摘要:
Disclosed are compounds, having the general formula: ##STR1## wherein: m=0, 1, 2; n=0, 1 with the condition that when m=0, also n=0;p=0, 1; q=1, 2;X is either oxygen or sulphur;A=N, CH;R is H, CH.sub.3, F;R.sub.1 is selected from chlorine, bromine, fluorine, CF.sub.3, phe=nyl, C.sub.1 -C.sub.2 -alkoxy, C.sub.1 -C.sub.2 -haloalkoxy, alkylthio, haloalkyl=thio, wherein the halogen is Cl, Br, F;R.sub.2 is selected from H, chlorine, bromine, fluorine;R.sub.f is selected from the group formed by alkyls containing from 2 to 4 carbon atoms, and containing at least 4 atoms of halogen selected from F, Cl and Br, of which at least 3 are F atoms; alkenyls and alkynyls containing up to 4 carbon atoms, containing at least 2 F atoms and, optionally, other halogens selected between Cl and Br.The present invention relates to azolyl-derivatives, more particularly to substituted azolyldioxanes and azolyldioxolanes, endowed with high fungicidal activity, to the process for their preparation, and to their related use in the agrarian field.
摘要翻译:公开了具有以下通式的化合物:其中:m = 0,1,2; n = 0,1,条件是当m = 0时,n = 0; p = 0,1, q = 1,2; X是氧或硫; A = N,CH; R为H,CH 3,F; R 1选自氯,溴,氟,CF 3,phe = nyl,C 1 -C 2 - 烷氧基,C 1 -C 2卤代烷氧基,烷硫基,卤代烷基=硫代,其中卤素是Cl,Br,F; R2选自H,氯,溴,氟; Rf选自由含有2至4个碳原子的烷基形成的基团,并且含有至少4个选自F,Cl和Br的卤素,其中至少3个是F原子; 含有至多4个碳原子的烯基和炔基,其含有至少2个F原子,以及任选的选自Cl和Br之间的其它卤素。 本发明涉及唑类衍生物,更具体地涉及具有高杀真菌活性的取代的azolyldioxanes和azolyldioxolanes,其制备方法及其在土地领域的相关用途。
摘要:
Fungicidal compounds having the formula: ##STR1## wherein: R.sup.1 is selected from the group consisting of F, Cl, Br, CF.sub.3, a phenyl, a C.sub.1 -C.sub.2 alkoxy, a C.sub.1 -C.sub.2 haloalkoxy, an alkylthio, and a haloalkylthio radical, in which the halogen is F, Cl, or Br;R.sup.2 is selected from the group consisting of H, F, Cl, Br, and CF.sub.3 ;R.sup.3 is H, a C.sub.1 -C.sub.4 alkyl or a C.sub.3 -C.sub.6 cycloalkyl radical;Y is selected from the group consisting of H, CH.sub.3, OH, CN, and F;n is 1, 2, 3, 4 with the proviso that Y is OH when n is 1;m is 0 or 1;X is O or S;Rf is selected from the group consisting of C.sub.1 -C.sub.5 polyfluoroalkyl, C.sub.2 -C.sub.4 polyfluoroalkenyl, polyfluoroalkoxyalkyl and polyfluoroalkoxyalkenyl radicals, each one of them containing at least two fluorine atoms and, optionally, other halogen atoms selected from the group consisting of Cl and Br; andZ is CH or N.
摘要:
There are described compounds having general formula: ##STR1## wherein: R.sup.1 is selected from the group comprising F, Cl, Br, CF.sub.3, a phenyl, a C.sub.1 -C.sub.2 alkoxy, a C.sub.1 -C.sub.2 haloalkoxy, an alkylthio, a haloalkylthio radical, in which the halogen is F, Cl, Br;R.sup.2 is selected from the group comprising H, F, Cl, Br, CF.sub.3 ;R.sup.3, R.sup.4 and R.sup.5, which may be the same or different, are H, a C.sub.1 -C.sub.4 alkyl or a C.sub.3 -C.sub.6 cycloalkyl radical, on condition that R.sup.5 is different from R.sup.3, when R.sup.4 is H;Y is selected from the group comprising H, CH.sub.3, OH, CN, F;n is 1,2;m is 0,1;X is O or S;Rf is selected from the group consisting of C.sub.1 -C.sub.5 polyfluoroalkyl, C.sub.2 -C.sub.4 polyfluoroalkenyl, polyfluoroalkoxyalkyl and polyfluoroalkoxyalkenyl radicals, everyone of them containing at least two fluorine atoms and, optionally, other halogen atoms selected from Cl and Br;Z is CH or N.
摘要:
Disclosed are compounds having the formula: ##STR1## wherein: m=0, 1;n=0, 1;Z=CH, N;R.sub.1 is selected from chlorine, bromine, fluorine, CF.sub.3, phenyl, C.sub.1 -C.sub.2 -alkoxy, C.sub.1 -C.sub.2 -haloalkoxy, alkylthio, and haloalkylthio, wherein the halogen is Cl, Br, F;R.sub.2 is H, fluorine, chlorine, or bromine;R.sub.3 represents H, CH.sub.3, CN, or also F when m=1 or when n=1 and R.sub.4, R.sub.5 are H;R.sub.4, R.sub.5 are independently H or F;R.sub.3 and R.sub.4, furthermore, when m=0, may represent, taken together, a second bond between the two carbon atoms to which they are linked in formula (I); andR.sub.f is selected from the group consisting of polyfluoroalkyls, polyfluoroalkenyls and polyfluoroalkynyls containing up to 4 carbon atoms, containing at least 2 F atoms and, optionally, other halogens selected from Cl and Br.Anti-fungal compositions containing these new compounds.
