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公开(公告)号：US20070212577A1
公开(公告)日：2007-09-13
申请号：US10594626
申请日：2005-03-30
CPC分类号： B63G8/08 , B63H2021/003 , C01B3/22 , C01B2203/0266 , C01B2203/066 , C25B1/02 , Y02E60/324 , Y02T90/38
摘要： A submarine boat is provided on which a hydrogen generating device which can supply hydrogen easily to a hydrogen storing means and can generate a hydrogen-containing gas at a low temperature is loaded. A submarine boat provided with a fuel cell (30) for power generation by supply of hydrogen and oxidizing agent, a hydrogen generating device (10) for generating a gas containing hydrogen to be supplied to the fuel cell, and propelling device driven by electricity generated by the fuel cell, characterized in that the hydrogen generating device is to generate a gas containing hydrogen by decomposing a fuel containing an organic compound, comprising a partition membrane (11), a fuel electrode (12) provided on one surface of the partition membrane, means (16) for supplying a fuel containing the organic compound and water to the fuel electrode, an oxidizing electrode (14) provided on the other surface of the partition membrane, means (17) for supplying an oxidizing agent to the oxidizing electrode, and means for generating and collecting the gas containing hydrogen from the fuel electrode. There are cases: (1) the hydrogen generating device is an open circuit having neither means for withdrawing electric energy to outside from a hydrogen generating cell constituting the hydrogen generating device, nor means for providing electric energy from outside to the hydrogen generating cell; (2) the hydrogen generating device has means for withdrawing electric energy to outside with the fuel electrode serving as a negative electrode and the oxidizing electrode as a positive electrode; and (3) the hydrogen generating device has means for providing electric energy from outside with the fuel electrode serving as cathode and the oxidizing electrode as anode.
摘要翻译： 提供了一种能够容易地向氢存储装置供应氢气并且可以在低温下产生含氢气体的氢气发生装置的潜艇。 具有通过供给氢和氧化剂发电的燃料电池（30）的潜艇，用于产生供给燃料电池的含氢气体的氢生成装置（10），以及由电力驱动的推进装置 其特征在于，所述氢生成装置通过分解含有有机化合物的燃料来生成含有氢的气体，所述燃料包含分隔膜（11），设置在所述分隔膜的一个表面上的燃料电极（12） ，用于向燃料电极供给含有有机化合物和水的燃料的装置（16），设置在分隔膜的另一个表面上的氧化电极（14），用于向氧化电极供给氧化剂的装置（17） 以及用于从燃料电极产生和收集含有氢的气体的装置。 存在这样的情况：（1）氢生成装置是从构成氢生成装置的氢生成单元不向外部抽出电能的开路，也不是从外部向氢生成单元提供电能的装置。 （2）氢生成装置具有将燃料电极用作负极并且氧化电极作为正极而将电能抽出到外部的装置; 和（3）氢生成装置具有用于从外部提供电能的装置，其中用作阴极的燃料电极和作为阳极的氧化电极。
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公开(公告)号：US20070190372A1
公开(公告)日：2007-08-16
申请号：US10594702
申请日：2005-03-30
CPC分类号： H01M8/0656 , C01B3/22 , C01B2203/0266 , C01B2203/066 , H01M4/926 , H01M8/0668 , H01M2250/20 , Y02T90/32
摘要： An electric automobile is provided on which a hydrogen generating device which can supply hydrogen easily to a hydrogen storing means and can generate a hydrogen-containing gas at a low temperature is loaded. An electric automobile provided with a fuel cell (30) for power generation by supply of hydrogen and oxidizing agent, a hydrogen generating device (10) for generating a gas containing hydrogen to be supplied to the fuel cell, and a motor driven by electricity generated by the fuel cell, characterized in that the hydrogen generating device is to generate a gas containing hydrogen by decomposing a fuel containing an organic compound, comprising a partition membrane (11), a fuel electrode (12) provided on one surface of the partition membrane, means (16) for supplying a fuel containing the organic compound and water to the fuel electrode, an oxidizing electrode (14) provided on the other surface of the partition membrane, means (17) for supplying an oxidizing agent to the oxidizing electrode, and means for generating and collecting the gas containing hydrogen from the fuel electrode. There are cases: (1) the hydrogen generating device is an open circuit having neither means for withdrawing electric energy to outside from a hydrogen generating cell constituting the hydrogen generating device, nor means for providing electric energy from outside to the hydrogen generating cell; (2) the hydrogen generating device has means for withdrawing electric energy to outside with the fuel electrode serving as a negative electrode and the oxidizing electrode as a positive electrode; and (3) the hydrogen generating device has means for providing electric energy from outside with the fuel electrode serving as cathode and the oxidizing electrode as anode.
