公开(公告)号：US4218376A

公开(公告)日：1980-08-19

申请号：US962711

申请日：1978-11-21

申请人： Ryo Matsuura ,  Tomio Segawa ,  Yukio Nomiyama ,  Yoichi Kumada ,  Hideo Sawada

发明人： Ryo Matsuura ,  Tomio Segawa ,  Yukio Nomiyama ,  Yoichi Kumada ,  Hideo Sawada

IPC分类号： C09B47/10

CPC分类号： C09B47/10

摘要： Highly chlorinated copper phthalocyanine is produced by charging chlorine under an elevated pressure of 1 to 20 Kg/cm.sup.2 (gauge) into a solution of a copper phthalocyanine in the presence of pyrosulfuryl chloride and a catalyst of sulfur or sulfur chloride.Pyrosulfuryl chloride can be formed by a reaction of chlorosulfonic acid with chlorine and sulfur or sulfur chloride under an elevated pressure.An auxiliary catalyst of iodine, iodine chloride or a metal chloride can be incorporated to improve the chlorination.

摘要翻译： 通过在1至20Kg / cm 2（表压）的升高的压力下，将氯代铜酞菁在硫代硫酰氯和硫或氯化硫的催化剂的溶液中加入到高氯化铜酞菁中。 焦硫磺酰氯可以通过氯磺酸与氯和硫或氯化硫在升高的压力下反应形成。 可以引入碘，氯化碘或金属氯化物的辅助催化剂以改善氯化。

公开(公告)号：US20080039592A1

公开(公告)日：2008-02-14

申请号：US11659811

申请日：2005-08-11

申请人： Hideo Sawada ,  Junji Tagami ,  Toru Nikaido ,  Khairul Matin ,  Yoshinori Kadoma ,  Eiichi Masuhara ,  Koichi Okada ,  Junichi Yamauchi

发明人： Hideo Sawada ,  Junji Tagami ,  Toru Nikaido ,  Khairul Matin ,  Yoshinori Kadoma ,  Eiichi Masuhara ,  Koichi Okada ,  Junichi Yamauchi

IPC分类号： C08G61/02 ,  A61C5/00

CPC分类号： A61K6/083 ,  A61K6/0017 ,  A61K6/0023 ,  C08L33/00

摘要： A dental polymerizable composition comprising (a) a fluorine compound comprising a chain polymer having a main chain comprising a monomer unit having a hydrophilic group, and terminal groups comprising a fluoroalkyl group at each of both ends of the main chain; (b) a polymerizable monomer; and (c) a polymerization initiator. The dental polymerizable composition can be suitably used, for example, for dental composite resins, such as dental composite filler materials, crowning materials, and bonding materials; dental adhesive agents, such as teeth-straightening adhesive agents, cavity-coating adhesive agents, and tooth fissure sealing materials; denture base materials, denture base mucosal adjusting materials, fissure sealants, coating agents applied to tooth surface or dental prosthetic, surface glazes, and the like, and especially for various coating applications, for example, a fissure sealant, a coating agent to tooth surface or dental prosthetic, surface stains or a surface glaze, a hypersensitive inhibitor, a dental manicure, or the like.

摘要翻译： 1.一种牙科用聚合性组合物，其含有（a）含有具有主链的链状聚合物的氟化合物，所述主链含有具有亲水基团的单体单元和在所述主链的两端各自含有氟代烷基的末端基团; （b）可聚合单体; 和（c）聚合引发剂。 牙科用聚合性组合物可以适用于例如牙科用复合树脂，例如牙科复合填料，冠状材料和粘合材料; 牙齿粘合剂如牙齿矫直粘合剂，空腔涂布粘合剂和牙齿裂缝密封材料; 义齿基材，假牙基底粘膜调节材料，裂缝密封剂，涂在牙齿表面上的涂布剂或牙齿假体，表面釉料等，特别是用于各种涂覆应用，例如裂缝密封剂，牙齿表面涂层剂 或牙齿假体，表面污渍或表面釉，过敏性抑制剂，牙齿修指甲等。

公开(公告)号：US07144962B2

公开(公告)日：2006-12-05

申请号：US10477785

申请日：2002-08-08

申请人： Hidetaka Takahashi ,  Hideo Sawada

发明人： Hidetaka Takahashi ,  Hideo Sawada

IPC分类号： C08C19/18 ,  C08C19/25

CPC分类号： C08J7/047 ,  C08J7/12 ,  C08J2321/00 ,  C08J2401/10 ,  C08K5/02 ,  C08K5/54 ,  Y10T428/31663 ,  C08L21/00

摘要： A method for the surface treatment of rubber, a process for production of a rubber article, and a rubber composition wherein a structure derived from a fluorine compound containing a fluoroalkyl at both ends of its molecule are joined to a polymer main chain of crosslinked rubber in the vicinity of the surface of a rubber base (molding). The method involves causing the fluorine compound and a silane coupling agent to exist in the vicinity of the surface of a rubber base, and heat-treating the rubber base. The production process comprises compounding and mixing raw rubber and a silane coupling agent to obtaining a molding of crosslinked rubber and heating the molding. The rubber composition contains raw rubber, a crosslinking agent, the fluorine compound and a silane coupling agent.

