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    Method to make methyl isobutyl ketone and diisobutyl ketone
    2.
    发明申请
    Method to make methyl isobutyl ketone and diisobutyl ketone 有权
    制备甲基异丁基酮和二异丁基酮的方法

    公开(公告)号：US20090306434A1

    公开(公告)日：2009-12-10

    申请号：US11991277

    申请日：2006-09-26

    申请人： Jeffrey S. Sawrey ,  Richard W. Wegman

    发明人： Jeffrey S. Sawrey ,  Richard W. Wegman

    IPC分类号： C07C45/67

    CPC分类号： C07C45/68 ,  B01J23/44 ,  B01J23/868 ,  C07C45/62 ,  C07C45/66 ,  C07C45/72 ,  C07C45/73 ,  C07C49/04 ,  C07C49/203 ,  C07C49/17

    摘要： An improved method for the manufacture of MIBK and DIBK from DMK and/or IPA, by reacting, in the presence of an aldol condensation catalyst, a gaseous mixture comprising hydrogen and DMK and/or IPA. The improvement is the use of a reaction pressure greater than 207 kPa (30 psig) to increase the ratio of MIBK to DIBK. In addition a method for the manufacture of MIBK and DIBK by reacting, in the presence of an aldol condensation catalyst, a gaseous mixture consisting essentially of DMK and/or IPA and optionally water.

    摘要翻译： 在醛醇缩合催化剂存在下，通过使含有氢和DMK和/或IPA的气态混合物反应，从DMK和/或IPA制备MIBK和DIBK的改进方法。 改进之处在于使用大于207kPa（30psig）的反应压力来提高MIBK与DIBK的比例。 另外，在醛醇缩合催化剂的存在下，基本上由DMK和/或IPA组成的气态混合物和任选的水反应制备MIBK和DIBK的方法。

    Hydroformylation process
    4.
    发明授权
    Hydroformylation process 失效
    加氢甲酰化过程

    公开(公告)号：US4429165A

    公开(公告)日：1984-01-31

    申请号：US391679

    申请日：1982-06-24

    申请人： Richard W. Wegman

    发明人： Richard W. Wegman

    IPC分类号： C07C41/50 ,  C07C45/49

    CPC分类号： C07C41/50 ,  C07C45/49

    摘要： Process for selective production of acetaldehyde and dimethyl acetal by the reaction of methanol with carbon monoxide in contact with a catalyst containing cobalt atom, halide atom and a mixture of a trivalent phosphorus compound and a trivalent nitrogen compound. The amount of trivalent nitrogen compound in its mixture varies from 5 mole percent to 50 mole percent of such mixture.

    摘要翻译： 通过与含有钴原子，卤化物原子和三价磷化合物和三价氮化合物的混合物的甲醇与一氧化碳的反应的反应来选择性生产乙醛和二甲基缩醛的方法。 其混合物中三价氮化合物的量为该混合物的5摩尔％至50摩尔％。

    Hydrogenation with Cu-Al catalysts
    6.
    发明授权
    Hydrogenation with Cu-Al catalysts 失效
    用Cu-Al催化剂氢化

    公开(公告)号：US5191091A

    公开(公告)日：1993-03-02

    申请号：US825339

    申请日：1992-01-27

    申请人： Richard W. Wegman ,  David R. Bryant

    发明人： Richard W. Wegman ,  David R. Bryant

    IPC分类号： B01J23/72 ,  C07C29/149

    CPC分类号： C07C29/149 ,  B01J23/72

    摘要： A process for hydrogenating bound oxygen-containing organic feeds into their corresponding alcohols by contact with a coprecipitated copper-aluminum catalyst that has been activated by contact with reducing gas at a temperature that gradually increases.