摘要翻译： 提供一种电动汽车，在该电动汽车上装载能够容易地向氢存储装置供应氢并可在低温下产生含氢气体的氢生成装置。 一种电动汽车，其具有通过供给氢和氧化剂发电的燃料电池（30），用于产生供给燃料电池的含氢气体的氢生成装置（10），以及由电力驱动的电动机 其特征在于，所述氢生成装置通过分解含有有机化合物的燃料来生成含有氢的气体，所述燃料包含分隔膜（11），设置在所述分隔膜的一个表面上的燃料电极（12） ，用于向燃料电极供给含有有机化合物和水的燃料的装置（16），设置在分隔膜的另一个表面上的氧化电极（14），用于向氧化电极供给氧化剂的装置（17） 以及用于从燃料电极产生和收集含有氢的气体的装置。 存在这样的情况：（1）氢生成装置是从构成氢生成装置的氢生成单元不向外部抽出电能的开路，也不是从外部向氢生成单元提供电能的装置。 （2）氢生成装置具有将燃料电极用作负极并且氧化电极作为正极而将电能抽出到外部的装置; 和（3）氢生成装置具有用于从外部提供电能的装置，其中用作阴极的燃料电极和作为阳极的氧化电极。
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3.发明申请Hydrogen generating method and hydrogen generating system based on the method 有权基于该方法的氢气发生方法和氢气发生系统公开(公告)号：US20070154748A1
公开(公告)日：2007-07-05
申请号：US10584267
申请日：2004-12-21
CPC分类号： C25B1/02 , C25B9/10 , H01M8/0612 , Y02E60/366
摘要： The present invention aims to provide a hydrogen generating method for generating hydrogen-containing gas little contaminated with nitrogen, CO, etc., by decomposing fuel containing an organic compound at low temperature while requiring the supply of no or little electric energy from an external source, and a hydrogen generating system based on the method. The hydrogen generating method provided by the present invention comprises providing a fuel electrode (12) in contact with one surface of a partition membrane (11), supplying fuel containing an organic compound and water to the fuel electrode (12), providing an oxidizing electrode (14) in contact with the other surface of the partition membrane (11), and supplying an oxidizing agent to the oxidizing electrode (14), wherein fuel containing the organic compound is decomposed and hydrogen is generated on the fuel electrode (12). A hydrogen generating system based on the method can work under three different conditions: (a) it works under open-circuit condition where no electric energy is withdrawn to outside from a hydrogen generating cell (10) constituting the hydrogen generating system, and no electric energy is supplied from outside to the hydrogen generating cell; (b) it works under a condition where electric energy is withdrawn from the hydrogen generating cell with the fuel electrode (12) serving as a negative electrode and the oxidizing electrode (14) as a positive electrode; and (c) it works under another condition where external electric energy is provided to the hydrogen generating cell with the fuel electrode (12) serving as cathode and the oxidizing electrode (14) as anode.
