THERMOSET 3-OXO-ISOINDOLINE DIPHTHALONITRILE POLYMERS, METHOD OF MANUFACTURE, AND USES THEREOF

    公开(公告)号:US20190284339A1

    公开(公告)日:2019-09-19

    申请号:US16270747

    申请日:2019-02-08

    Abstract: A thermoset polymer product comprising 4,4′-(((3-oxo-isoindoline-1,1-diyl)bis(4,1-arylene))bis(oxy))dibenzonitrile units of formula (2) wherein the units are derived from a 4,4′-(((3-oxo-isoindoline-1,1-diyl)bis(4,1-arylene))bis(oxy))diphthalonitrile monomer of formula (1) wherein R is a C1-25 hydrocarbyl, preferably a C1-6 alkyl, a phenyl, or a phenyl substituted with up to five C1-6 alkyl groups, more preferably a C1-3 alkyl or a phenyl; each occurrence of R2 and R3 is independently a hydrogen, a halogen, or a C1-25 hydrocarbyl, preferably a hydrogen, a halogen, or a C1-6 alkyl, more preferably a hydrogen or a C1-3 alkyl; p and q are each independently 0 to 4, preferably 0 or 1, more preferably 0; and G is a residue of a cyano group, and is a C1-25 hydrocarbyl linking group having a valence of at least 2.

    Method of forming phenylene ether oligomer

    公开(公告)号:US10259762B2

    公开(公告)日:2019-04-16

    申请号:US16061764

    申请日:2016-11-10

    Abstract: A phenylene ether oligomer is prepared by a process that includes partially converting 2,6-dimethylphenol to 3,3′,5,5′-tetramethyl-4,4′-dihydroxybiphenyl and/or 3,3′,5,5′-tetramethyldiphenoquinone, converting the residual 2,6 dimethylphenol to poly(2,6-dimethyl-1,4-phenylene ether) and any 3,3′,5,5′-tetramethyl-4,4′-dihydroxybiphenyl to 3,3′,5,5′-tetramethyldiphenoquinone, and reacting the poly(2,6-dimethyl-1,4-phenylene ether) and 3,3′,5,5′-tetramethyldiphenoquinone to form the phenylene ether oligomer. The preparation can be conducted without isolation of intermediates.

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