    摘要翻译： 通过与在逐渐增加的温度下与还原气体接触而活化的共沉淀的铜 - 铝催化剂接触，将结合的含氧有机进料氢化为相应的醇。

    Production of acetate esters from alcohols using rhodium complex catalysts
    7.
    发明授权
    Production of acetate esters from alcohols using rhodium complex catalysts 失效
    使用铑配合物催化剂从醇制备乙酸酯

    公开(公告)号：US4990654A

    公开(公告)日：1991-02-05

    申请号：US462888

    申请日：1990-01-04

    申请人： Richard W. Wegman

    发明人： Richard W. Wegman

    IPC分类号： C07C69/14

    CPC分类号： C07C69/14 ,  C07C67/36

    摘要： A process for the production of acetate esters by the catalytic reaction of an alcohol of the formula ROH and carbon monoxide in contact with a homogeneous catalyst system of rhodium metal atom, a phosphorus containing ligand in which there is present at least one oxo (.dbd.O) oxygen atom attached to a phosphorus atom or a carbon atom to form a Z group and the ##STR1## group is located at least one carbon atom removed and preferably from 2-4 carbon atoms removed from the phosphorus atom of the molecules represented by the formulas ##STR2## and a halogen promoter, under mild reaction conditions, wherein R' is H, aryl, alkaryl, aralkyl or alkyl, and wherein 1 or more of said R' groups can be substituted with a Z group but not more than 3 of said R' groups in the molecule are so substituted; a is an integer from 0-4; b is an integer from 0-3; and Z is P(O)R'R'; --C(O)OR" or C(O)R", wherein R" is R'; and wherein ROH is methanol or a mixture of methanol and at least one higher alcohol.

    摘要翻译： 通过式ROH的醇与一氧化碳与铑金属原子的均相催化剂体系（含磷配体）的催化反应生产乙酸酯的方法，其中存在至少一个氧代（= O ）氧原子连接到磷原子或碳原子上以形成Z基团，并且“IMAGE”基团位于从被除去的至少一个碳原子上，优选从2-4个碳原子除去的分子的磷原子 在温和的反应条件下，其中R'是H，芳基，烷芳基，芳烷基或烷基，并且其中所述R'基团中的一个或多个可以是 被分子中被Z基团取代但不超过3个所述R'基团如此取代; a是0-4的整数; b是0-3的整数; Z为P（O）R'R'; -C（O）OR“或C（O）R”，其中R“为R'; 并且其中ROH是甲醇或甲醇与至少一种高级醇的混合物。

    GAS PHASE HYDROFORMYLATION PROCESS
    8.
    发明申请
    GAS PHASE HYDROFORMYLATION PROCESS 有权
    气相氢化方法

    公开(公告)号：US20120190894A1

    公开(公告)日：2012-07-26

    申请号：US13499317

    申请日：2010-10-06

    申请人： Richard W. Wegman

    发明人： Richard W. Wegman

    IPC分类号： C07C45/49 ,  C07C47/02

    CPC分类号： C07F9/65746 ,  C07B41/06 ,  C07C45/50 ,  C07F9/145 ,  C07C47/02

    摘要： A gas phase catalytic hydroformylation process for producing at least one aldehyde product in the presence of a transition metal-ligand complex hydroformylation catalyst and water vapor. Surprisingly, catalyst activity can be sustained by having traces of water vapor in the feed stream. Additionally, additional ligand can be added to replace lost ligand to maintain activity. In addition, it has been found that treatment of the catalyst with a buffer can rejuvenate catalyst activity.

    摘要翻译： 一种用于在过渡金属 - 配体络合物加氢甲酰化催化剂和水蒸气存在下生产至少一种醛产物的气相催化加氢甲酰化方法。 令人惊讶的是，通过在进料流中具有痕量的水蒸气可以维持催化剂活性。 另外，可以加入另外的配体以代替丢失的配体以维持活性。 此外，已经发现用缓冲液处理催化剂可以恢复催化剂活性。

    Production of carboxylic acids from alcohols using rhodium complex catalysts and organic ester source
    9.
    发明授权
    Production of carboxylic acids from alcohols using rhodium complex catalysts and organic ester source 失效
    使用铑配合物催化剂和有机酯源从醇制备羧酸

