公开(公告)号：US07329703B2

公开(公告)日：2008-02-12

申请号：US10742290

申请日：2003-12-19

申请人： Robert P. Dion ,  David H. Bank ,  Martin C. Beebe ,  Parvinder Walia ,  Peter C. LeBaron ,  James D. Oelberg ,  Mark A. Barger ,  Michael S. Paquette ,  Michael D. Read

发明人： Robert P. Dion ,  David H. Bank ,  Martin C. Beebe ,  Parvinder Walia ,  Peter C. LeBaron ,  James D. Oelberg ,  Mark A. Barger ,  Michael S. Paquette ,  Michael D. Read

IPC分类号： C08K3/34

CPC分类号： C08K3/346 ,  C08K9/04

摘要： The invention relates to polymers derived from macrocyclic oligomers containing organo clay fillers comprising a) a polymer derived from a macrocyclic oligomer; b) clay platelets; and c) the residue of one or more onium compounds having at least one ligand with a C5 or greater carbon chain and at least one ligand containing one or more functional groups having one or more active hydrogen atoms wherein the functional group is reactive with the macrocyclic oligomer and/or functional groups formed when the macrocyclic oligomer decyclizes wherein a portion of one or more of the onium compounds is ironically bound to the clay platelet and covalently bonded to the polymers derived from macrocyclic oligomers. The invention also relates to processes for preparing such compositions. Furthermore, the invention relates to articles prepared from organoclay filled polymer compositions.

摘要翻译： 本发明涉及衍生自含有机粘土填料的大环低聚物的聚合物，其包含a）衍生自大环低聚物的聚合物; b）粘土血小板; 和c）一种或多种具有至少一个具有C 5或更高碳链的配体和至少一种含有一个或多个具有一个或多个活性氢原子的官能团的配体的鎓化合物的残基，其中 所述官能团与大环低聚物脱环形成的大环低聚物和/或官能团反应，其中一种或多种鎓化合物的一部分与粘土片状物结合，并与衍生自大环低聚物的聚合物共价键合。 本发明还涉及制备这种组合物的方法。 此外，本发明涉及由有机粘土填充聚合物组合物制备的制品。

公开(公告)号：US20130096251A1

公开(公告)日：2013-04-18

申请号：US13700961

申请日：2011-06-21

申请人： Paul J. Popa ,  Gary E. Spilman ,  Zenon Lysenko ,  William A. Koonce ,  David A. Bobb ,  Martin C. Beebe ,  Thomas C. Thyne

发明人： Paul J. Popa ,  Gary E. Spilman ,  Zenon Lysenko ,  William A. Koonce ,  David A. Bobb ,  Martin C. Beebe ,  Thomas C. Thyne

IPC分类号： C08G18/83 ,  C08G18/12

CPC分类号： C08G18/837 ,  C08G18/10 ,  C08G18/12 ,  C08G18/289 ,  C08G18/4891 ,  C08G18/7621 ,  C09D175/04 ,  C09J175/04

摘要： Embodiments of the invention relate to crosslinkable silyl group-containing polymers and methods of producing them. In one embodiment a method of producing a silyl polymer is provided. The method includes reacting at least one natural oil based polyol with at least one isocyanate to form at least one prepolymer having at least one NCO group. The at least one natural oil based polyol includes the reaction product of hydroxymethylated fatty acids or esters thereof and at least one polyol initiator. The prepolymer having at least one NCO group is reacted with at least one amino functional alkoxy silane to form the silyl polymer, such that the silyl polymer includes at least one crosslinkable silyl group, at least one urethane group, and at least one urea group in each molecule.

摘要翻译： 本发明的实施方案涉及可交联的含甲硅烷基的聚合物及其制备方法。 在一个实施方案中，提供了产生甲硅烷基聚合物的方法。 所述方法包括使至少一种天然油基多元醇与至少一种异氰酸酯反应以形成至少一种具有至少一个NCO基团的预聚物。 所述至少一种天然油基多元醇包括羟甲基化脂肪酸或其酯与至少一种多元醇引发剂的反应产物。 具有至少一个NCO基团的预聚物与至少一个氨基官能的烷氧基硅烷反应以形成甲硅烷基聚合物，使得甲硅烷基聚合物包括至少一个可交联甲硅烷基，至少一个氨基甲酸酯基和至少一个脲基 每个分子。