摘要:
The present invention relates to a process for the manufacture of 2,2-disubstituted propiolactones via the pyrolysis of methylene diisoalkylate in the vapor phase over a fixed bed catalyst system. The reaction of the invention is as follows: ##SPC1##Wherein R is alkyl of from 1 to 4 carbon atoms and R.sup.1 is alkyl of from 1 to 4 carbon atoms or phenyl. The catalyst comprises an oxide of a metal selected from the group Ag, U, Zn, Ti, Zr, Th, Ta, Nb, Mo, W, and Sn on a suitable support. A preferred catalyst is the metal oxide-silica gel complex which results from heating the calcined residue of a salt of a metal selected from the group consisting of Ta, Ti, Nb and Zr supported upon a silica gel in the presence of nitrogen and steam at a temperature of from about 650.degree. C. to about 1000.degree. C. The process is operable at temperatures from about 240.degree. C. to about 360.degree. C. with contact times ranging from about 0.1 second to about 30.0 seconds. The gaseous ester feed may, if desired, be diluted with an inert gas such as nitrogen and the reactor may be run at atmospheric, or superatmospheric pressure.
摘要:
This invention relates to improved processes for hydrocarbon resin preparation. More particularly, the invention relates to treating the C.sub.5 and higher mixed thermally soaked hydrocarbon fraction mixture obtained in the steam cracking of propane and ethane with alumina prior to polymerizing the hydrocarbon fraction mixture with a Friedel-Crafts catalyst to form a high softening point hydrocarbon resin. The polymerized resin is then quenched or diluted, washed to remove catalyst residues, dried and hydrogenated to provide high softening point hydrocarbon resins.
摘要:
An device for use down-hole in an oil well for inducing heavy crude oil to flow into the inlet of a centrifugal pump by creating a positive pressure on the bottom inlet of the pump. The device inserts into the down-hole equipment string between the gas separator and the centrifugal pump. The device consists of an auger that attaches to and rotates with the shaft of an electric down-hole motor and a housing that surrounds the auger. The housing connects to the gas separator at the bottom end of the device and connects to the centrifugal pump at a top end of the device. The auger has tight clearance with the housing to enable the rotating auger to force the fluid upward within the housing as the auger rotates. The vanes of the auger are arranged so that the fluid is pushed with increasing pressure as it moves upward through the device to the centrifugal pump.
摘要:
This invention relates to novel hydrocarbon resins and processes for their preparation. More particularly, the invention relates to a liquid hydrocarbon resin prepared by polymerizing norbornene and xylene with a Friedel-Crafts catalyst. The polymerized resin is hydrogenated to provide water white liquid hydrocarbon resins useful as liquid tackifiers in preparing hot-melt adhesive formulations.
摘要:
A snap-fit assembled wrist mount for special receptacle rotatable tray holders for graphics and special receptacle rotatable platform holders for electronic devices.
摘要:
A low molecular weight crystalline homopolypropylene wax of low softening point is disclosed. This homopolypropylene wax is prepared from high molecular weight crystalline polypropylene by thermal degradation in the presence of a relatively high amount of peroxide.