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    Polymerization using late transition metal catalyst complexes formed in situ
    3.
    发明授权
    Polymerization using late transition metal catalyst complexes formed in situ 失效
    使用晚期形成的过渡金属催化剂复合物进行聚合

    公开(公告)号：US06506859B1

    公开(公告)日：2003-01-14

    申请号：US09642487

    申请日：2000-08-18

    申请人： Abhimanyu O. Patil ,  Robert T. Stibrany ,  Stephen Zushma ,  Enock Berluche ,  Donald N. Schulz

    发明人： Abhimanyu O. Patil ,  Robert T. Stibrany ,  Stephen Zushma ,  Enock Berluche ,  Donald N. Schulz

    IPC分类号： C08F442

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/02 ,  C08F4/54 ,  C08F2500/03 ,  C08F220/12

    摘要： The invention is directed towards the formation of polymers and copolymers using late transition metal polymerization catalyst complexes which are formed in situ. In the first process step of the instant invention, a composition having the formula MXZn is simultaneously contacted with a ligand and an activating cocatalyst. Referring to the formula, M is selected from the group consisting of Cu, Ag, and Au; X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert; Z is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, a neutral coordinating ligand, and any other moiety into which a monomer can insert; n equals 0, 1 or 2. In the second process step of the instant invention, olefinic monomers are contacted with the activated catalyst composition under polymerization conditions.

    摘要翻译： 本发明涉及使用在原位形成的后过渡金属聚合催化剂络合物形成聚合物和共聚物。 在本发明的第一工艺步骤中，具有式MXZn的组合物与配体和活化助催化剂同时接触。 参考式，M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃和 单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃， 中性配位配体和单体可插入的任何其它部分; n等于0,1或2.在本发明的第二工艺步骤中，烯烃单体在聚合条件下与活化的催化剂组合物接触。

    Chromium complexes and their use in olefin polymerization
    4.
    发明授权
    Chromium complexes and their use in olefin polymerization 失效
    铬络合物及其在烯烃聚合中的应用

    公开(公告)号：US07498287B2

    公开(公告)日：2009-03-03

    申请号：US11904056

    申请日：2007-09-25

    申请人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    发明人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    IPC分类号： C08F4/69

    CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

    摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful polymerizing olefinic monomers.

    摘要翻译： 具有式I的组合物，其中R1和R2独立地为氢，C1至C12直链和支链烷基，C3至C12环烷基，芳基，C1至C12烷氧基，F，C1，SO3，C1至C12全氟烷基和N（​​CH3） 2，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基和2,2,2-三氟乙基，A是-C（R 4） - ， - （CH 2） x - ， - （CH 2）x NH（CH 2）x - 或-CY 2 CY 2 - ，其中R 4是烃基，卤代烃基或具有1至12个碳原子的烷氧基，x是1至12的整数，Y 是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，有用的是使烯烃单体聚合。

    Chromium complexes and their use in olefin polymerization
    6.
    发明授权
    Chromium complexes and their use in olefin polymerization 失效
    铬络合物及其在烯烃聚合中的应用

    公开(公告)号：US07498390B2

    公开(公告)日：2009-03-03

    申请号：US11904057

    申请日：2007-09-25

    申请人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    发明人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    IPC分类号： C08F4/69

    CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

    摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, ps where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.

    摘要翻译： 具有式I的组合物，其中R1和R2独立地为氢，C1至C12直链和支链烷基，C3至C12环烷基，芳基，C1至C12烷氧基，F，C1，SO3，C1至C12全氟烷基和N（​​CH3） 2，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基和2,2,2-三氟乙基，A是-C（R 4） - ， - （CH 2） x - ， - （CH 2）x NH（CH 2）x - 或-CY 2 CY 2 - ，其中R 4是烃基，卤代烃基或具有1至12个碳原子的烷氧基，x是1至12的整数， Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，可用于聚合烯烃单体。

    Chromium complexes and their use in olefin polymerization
    7.
    发明授权
    Chromium complexes and their use in olefin polymerization 有权
    铬络合物及其在烯烃聚合中的应用

    公开(公告)号：US07297805B2

    公开(公告)日：2007-11-20

    申请号：US11152802

    申请日：2005-06-14

    申请人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    发明人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    IPC分类号： C07F11/00 ,  C08F4/69

    CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

    摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.