    公开(公告)号：US5026907A

    公开(公告)日：1991-06-25

    申请号：US794606

    申请日：1985-11-06

    申请人： Richard W. Wegman ,  David J. Schreck

    发明人： Richard W. Wegman ,  David J. Schreck

    IPC分类号： B01J31/18 ,  B01J31/24 ,  B01J31/26 ,  C07C51/12 ,  C07C51/56

    CPC分类号： B01J31/26 ,  B01J31/1875 ,  B01J31/2404 ,  B01J31/2495 ,  C07C51/12 ,  C07C51/56 ,  B01J2531/822

    摘要： A process for the production of organic carboxylic acids and organic carboxylic acid anhydrides by the catalytic reaction of an alcohol of the formula ROH and carbon monoxide in contact with an organic ester source and a homogeneous catalyst system of rhodium metal atom, a phosphorus containing ligand in which there is present at least one oxo (.dbd.O) oxygen atom attached to a phosphorus atom or a carbon atom to form a Z group and the ##STR1## in said Z group is located at least one carbon atom removed and preferably from 2-4 carbon atoms removed from the phosphorus atom of the molecules represented by the formulas ##STR2## and a halogen source, under mild reaction conditions, wherein R' is -H, aryl, alkaryl, aralkyl or alkyl, and wherein 1 or more of said R' groups can be substituted with a Z group but not more than 3 of said R' groups in the molecule are so substituted; a is an integer from 0-4; b is an integer from 0-3; and Z is P(O)R'R'; --C(O)OR" or C(O)R", wherein R" is R'; and wherein ROH is methanol or a mixture of methanol and at least one higher alcohol.

    摘要翻译： 通过式ROH的醇和与有机酯源接触的一氧化碳和铑金属原子的均相催化剂体系（含磷配体）的催化反应生产有机羧酸和有机羧酸酐的方法 其中存在至少一个与磷原子或碳原子连接以形成Z基团的氧代（= O）氧原子，并且所述Z基团中的“IMAGE”位于除去的至少一个碳原子，优选2- 在温和的反应条件下，由式（VI）或（VI）表示的分子的磷原子除去4个碳原子和卤素源，其中R'是-H，芳基，烷芳基，芳烷基 或烷基，并且其中所述R'基团中的一个或多个可以被Z基团取代，但在分子中不超过3个所述R'基团是如此取代的; a是0-4的整数; b是0-3的整数; Z为P（O）R'R'; -C（O）OR“或C（O）R”，其中R“为R'; 并且其中ROH是甲醇或甲醇与至少一种高级醇的混合物。

    Production of carboxylic acids from alcohols using rhodium complex catalysts
    10.
    发明授权
    Production of carboxylic acids from alcohols using rhodium complex catalysts 失效
    使用铑配合物催化剂从醇制备羧酸

    公开(公告)号：US4670570A

    公开(公告)日：1987-06-02

    申请号：US891065

    申请日：1986-07-31

    申请人： Richard W. Wegman ,  Anthony G. Abatjoglou

    发明人： Richard W. Wegman ,  Anthony G. Abatjoglou

    IPC分类号： C07C67/36 ,  B01J31/24 ,  C07B61/00 ,  C07C51/12 ,  C07C53/08 ,  C07C53/122 ,  C07C69/14 ,  C01F15/00

    CPC分类号： C07C51/12

    摘要： A process for the production of organic carboxylic acids by the catalytic reaction of an alcohol and, carbon monoxide in contact with a homogeneous catalyst system of rhodium metal atom, a phosphorus containing ligand in which there is present at least one oxo oxygen atom attached to a phosphorus atom or a carbon atom to form a Z group and the ##STR1## in said Z group is located at least one carbon atom removed from the phosphorus atom of the molecules represented by the formulas ##STR2## and a halogen promoter, under mild reaction conditions, wherein R' is aryl, alkaryl, aralkyl or alkyl, and wherein 1 or more of said R' groups can be substituted with a Z group but not more than 3 of said R' groups in the molecule are so substituted; a is an integer from 0-4; b is an integer from 0-3; and Z is P(O)R'R'; --C(O)OR" or C(O)R", wherein R" is R' or --H.

    摘要翻译： 通过醇和与铑金属原子的均相催化剂体系接触的一氧化碳，含磷配位体生产有机羧酸的方法，其中存在至少一个氧代氧原子连接到 磷原子或碳原子形成Z基团，并且所述Z基团中的“IMAGE”位于从由下式表示的分子的磷原子上除去的至少一个碳原子（V）或（ VI）和卤素促进剂，其中R'是芳基，烷芳基，芳烷基或烷基，并且其中1个或更多个所述R'基团可以被Z基团取代，但不超过3个所述R' 分子中的基团如此取代; a是0-4的整数; b是0-3的整数; Z为P（O）R'R'; -C（O）OR“或C（O）R”，其中R“为R'或-H。