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1.发明授权公开(公告)号：US10730965B2
公开(公告)日：2020-08-04
申请号：US16066442
申请日：2016-12-23
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Akhlaq Moman , Ian Blackmore
IPC: C08F4/649 , C08F4/654 , C08F4/655 , C08F4/656 , C08F10/02 , C08F2/34 , C08F4/651 , C08F4/659 , C08F110/02 , C08F210/02
Abstract: The present invention relates to a process for preparing a solid catalyst component suitable for producing polyethylene and its copolymers, said process comprising the steps of: (a) contacting a dehydrated support having hydroxyl groups with a magnesium compound having the general formula MgR1R2; (b) contacting the product obtained in step (a) with modifying compounds (A) and/or (B) and/or (C), wherein: (A) is at least one oxygen and/or nitrogen comprising organic compound; (B) is a compound having the general formula R11f(R12O)gSiXh, (C) is a compound having the general formula (R13O)4M, and (c) contacting the product obtained in step (b) with a titanium halide compound having the general formula TiX4, wherein Ti is a titanium atom and X is a halide atom, wherein an organometallic compound is added either before step (a) and/or after step (c). The invention also relates to a solid catalyst component obtainable by said process. The invention further relates to a process for producing polyethylene and its copolymers in the presence of the solid catalyst component and a co-catalyst.
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公开(公告)号：US20190276567A1
公开(公告)日：2019-09-12
申请号：US16340918
申请日：2017-10-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Patrick Elisabeth Luc Voets , Abderrahman Meddad , Henrica Norberta Alberta Maria Steenbakkers-Menting , Akhlaq Moman
Abstract: The invention relates to a biaxially oriented polypropylene (BOPP) film comprising a propylene homopolymer or propylene-ethylene copolymer having an ethylene content of at most 1.0 wt % based on the propylene-ethylene copolymer having an Mw/Mn in the range from 5.0 to 12, wherein Mw stands for the weight average molecular weight and Mn stands for the number average weight and wherein Mw and Mn are measured according to ASTM D6474-12, an XS in the range from 1.0 to 6.0 wt %, wherein XS stands for the amount of xylene solubles which are measured according to ASTM D 5492-10, a melt flow rate in the range of 1 to 10 dg/min as measured according to IS01133 (2.16 kg/230° C.) and a crystal size distribution as indicated by a height/width ratio of the highest peak of the first cooling curve of at least 0.70 W/g° C. as determined by ASTM D3418-08 using a heating and cooling rate of 10° C./min.
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3.发明申请公开(公告)号：US20190225715A1
公开(公告)日：2019-07-25
申请号：US16340941
申请日：2017-10-11
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Abstract: The invention relates to a process for preparing a solid support for a procatalyst suitable for preparing a catalyst composition for olefin polymerization, said process for preparing said solid support comprising reacting a compound R42MgX42-z with a silane compound Si(OR5)4-n(R6)n in a solvent and mixing the resulting mixture with a mixing device and at a certain mixing speed in order to give a solid support Mg(OR1)xX12-x said solid support obtained having an average particle size of at most 17 μm, preferably at most 16 or 14 μm, more preferably at most 12 μm. The invention further relates to a solid support, a process for preparing a procatalyst and said procatalyst as well as polyolefins obtained using said procatalyst.
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4.发明申请公开(公告)号：US20180371115A1
公开(公告)日：2018-12-27
申请号：US16066172
申请日：2016-12-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Akhlaq Moman , Ian Blackmore
Abstract: The present invention relates to a process for preparing a solid catalyst component suitable for producing polyethylene and its copolymers, said process comprising the steps of: (a) contacting a dehydrated support having hydroxyl groups with a magnesium compound having the general formula MgR1R2; (b) contacting the product obtained in step (a) with modifying compounds (A) and/or (B) and/or (C), wherein: (A) is an 4-amino-pent-3-en-2-one; (B) is a compound having the general formula R11f(R12O)g,SiXh, (C) is a compound having the general formula (R13O)4M, and (c) contacting the product obtained in step (b) with a titanium halide compound having the general formula TiX4, wherein Ti is a titanium atom and X is a halide atom. The invention also relates to a solid catalyst component obtainable by said process. The invention further relates to a process for producing polyethylene and its copolymers in the presence of the solid catalyst component and a co-catalyst.
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公开(公告)号：US12291627B2
公开(公告)日：2025-05-06
申请号：US17263338
申请日：2019-07-22
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Henrica Norberta Alberta Maria Steenbakkers-Menting , Tinashe Victor Mandishonha Ndoro , Desiree Marie Louise Seegers , Erik Delsman , Raymond Gerlofsma , Tim Kiggen , Martin Alexander Zuideveld , Akhlaq Moman , Patrick Elisabeth Luc Voets
Abstract: The invention relates to a polypropylene composition comprising a terpolymer composition comprising (A) a first terpolymer fraction containing propylene, ethylene and 1-hexene, wherein the first terpolymer fraction has a melt flow rate of 0.005 to 0.20 dg/min determined by ISO 1133-1:2011 (230° C., 2.16 kg) and (B) a second terpolymer fraction containing propylene, ethylene and 1-hexene, wherein the second terpolymer fraction has a melt flow rate of 0.30 to 70 dg/min determined by ISO 1133-1:2011 (230° C., 2.16 kg), wherein the first terpolymer fraction is prepared using a first set of reaction conditions, the second terpolymer fraction is prepared using a second set of reaction conditions and the first and second set of reaction conditions are different, wherein the polypropylene composition (i) has a melt flow rate of 0.10 to 0.70 dg/min determined by ISO 1133-1:2011 (230° C., 2.16 kg), (ii) has a content of ethylene derived units in the range from 1.6 to 3.0 wt %; (iii) has a content of 1-hexene derived units in the range from 1.7 to 4.0 wt %; and (iv) has a ratio of the content of ethylene derived units to the content of 1-hexene derived units in the composition of at least 0.70.