摘要翻译： 橡胶的表面处理方法，橡胶制品的制造方法以及橡胶组合物，其中分子的两端含氟烷基的氟化合物的结构与交联橡胶的聚合物主链接合 橡胶基材表面附近（成型）。 该方法包括使氟化合物和硅烷偶联剂存在于橡胶基材表面附近，并对橡胶基材进行热处理。 制备方法包括混合生橡胶和硅烷偶联剂以获得交联橡胶的模塑并加热模塑。 橡胶组合物含有生橡胶，交联剂，氟化合物和硅烷偶联剂。

公开(公告)号：US4631151A

公开(公告)日：1986-12-23

申请号：US702632

申请日：1985-02-19

申请人： Michio Kobayashi ,  Masato Yoshida ,  Hideo Sawada ,  Hidehiko Hagii ,  Kazuyoshi Aoshima

发明人： Michio Kobayashi ,  Masato Yoshida ,  Hideo Sawada ,  Hidehiko Hagii ,  Kazuyoshi Aoshima

IPC分类号： C07B31/00 ,  C07B37/04 ,  C07B39/00 ,  C07C17/00 ,  C07C17/32 ,  C07C22/02 ,  C07C22/08 ,  C07C41/00 ,  C07C41/30 ,  C07C43/225 ,  C07C53/21 ,  C07C67/00 ,  C07C69/145 ,  C07C69/63 ,  C09F7/00 ,  C07C19/08

CPC分类号： C07B39/00 ,  C07C17/32 ,  C07C41/30 ,  C07C53/21

摘要： A fluorine-containing aromatic derivative is produced by causing a di(haloacyl)peroxide to react upon benzene, a mono-substituted benzene, naphthalene, or a mono-substituted naphthalene thereby introducing an X(CF.sub.2).sub.n -group into the benzene ring or the naphthalene ring.

摘要翻译： 通过使二（卤代酰基）过氧化物在苯，单取代的苯，萘或单取代萘上反应从而将X（CF 2）n - 基团引入苯环或 萘环。

公开(公告)号：US07943802B2

公开(公告)日：2011-05-17

申请号：US11715495

申请日：2007-03-08

申请人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

发明人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

IPC分类号： C07C27/10

CPC分类号： C07F7/21

摘要： A nanoparticle composite includes a host molecule including a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at opposite terminals thereof and a three-dimensional silica network section, and having a structure represented by the following formula (1): where X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group, independent NHR group (where R is alkyl group) or independent OCY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O, independent NH—C═O or independent NR—C═O (where R is alkyl group); n is 1≦n≦10; and m is 1≦m≦n; and a guest molecule included in the host molecule.

摘要翻译： 纳米颗粒复合材料包括主体分子，其包括分别具有相对端的亲水基团和氟代烷基的链低聚物部分和三维二氧化硅网络部分，并具有由下式（1）表示的结构：其中X是 亲水基团，独立的OH基团，独立的NCO基团，独立的NH2基团，独立的NHR基团（其中R是烷基）或独立的OCY基团（其中Y是亲水基团）; RF是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O，独立的O = C-O，独立的NH-C = O或独立的NR-C = O（其中R是烷基）; n为1＆nlE; n＆nlE; 10; 并且m是1＆nlE; m＆nlE; n; 和宿主分子中包含的客体分子。

公开(公告)号：US07683103B2

公开(公告)日：2010-03-23

申请号：US11659811

申请日：2005-08-11

申请人： Hideo Sawada ,  Junji Tagami ,  Toru Nikaido ,  Khairul Matin ,  Yoshinori Kadoma ,  Eiichi Masuhara ,  Koichi Okada ,  Junichi Yamauchi

发明人： Hideo Sawada ,  Junji Tagami ,  Toru Nikaido ,  Khairul Matin ,  Yoshinori Kadoma ,  Eiichi Masuhara ,  Koichi Okada ,  Junichi Yamauchi