摘要翻译： 本发明的目的在于提供一种通过在低温下分解含有有机化合物的燃料来产生几乎不受氮，CO等污染的含氢气体的氢生成方法，同时需要从外部源提供或少量的电能 ，以及基于该方法的氢生成系统。 本发明提供的氢生成方法包括提供与分隔膜（11）的一个表面接触的燃料电极（12），向燃料电极（12）供给含有有机化合物和水的燃料，提供氧化电极 （14）与分隔膜（11）的另一个表面接触，并向氧化电极（14）供给氧化剂，其中含有有机化合物的燃料分解并在燃料电极（12）上产生氢。 基于该方法的氢气发生系统可以在三种不同的条件下工作：（a）在从构成氢气发生系统的氢气发生电池（10）向外部排出电能的开路条件下工作，不产生电 能量从外部供应到氢气发生单元; （b）在燃料电极（12）作为负极并且氧化电极（14）为正极的氢发生电池中取出电能的条件下工作; 和（c）在燃料电极（12）作为阴极和氧化电极（14）为阳极的情况下，向氢生成单元提供外部电能的另一条件下工作。
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公开(公告)号：US07939210B2
公开(公告)日：2011-05-10
申请号：US10594702
申请日：2005-03-30
CPC分类号： H01M8/0656 , C01B3/22 , C01B2203/0266 , C01B2203/066 , H01M4/926 , H01M8/0668 , H01M2250/20 , Y02T90/32
摘要： An electric automobile includes a fuel cell for power generation by supply of hydrogen and oxidizing agent, a hydrogen generating device for generating a gas containing hydrogen to be supplied to the fuel cell, and a motor driven by electricity generated by the fuel cell. The hydrogen generating device generates gas containing hydrogen by decomposing an organic compound-containing fuel, and includes a proton conductive partition membrane, a fuel electrode provided on one surface of the partition membrane to directly generate the gas containing hydrogen, a device for supplying, to the fuel electrode, water and organic compound-containing fuel capable of producing a proton as a result of electrochemical oxidization which can pass through the partition membrane, an oxidizing electrode provided on the other surface of the partition membrane, a device for supplying the oxidizing agent to the oxidizing electrode, and a device for generating and collecting the gas containing hydrogen.
摘要翻译： 电动汽车包括用于通过供应氢气和氧化剂发电的燃料电池，用于产生供给燃料电池的含氢气体的氢产生装置和由燃料电池产生的电驱动的电动机。 氢发生装置通过分解含有机化合物的燃料来产生含氢气体，并且包括质子传导隔膜，设置在分隔膜的一个表面上的燃料电极，以直接产生含氢气体的装置， 能够通过隔离膜的电化学氧化产生质子的燃料电极，水和含有机化合物的燃料，设置在分隔膜的另一个表面上的氧化电极，用于供给氧化剂的装置 到氧化电极，以及用于产生和收集含氢气体的装置。
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公开(公告)号：US07910252B2
公开(公告)日：2011-03-22
申请号：US10594711
申请日：2005-03-30
CPC分类号： H01M8/0668 , B01J4/008 , C01B3/22 , C01B2203/0266 , C01B2203/066 , H01M8/04216 , H01M8/0656 , H01M2250/20 , Y02E60/328 , Y02T90/32
摘要： A hydrogen supply system includes at least a hydrogen supply device for supplying hydrogen to a hydrogen storing device, and a hydrogen generating device producing hydrogen containing gas to be supplied to the hydrogen supply device. The hydrogen generating device produces the hydrogen containing gas by decomposing a fuel containing an organic compound, and includes a partition membrane, a fuel electrode provided on one surface of the partition membrane for generating hydrogen containing gas, a device for supplying a fuel containing the organic compound and water to the fuel electrode, an oxidizing electrode provided on the other surface of the partition membrane, a device for supplying an oxidizing agent to the oxidizing electrode, and a device for collecting the hydrogen containing gas directly from the fuel electrode.