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Patent Agency Ranking
公开(公告)号：US20250101152A1
公开(公告)日：2025-03-27
申请号：US18717584
申请日：2022-12-08
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Akhlaq Moman , Vladimir Aleksandrovich Zakharov , Sergei Andreevich Sergeev , Artem Barabanov
IPC: C08F110/06
Abstract: A process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, the procatalyst obtained or obtainable by the process; and a catalyst composition for olefin polymerization comprising the procatalyst. In particular an activator according to Formula (I) can be used in the preparation of a supported Ziegler-Natta type procatalyst useful for a process for the preparation of polyolefins.
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公开(公告)号：US10717791B2
公开(公告)日：2020-07-21
申请号：US15780538
申请日：2016-11-23
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Akhlaq Moman , Abdulaziz Al-Humydi , Inaamul Haq Siddiqui , Sudhakar R. Padmanabhan , Bandar Abdullah Almohammadi , Ahmad Abdullah Alshaiban
IPC: C08F110/06
Abstract: A procatalyst for polymerization of olefins, which procatalyst is based on a magnesium compound of the formula MgR′R″ wherein R′ is an alkoxide or aryloxide group and R″ is an alkoxide or aryloxide group or halogen, an activator being a monoester and an internal donor represented by a compound according to formula A: as described herein. Also described is a polymerization catalyst system comprising the procatalyst, a co-catalyst and optionally an external electron donor; a process of making a polyolefin, by contacting an olefin with the catalyst system; a polyolefin, obtained by or obtainable by the process; and a polyolefin, having a molecular weight distribution of between 4 and 15, a molecular weight (Mw) of between 300,000 to 1,500,000 g/mol, a melting temperature of more than 150° C., a value for the xylene solubles of less than 4 wt. % and a shaped article therefrom.
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公开(公告)号：US20200055968A1
公开(公告)日：2020-02-20
申请号：US16336993
申请日：2017-06-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Akhlaq Moman , Inaamul Haq Siddiqui , Sudhakar R. Padmanabhan , Osamah Al-Humaidan , Haitham Al-Enazi
IPC: C08F4/651 , C08F4/656 , C08F210/06
Abstract: The present invention relates to a process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, said process comprising the steps of: Step A) providing or preparing a Grignard compound; Step B) contacting the Grignard compound an alkoxy- or aryloxy silane compound, to give a solid support; Step C) optionally contacting the solid support obtained with at least one activating compound; and Step D) reacting the (activated) support with a halogen-containing Ti-compound as catalytic species, an activator and at least one internal electron donor in several sub steps wherein the internal donor is added in portions during at least two of said stages to obtain a procatalyst. The invention moreover relates to a procatalyst, a catalytic system comprising said procatalyst and to a process to prepare polyolefins using said catalyst system and the polyolefins obtained therewith.
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公开(公告)号：US11192962B2
公开(公告)日：2021-12-07
申请号：US16336993
申请日：2017-06-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Akhlaq Moman , Inaamul Haq Siddiqui , Sudhakar R. Padmanabhan , Osamah Al-Humaidan , Haitham Al-Enazi
IPC: C08F4/651 , C08F4/656 , C08F210/06 , C08F110/06
Abstract: The present invention relates to a process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, said process comprising the steps of: Step A) providing or preparing a Grignard compound; Step B) contacting the Grignard compound an alkoxy- or aryloxy silane compound, to give a solid support; Step C) optionally contacting the solid support obtained with at least one activating compound; and Step D) reacting the (activated) support with a halogen-containing Ti-compound as catalytic species, an activator and at least one internal electron donor in several sub steps wherein the internal donor is added in portions during at least two of said stages to obtain a procatalyst. The invention moreover relates to a procatalyst, a catalytic system comprising said procatalyst and to a process to prepare polyolefins using said catalyst system and the polyolefins obtained therewith.
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公开(公告)号：US11001651B2
公开(公告)日：2021-05-11
申请号：US16340918
申请日：2017-10-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Patrick Elisabeth Luc Voets , Abderrahman Meddad , Henrica Norberta Alberta Maria Steenbakkers-Menting , Akhlaq Moman
IPC: C08F10/06 , C08F110/06 , B29C55/12 , C08J5/18 , B29C55/00 , B29K623/00
Abstract: The invention relates to a biaxially oriented polypropylene (BOPP) film comprising a propylene homopolymer or propylene-ethylene copolymer having an ethylene content of at most 1.0 wt % based on the propylene-ethylene copolymer having an Mw/Mn in the range from 5.0 to 12, wherein Mw stands for the weight average molecular weight and Mn stands for the number average weight and wherein Mw and Mn are measured according to ASTM D6474-12, an XS in the range from 1.0 to 6.0 wt %, wherein XS stands for the amount of xylene solubles which are measured according to ASTM D 5492-10, a melt flow rate in the range of 1 to 10 dg/min as measured according to IS01133 (2.16 kg/230° C.) and a crystal size distribution as indicated by a height/width ratio of the highest peak of the first cooling curve of at least 0.70 W/g° C. as determined by ASTM D3418-08 using a heating and cooling rate of 10° C./min.
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