/14 , C09D11/10
CPC分类号： C09D11/102 , C07D233/14
摘要： Quaternized oligourethanes, useful as dispersing agents in preparing high-solids pigment concentrates for use in manufacturing inks, especially inks intended for use in gravure and packaging applications. The novel oligourethanes are prepared by reacting an appropriate ester or alcohol with a hydroxyethylimidazoline and polyisocyanate followed by quaternization with acids or alkyl derivatives of acids.
摘要翻译： 季铵化的低聚氨酯，可用作制备用于制造油墨的高固含量颜料浓缩物的分散剂，特别是用于凹版印刷和包装应用中的油墨。 通过使适当的酯或醇与羟乙基咪唑啉和多异氰酸酯反应，然后用酸或酸的烷基衍生物进行季铵化来制备新的寡聚氨酯。
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