IPC分类号： A61K6/00

CPC分类号： A61K6/083 ,  A61K6/0017 ,  A61K6/0023 ,  C08L33/00

摘要： A dental polymerizable composition comprising (a) a fluorine compound comprising a chain polymer having a main chain comprising a monomer unit having a hydrophilic group, and terminal groups comprising a fluoroalkyl group at each of both ends of the main chain; (b) a polymerizable monomer; and (c) a polymerization initiator. The dental polymerizable composition can be suitably used, for example, for dental composite resins, such as dental composite filler materials, crowning materials, and bonding materials; dental adhesive agents, such as teeth-straightening adhesive agents, cavity-coating adhesive agents, and tooth fissure sealing materials; denture base materials, denture base mucosal adjusting materials, fissure sealants, coating agents applied to tooth surface or dental prosthetic, surface glazes, and the like, and especially for various coating applications, for example, a fissure sealant, a coating agent to tooth surface or dental prosthetic, surface stains or a surface glaze, a hypersensitive inhibitor, a dental manicure, or the like.

摘要翻译： 1.一种牙科用聚合性组合物，其含有（a）含有具有主链的链状聚合物的氟化合物，所述主链含有具有亲水基团的单体单元和在所述主链的两端各自含有氟代烷基的末端基团; （b）可聚合单体; 和（c）聚合引发剂。 牙科用聚合性组合物可以适用于例如牙科用复合树脂，例如牙科复合填料，冠状材料和粘合材料; 牙齿粘合剂如牙齿矫直粘合剂，空腔涂布粘合剂和牙齿裂缝密封材料; 义齿基材，假牙基底粘膜调节材料，裂缝密封剂，涂在牙齿表面上的涂布剂或牙齿假体，表面釉料等，特别是用于各种涂覆应用，例如裂缝密封剂，牙齿表面涂层剂 或牙齿假体，表面污渍或表面釉，过敏性抑制剂，牙齿修指甲等。

公开(公告)号：US20090047518A1

公开(公告)日：2009-02-19

申请号：US12282314

申请日：2007-03-06

申请人： Hideo Sawada ,  Masashi Sugiya ,  Ryo Ebara ,  Katsuhiko Tsunashima

发明人： Hideo Sawada ,  Masashi Sugiya ,  Ryo Ebara ,  Katsuhiko Tsunashima

IPC分类号： B32B1/00

CPC分类号： C09C1/3081 ,  B82Y30/00 ,  C01B33/149 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/62 ,  C01P2004/64 ,  C09C1/30 ,  Y10T428/2995

摘要： An object of the invention is to provide a substance enabling uniformly dispersing an ionic liquid or a phosphonium salt in various solvents, resin materials, and the like.A powdery silica composite particle obtained by a surface treatment step comprising providing a reaction solution by mixing a silica sol containing a core silica particle having an average particle size of 5 to 200 nm, an alkoxysilane, and an ionic liquid and hydrolyzing the alkoxysilane by addition of an acid or an alkali to the reaction solution to surface-treat the core silica particle.

摘要翻译： 本发明的目的是提供一种能够将离子液体或鏻盐均匀分散在各种溶剂，树脂材料等中的物质。 通过表面处理步骤得到的粉状二氧化硅复合颗粒，其包括通过混合含有平均粒度为5〜200nm的核心二氧化硅粒子的二氧化硅溶胶，烷氧基硅烷和离子液体来提供反应溶液，并通过加成水解该烷氧基硅烷 的酸或碱加到反应溶液中以表面处理芯二氧化硅颗粒。

公开(公告)号：US20090036599A1

公开(公告)日：2009-02-05

申请号：US12293949

申请日：2007-03-16

申请人： Hideo Sawada ,  Masashi Sugiya ,  Ryo Ebara

发明人： Hideo Sawada ,  Masashi Sugiya ,  Ryo Ebara

IPC分类号： C08L75/14 ,  C08G18/71

CPC分类号： C08G18/8108 ,  C08F220/24 ,  C08F220/36 ,  C08F220/58 ,  C08G18/302 ,  C08G18/8116

摘要： A material enabling uniformly dispersing an ionic liquid or a phosphonium salt in various solvents or resin materials is provided. The material is powdery particles of a three-dimensionally crosslinked clathrate obtained by a process including a first-order polymerization step in which a fluoroalkanoyl peroxide compound, a monofunctional monomer, and a polyfunctional monomer having an olefinic double bond and an isocyanate group are reacted to one another to obtain a fluoroalkyl-containing cooligomer and a crosslinking step including the substeps of mixing the fluoroalkyl-containing cooligomer and an ionic liquid or a phosphonium salt and causing the cooligomer to react with itself at the isocyanate groups thereof in the presence of the ionic liquid or the phosphonium salt to obtain powdery three-dimensionally crosslinked clathrate particles.