    摘要翻译： 具有式I的组合物，其中R 1和R 2独立地是氢，C 1至C 12直链 和支链烷基，C 3至C 12环烷基，芳基，C 1至C 12烷氧基，F， Cl，SO 3，C 1至C 12全氟烷基和N（​​CH 3 3）2 R 3，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 1〜 C 1 -C 4 - （CH 3） - ，其中C（R 4） - ， x（CH 2）2 - ， - （CH 2 CH 2）x NH 2（CH 2） ）其中R 4是烃基，卤代烃基，卤代烃基， 或1至12个碳原子的烷氧基，x是1至12的整数，Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，可用于聚合烯烃单体。

    Late transition metal complexes, their use as catalysts and polymers therefrom
    8.
    发明授权
    Late transition metal complexes, their use as catalysts and polymers therefrom 失效
    后期过渡金属络合物，它们用作催化剂和聚合物

    公开(公告)号：US06479425B1

    公开(公告)日：2002-11-12

    申请号：US09642488

    申请日：2000-08-18

    申请人： Robert T. Stibrany ,  Smita Kacker

    发明人： Robert T. Stibrany ,  Smita Kacker

    IPC分类号： B01J3118

    CPC分类号： C08F10/00 ,  B01J23/72 ,  B01J31/143 ,  B01J31/1805 ,  B01J31/1825 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  C07F1/005 ,  C07F1/08 ,  C08F10/02 ,  C08F110/02 ,  C08F210/02 ,  C08F220/10 ,  C08F4/54 ,  C08F4/44 ,  C08F4/50 ,  C08F220/12

    摘要： The invention provides a novel metal complex which, when used with an activating cocatalyst, provides a novel catalyst composition. The invention also provides a polymerization method which utilizes the catalyst composition to produce polymers and copolymers containing polar monomer groups. More specifically, the invention comprises a composition comprising the formula LMXZn wherein X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert. M is selected from the group consisting of Cu, Ag, and Au. L is a nitrogen-containing bidentate ligand having more than two nitrogen atoms. Z is a neutral coordinating ligand and n equals 0, 1, or 2.

    摘要翻译： 本发明提供了一种新型金属络合物，当与活化助催化剂一起使用时，提供了新的催化剂组合物。 本发明还提供一种利用催化剂组合物制备含有极性单体基团的聚合物和共聚物的聚合方法。 更具体地说，本发明包括一种包含式LMXZn的组合物，其中X选自卤化物，氢化物，三氟甲磺酸酯，乙酸酯，硼酸酯，C 1至C 12烷基，C 1至C 12烷氧基，C 3至C 12环烷基，C 3至C 12环烷氧基 ，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃和单体可以插入的任何其它部分。 M选自Cu，Ag和Au。 L是具有两个以上氮原子的含氮二齿配位体。 Z是中性配位配体，n等于0,1或2。

    Manganese oligomer containing main group elements
    9.
    发明授权
    Manganese oligomer containing main group elements 失效
    含有主要组分元素的马来西亚低分子

    公开(公告)号：US5099045A

    公开(公告)日：1992-03-24

    申请号：US698046

    申请日：1990-05-10

    申请人： Sergiu M. Gorun ,  Robert T. Stibrany

    发明人： Sergiu M. Gorun ,  Robert T. Stibrany

    IPC分类号： C07F13/00

    CPC分类号： C07F13/005

    摘要： One embodiment of the present invention is based on the discovery of another hexadecanuclear manganese aggregate having a core of 6 barium ions surrounding a carbonate ion. Stated differently, one embodiment of the present invention comprises a composition of matter having the formula:[Mn.sub.16 Ba.sub.10 O.sub.4 (OH).sub.4 (CO.sub.3).sub.5 L.sub.8 ].xH.sub.2 Owherein x is an integer ranging from about 0 to about 120 and L is a ligand.Another embodiment of the present invention comprises a method of preparing the novel compounds of the present invention, which method comprises preparing a chloride free aqueous solution containing a source of carbonate ion selected from sodium carbonate, CO.sub.2 and mixtures thereof and a compound having the formula:Ba.sub.2 [Mn.sub.4 (O)(OH)(O.sub.2 CR).sub.2 L.sub.2 ].xH.sub.2 Owherein R is hydrogen or a hydrocarbyl group, x is an integer ranging from 0 to about 30, and L is a ligand having formula I set forth above, and thereafter allowing the reaction mixture to stand for a time sufficient for a compound having the formula:[Mn.sub.16 Ba.sub.10 O.sub.4 (OH).sub.4 (CO.sub.3).sub.5 L.sub.8 ].xH.sub.2 Oto form.The compounds of the present invention have magnetic properties rendering them particularly suitable for use in magnetic thermometry and magnetic fluids.

    摘要翻译： 本发明的一个实施方案是基于碳酸根离子周围具有6个钡离子核心的另一个十六碳核锰骨料的发现。 换句话说，本发明的一个实施方案包括具有下式的物质组合物：[Mn16Ba10O4（OH）4（CO3）5L8]·xH2O其中x为约0至约120的整数，L为配体。 本发明的另一个实施方案包括制备本发明的新化合物的方法，该方法包括制备含有选自碳酸钠，CO 2及其混合物的碳酸根离子源的无氯化物水溶液和具有下式的化合物： Ba2 [Mn4（O）（OH）（O2CR）2L2]·xH2O其中R为氢或烃基，x为0至约30的整数，L为上述式I的配体， 使反应混合物放置足够的时间，使其具有下式的化合物：[Mn16Ba10O4（OH）4（CO3）5L8]·xH2O形成。 本发明的化合物具有磁性，使得它们特别适用于磁测温和磁性流体。