摘要翻译： 氢供给系统至少包括用于向氢存储装置供给氢的氢供给装置和产生供给氢供给装置的含氢气体的氢生成装置。 氢产生装置通过分解含有有机化合物的燃料来产生含氢气体，并且包括分隔膜，设置在用于产生含氢气体的分隔膜的一个表面上的燃料电极，用于供给含有有机化合物的燃料的装置 化合物和水到燃料电极，设置在分隔膜的另一个表面上的氧化电极，向氧化电极供应氧化剂的装置，以及用于从燃料电极直接收集含氢气体的装置。
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公开(公告)号：US20080171244A1
公开(公告)日：2008-07-17
申请号：US11794357
申请日：2005-12-26
CPC分类号： H01M8/0656 , C25B1/02 , H01M4/926 , H01M8/0668 , H01M2250/20 , Y02T90/32
摘要： A standalone hydrogen generating system is provided using a hydrogen generating device which can generate a hydrogen-containing gas at a low temperature and can be operated only by electric energy supplied from a fuel cell and does not require large electric energy.In the standalone hydrogen generating system provided with at least a hydrogen generating cell (10) constituting a hydrogen generating device, auxiliary machines (16), (17) for operating the hydrogen generating device, and a fuel cell (33) for supplying electric energy to the auxiliary machines (16), (17), the hydrogen generating device is to generate a gas containing hydrogen by decomposing a fuel containing an organic compound, comprising a partition membrane (11), a fuel electrode (12) provided on one surface of the partition membrane (11), means for supplying a fuel containing the organic compound and water to the fuel electrode (12), an oxidizing electrode (14) provided on the other surface of the partition membrane (11), means for supplying an oxidizing agent to the oxidizing electrode (14), and means for generating and collecting the gas containing hydrogen from the fuel electrode (12). There are cases in the hydrogen generating device: (a) the hydrogen generating cell (10) in the hydrogen generating device is an open circuit having neither means for withdrawing electric energy to outside from the cell (10), nor means for providing electric energy from outside to the cell (10); (b) means for withdrawing electric energy to outside with the fuel electrode (12) serving as a negative electrode and the oxidizing electrode (14) as a positive electrode; and (c) means for providing electric energy from outside with the fuel electrode (12) serving as cathode and the oxidizing electrode (14) as anode.
摘要翻译： 使用能够在低温下产生含氢气体的氢生成装置来提供独立的氢生成系统，并且仅能够通过从燃料电池供给的电能进行操作，并且不需要大的电能。 在至少具有构成氢生成装置的氢生成电池（10）的独立的氢生成系统中，用于操作氢生成装置的辅助机器（16），（17）和用于供给电能的燃料电池（33） 通过分解含有有机化合物的燃料，氢辅助机构（16），（17）通过分解含有氢气的气体，包括分隔膜（11），设置在一个表面上的燃料电极（12） 的分隔膜（11）的另一面上设置有用于向燃料电极（12）供给含有有机化合物和水的燃料的装置，设置在分隔膜（11）的另一个面上的氧化电极（14） 氧化剂到氧化电极（14），以及用于从燃料电极（12）产生和收集含有氢的气体的装置。 在氢生成装置中存在这样的情况：（a）氢生成装置中的氢生成单元（10）是不具有从电池（10）向外部取出电能的开路，也不具有用于提供电能的装置 从外部到细胞（10）; （b）用作为负极的燃料电极（12）和作为正极的氧化电极（14）将电能抽出到外部的装置; 和（c）用于从作为阴极的燃料电极（12）和作为阳极的氧化电极（14）从外部提供电能的装置。
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公开(公告)号：US07476456B2
公开(公告)日：2009-01-13
申请号：US10594626
申请日：2005-03-30
CPC分类号： B63G8/08 , B63H2021/003 , C01B3/22 , C01B2203/0266 , C01B2203/066 , C25B1/02 , Y02E60/324 , Y02T90/38
摘要： A submarine boat provided with a fuel cell (30) for power generation by supply of hydrogen and oxidizing agent, a hydrogen generating device (10) for generating a gas containing hydrogen to be supplied to the fuel cell, and propelling device driven by electricity generated by the fuel cell, characterized in that the hydrogen generating device is to generate a gas containing hydrogen by decomposing a fuel containing an organic compound, comprising a partition membrane (11), a fuel electrode (12) provided on one surface of the partition membrane, means (16) for supplying a fuel containing the organic compound and water to the fuel electrode, an oxidizing electrode (14) provided on the other surface of the partition membrane, means (17) for supplying an oxidizing agent to the oxidizing electrode, and means for generating and collecting the gas containing hydrogen from the fuel electrode.