摘要:
Compounds having the formula: ##STR1## wherein: m=1 or 2;q=1 or 2;Y=a haloethylene or haloethenyl group;X is oxygen or sulfur;A=N or CH;R is H, CH.sub.3 or F;R.sub.1 is selected from the group comprising chlorine, bromine, fluorine, CF.sub.3, phenyl, C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 haloalkoxy, alkylthio, haloalkylthio radical, wherein the halogen is Cl, Br or F;R.sub.2 is selected from the group comprising H, chlorine, bromine or fluorine; andR.sub.f is a C.sub.1 -C.sub.5 polyfluoroalkyl or a C.sub.2 -C.sub.4 polyfluoroalkenyl radical containing at least 3 fluorine aotms and, optionally, other halogen atoms selected from the group comprising Cl and Br. These compounds have good fungicidal activity.
摘要:
Compounds having the formula: ##STR1## wherein: m=1 or 2;q=1 or 2;Y=a haloethylene or haloethenyl group;X is oxygen or sulfur;A=N or CH;R is H, CH.sub.3 or F;R.sub.1 is selected from the group comprising chlorine, bromine, fluorine CF.sub.3, phenyl, C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 haloalkoxy, alkylthio, haloalkylthio radical, wherein the halogen is Cl, Br or F;R.sub.2 is selected from the group comprising H, chlorine, bromine or fluorine; andR.sub.f is a C.sub.1 -C.sub.5 polyfluoroalkyl or a C.sub.2 -C.sub.4 polyfluoroalkenyl radical containing at least 3 fluorine atoms and, optionally, other halogen atoms selected from the group comprising Cl and Br. These compounds have good fungicidal activity.
摘要翻译:具有下式的化合物:其中:m = 1或2; q = 1或2; Y =卤代乙烯基或卤代乙烯基; X是氧或硫; A = N或CH; R为H,CH 3或F; R 1选自氯,溴,氟CF 3,苯基,C 1 -C 2烷氧基,C 1 -C 2卤代烷氧基,烷硫基,卤代烷硫基,其中卤素是Cl,Br或F; R2选自H,氯,溴或氟; 并且Rf是含有至少3个氟原子的C1-C5多氟烷基或C2-C4多氟烯基,以及任选的选自Cl和Br的其它卤素原子。 这些化合物具有良好的杀真菌活性。
摘要:
A method of fighting fungus infections by using compounds having the formula: ##STR1## wherein: R is H, a C.sub.1 -C.sub.4 alkyl, an alkenyl, or an alkynyl radical; n is 1 or 2;A represents a C.sub.1 -C.sub.6 alkylene bridge, an arylene or a heterocyclic bridge;X represents O, S, SO, SO.sub.2 ; andR.sup.1 is selected from the group consisting of C.sub.1 -C.sub.6 alkyl radicals, a phenyl radical, optionally substituted, polyfluoroalkyl radicals containing from 1 to 4 carbon atoms and at least 2 fluorine atoms, polyfluoroalkenyl radicals containing from 2 to 4 carbon atoms and at least 2 fluorine atoms, but excluding compounds having the formula (I) wherein A is an alkylene radical, n is 2, and R.sup.1 is a C.sub.1 -C.sub.6 alkyl radical.
摘要:
There are disclosed compounds having general formula (I): ##STR1## wherein: X is H, a phenyl, phenylalkyl, phenylcarbonyl, phenyloxy group, optionally substituted with a halogen; Y is N or CH; R.sup.1 is H or a phenyl group; R.sup.2 and R.sup.3, equal or different, are H, an alkyl, alkoxy group or together they are an atom of ketonic oxygen; R.sup.4 and R.sup.5, equal or different, are H or an alkyl group; R.sup.6 and R.sup.7, equal or different, are H, an alkyl group or one of them forms with R.sup.2 or R.sup.3 an alkylidenic or etheric bridge; or they form a dioxyalkylidenic or alkylidenic ring; m=0, 1; n=0, 1, 2, 3. The compounds are endowed with fungicide and systemic properties.
摘要:
There are disclosed compounds having the formula (I) and (II): ##STR1## wherein: R' and R", equal to or different from each other, are a C.sub.1 -C.sub.7 alkyl, a C.sub.3 -C.sub.7 cycloalkyl, a heterocycloalkyl, alkoxyalkyl, dialkoxyalkyl, haloalkyl;X is a halogen, a C.sub.1 -C.sub.4 alkyl, a haloalkyl, alkoxyl, phenyl; andY is H or a halogen.
摘要:
Described herein are .alpha.-(1-triazolyl)-keto-derivatives of general formula: ##STR1## wherein R is phenyl or heteroaryl, optionally substituted, alkyl; R.sup.1 is alkoxyl, optionally substituted aryloxy, alkyl, alkenyl, alkynyl, alkoxyalkyl, alkoxycarbonyl, cyano, optionally substituted phenyl, or, along with R.sup.2, an alkylidene; R.sup.2 is H or, along with R.sup.1, an alkylidene; R.sup.3 is alkylcarbonyl, alkoxycarbonyl, arylcarbonyl, cyano or alkoxyalkylcarbonyl; such compounds being endowed with a high fungicidal activity.
摘要翻译:本文描述的是以下通式的α-(1-三唑基) - 酮衍生物:其中R是苯基或杂芳基,任选取代的烷基; R 1为烷氧基,任选取代的芳氧基,烷基,烯基,炔基,烷氧基烷基,烷氧基羰基,氰基,任选取代的苯基,或与R 2一起为亚烷基; R2是H或与R1一起是亚烷基; R3是烷基羰基,烷氧基羰基,芳基羰基,氰基或烷氧基烷基羰基; 这种化合物被赋予高杀真菌活性。