摘要翻译： 提供能够将离子液体或鏻盐均匀分散在各种溶剂或树脂材料中的材料。 该材料是通过包括一级聚合步骤的方法获得的三维交联的包合物的粉末颗粒，其中氟代烷酰基过氧化物化合物，单官能单体和具有烯属双键和异氰酸酯基团的多官能单体与 彼此获得含氟烷基的共聚物和交联步骤，其包括将含氟代烷基的共聚物和离子液体或鏻盐混合的子步骤，并使得冷凝体在离子的存在下在其异氰酸酯基团与自身反应 液体或鏻盐，得到粉末状三维交联的包合物颗粒。

公开(公告)号：US20080064903A1

公开(公告)日：2008-03-13

申请号：US11715495

申请日：2007-03-08

申请人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

发明人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

IPC分类号： C07C27/10

CPC分类号： C07F7/21

摘要： A nanoparticle composite includes a host molecule including a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at opposite terminals thereof and a three-dimensional silica network section, and having a structure represented by the following formula (1): where X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group, independent NHR group (where R is alkyl group) or independent OCY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O, independent NH—C═O or independent NR—C═O (where R is alkyl group); n is 1≦n≦10; and m is 1≦m≦n; and a guest molecule included in the host molecule.

摘要翻译： 纳米颗粒复合材料包括主体分子，其包括分别具有相对端的亲水基团和氟代烷基的链低聚物部分和三维二氧化硅网络部分，并具有由下式（1）表示的结构：其中X是 独立的OH基团，独立的NCO基团，独立的NH 2基团，独立的NHR基团（其中R是烷基）或独立的OCY基团（其中Y是亲水基团）; R F是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O，独立的O-C-O，独立的NH-C-O或独立的NR-C-O（其中R是烷基）; n为1 <= n <= 10; 并且m是1 <= m <= n; 和宿主分子中包含的客体分子。

公开(公告)号：US5118879A

公开(公告)日：1992-06-02

申请号：US601736

申请日：1990-10-25

申请人： Nobumasa Kamigata ,  Masato Yoshida ,  Hideo Sawada ,  Masaharu Nakayama

发明人： Nobumasa Kamigata ,  Masato Yoshida ,  Hideo Sawada ,  Masaharu Nakayama

IPC分类号： C07C19/10 ,  C07C21/18 ,  C07C22/08 ,  C07C25/13 ,  C07C25/24 ,  C07C43/225 ,  C07C205/11

CPC分类号： C07C25/24 ,  C07C19/10 ,  C07C205/11 ,  C07C21/18 ,  C07C22/08 ,  C07C25/13 ,  C07C43/225

摘要： Fluoroalkyl derivatives which are novel compounds represented by the following general formula (I) or (II) of: ##STR1## orR.sub.1 --CH.dbd.CR.sub.2 (CF.sub.2).sub.n F (II)(wherein R.sub.1 stands for ##STR2## (where X stands for a hydrogen atom, a chlorine atom, a bromine atom, a fluorine atom, an iodine atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group or a nitro group), an aroyloxy group, or an alkyl or alkoxycarbonyl group having 1 to 20 carbon atoms, and R.sub.2 stands for a hydrogen atom or a methyl group; and n stands for an integer of from 1 to 20.) A process for the preparation of the derivative is a process comprising reacting an olefin compound and a fluoroalkanesulfonyl chloride in the presence of a metal catalyst, or a process comprising an additional alkali treatment step which follows the aforementioned process.

摘要翻译： PCT No.PCT / JP90 / 00242 Sec。 371 1990年10月25日第 102（e）1990年10月25日日期PCT提交1990年2月27日PCT公布。 出版物WO90 / 09972 1990年9月7日，由以下通式（I）或（II）表示的新化合物：（I）或R1-CH = CR2（CF2）nF（Ⅱ）（其中R1 代表（其中X代表氢原子，氯原子，溴原子，氟原子，碘原子，甲基，乙基，甲氧基，乙氧基或硝基） 芳氧基，碳原子数1〜20的烷基或烷氧基羰基，R2表示氢原子或甲基，n表示1〜20的整数）。 衍生物是一种方法，包括在金属催化剂存在下使烯烃化合物和氟烷基磺酰氯反应，或包括依照上述方法的另外的碱处理步骤的方法。