摘要翻译： 具有通过供给氢和氧化剂发电的燃料电池（30）的潜艇，用于产生供给燃料电池的含氢气体的氢生成装置（10），以及由电力驱动的推进装置 其特征在于，所述氢生成装置通过分解含有有机化合物的燃料来生成含有氢的气体，所述燃料包含分隔膜（11），设置在所述分隔膜的一个表面上的燃料电极（12） ，用于向燃料电极供给含有有机化合物和水的燃料的装置（16），设置在分隔膜的另一个表面上的氧化电极（14），用于向氧化电极供给氧化剂的装置（17） 以及用于从燃料电极产生和收集含有氢的气体的装置。
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公开(公告)号：US20080090125A1
公开(公告)日：2008-04-17
申请号：US10594711
申请日：2005-03-30
CPC分类号： H01M8/0668 , B01J4/008 , C01B3/22 , C01B2203/0266 , C01B2203/066 , H01M8/04216 , H01M8/0656 , H01M2250/20 , Y02E60/328 , Y02T90/32
摘要： A hydrogen supply system is provided which can supply hydrogen easily to a hydrogen storing means, can generate a gas containing hydrogen at a low temperature and uses a hydrogen generating device which does not require a large quantity of electric energy.In a hydrogen supply system comprising at least hydrogen supply means for supplying hydrogen to hydrogen storing means such as a hydrogen storage container loaded on a fuel cell automobile, for example, and a hydrogen generating device (10) for generating a gas containing hydrogen to be supplied to the hydrogen supply means, the hydrogen generating device is to generate the gas containing hydrogen by decomposing a fuel containing an organic compound, comprising a partition membrane (11), a fuel electrode (12) provided on one surface of the partition membrane, means (16) for supplying a fuel containing the organic compound and water to the fuel electrode, an oxidizing electrode (14) provided on the other surface of the partition membrane, means (17) for supplying an oxidizing agent to the oxidizing electrode, and means for generating and collecting the gas containing hydrogen from the fuel electrode. There are cases: (1) the hydrogen generating device is an open circuit having neither means for withdrawing electric energy to outside from a hydrogen generating cell constituting the hydrogen generating device, nor means for providing electric energy from outside to the hydrogen generating cell; (2) the hydrogen generating device has means for withdrawing electric energy to outside with the fuel electrode serving as a negative electrode and the oxidizing electrode as a positive electrode; and (3) the hydrogen generating device has means for providing electric energy from outside with the fuel electrode serving as cathode and the oxidizing electrode as anode.
摘要翻译： 提供一种可以容易地向氢存储装置供应氢气的氢气供应系统，可以在低温下产生含氢的气体，并且使用不需要大量电能的氢生成装置。 在氢供给系统中，至少包括氢供给装置，用于向例如装载在燃料电池汽车上的氢存储容器等氢存储装置供给氢，以及用于产生含氢气体的氢生成装置（10） 氢气产生装置通过分解含有有机化合物的燃料来产生含氢气体，该分解膜包括分隔膜（11），设置在隔膜的一个表面上的燃料电极（12） 用于向燃料电极供给含有有机化合物和水的燃料的装置（16），设置在分隔膜的另一个表面上的氧化电极（14），用于向氧化电极供给氧化剂的装置（17），以及 用于从燃料电极产生和收集含有氢的气体的装置。 存在这样的情况：（1）氢生成装置是从构成氢生成装置的氢生成单元不向外部抽出电能的开路，也不是从外部向氢生成单元提供电能的装置。 （2）氢生成装置具有将燃料电极用作负极并且氧化电极作为正极而将电能抽出到外部的装置; 和（3）氢生成装置具有用于从外部提供电能的装置，其中用作阴极的燃料电极和作为阳极的氧化电极。
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公开(公告)号：US20080063910A1
公开(公告)日：2008-03-13
申请号：US11794320
申请日：2005-12-26
IPC分类号： H01M8/06
CPC分类号： H01M8/04089 , C25B1/02 , H01M8/0612 , H01M8/22
摘要： A fuel cell power generating device is provided in which a hydrogen generating device which can supply hydrogen easily to a fuel cell and can continuously generate a hydrogen-containing gas at a low temperature and does not require large electric energy is used. A fuel cell power generating device provided with at least a fuel cell (30) for power generation by supply of hydrogen and oxidizing agent and a hydrogen generating device (10) for generating a gas containing hydrogen to be supplied to the fuel cell, characterized in that the hydrogen generating device (10) is to generate a gas containing hydrogen by decomposing a fuel containing an organic compound, comprising a partition membrane (11), a fuel electrode (12) provided on one surface of the partition membrane (11), means for supplying a fuel containing the organic compound and water to the fuel electrode (12), an oxidizing electrode (14) provided on the other surface of the partition membrane (11), means for supplying an oxidizing agent to the oxidizing electrode (14), and means for generating and collecting the gas containing hydrogen from the fuel electrode (12). There are cases in the hydrogen generating device: (a) the hydrogen generating cell (10) in the hydrogen generating device is an open circuit having neither means for withdrawing electric energy to outside from the cell (10), nor means for providing electric energy from outside to the hydrogen generating cell (10); (b) means for withdrawing electric energy to outside with the fuel electrode (12) serving as a negative electrode and the oxidizing electrode (14) as a positive electrode; and (c) means for providing the electric energy from outside with the fuel electrode (12) serving as cathode and the oxidizing electrode (14) as anode.
摘要翻译： 提供一种燃料电池发电装置，其中使用能够容易地向燃料电池供应氢并且可以在低温下连续生成含氢气体并且不需要大的电能的氢生成装置。 一种燃料电池发电装置，至少具有用于通过供给氢和氧化剂发电的燃料电池（30）和用于产生供给燃料电池的含氢气体的氢产生装置（10），其特征在于， 氢产生装置（10）通过分解含有有机化合物的燃料来产生含氢的气体，其包括分隔膜（11），设置在分隔膜（11）的一个表面上的燃料电极（12） 用于向燃料电极（12）供给含有有机化合物和水的燃料的装置，设置在分隔膜（11）的另一个表面上的氧化电极（14），向氧化电极（14）供给氧化剂的装置 ），以及用于从燃料电极（12）产生和收集含有氢的气体的装置。 在氢生成装置中存在这样的情况：（a）氢生成装置中的氢生成单元（10）是不具有从电池（10）向外部取出电能的开路，也不具有用于提供电能的装置 从外部到氢气发生电池（10）; （b）用作为负极的燃料电极（12）和作为正极的氧化电极（14）将电能抽出到外部的装置; 和（c）用于从作为阴极的燃料电极（12）和作为阳极的氧化电极（14）从外部提供电能的装置。
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10.发明授权Hydrogen generating method and hydrogen generating system based on the method 有权基于该方法的氢气发生方法和氢气发生系统公开(公告)号：US08679687B2
公开(公告)日：2014-03-25
申请号：US10584267
申请日：2004-12-21
CPC分类号： C25B1/02 , C25B9/10 , H01M8/0612 , Y02E60/366
摘要： The present invention aims to provide a hydrogen generating method for generating hydrogen-containing gas little contaminated with nitrogen, CO, etc., by decomposing fuel containing an organic compound at low temperature while requiring the supply of no or little electric energy from an external source, and a hydrogen generating system based on the method.A hydrogen generating system based on the method can work under multiple conditions: (a) it works under a condition where electric energy is withdrawn from the hydrogen generating cell with the fuel electrode (12) serving as a negative electrode and the oxidizing electrode (14) as a positive electrode; and (b) it works under another condition where external electric energy is provided to the hydrogen generating cell with the fuel electrode (12) serving as cathode and the oxidizing electrode (14) as anode.
摘要翻译： 本发明的目的在于提供一种通过在低温下分解含有有机化合物的燃料来产生几乎不受氮，CO等污染的含氢气体的氢生成方法，同时需要从外部源提供或少量的电能 ，以及基于该方法的氢生成系统。 基于该方法的氢生成系统可以在多种条件下工作：（a）在燃料电极（12）用作负极并且氧化电极（14）从氢发生单元取出电能的条件下工作 ）作为正极; 和（b）在燃料电极（12）作为阴极和氧化电极（14）为阳极的情况下，向氢生成电池提供外部电能的另一条件下起作用。
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