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公开(公告)号：US10995180B2
公开(公告)日：2021-05-04
申请号：US16065432
申请日：2016-12-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Mark A. Sanner , Thomas Link Guggenheim , Roy Ray Odle
Abstract: A polyetherimide composition includes a polyetherimide and two or more of a residual metal content, a sulfate anion, a phosphate anion, a nitrite anion, a nitrate anion, or a combination including at least one of the foregoing, a residual solvent content, a phosphorus-containing stabilizer, and alkali metal halide, alkaline earth metal halide, alkali metal carbonate, or a combination including at least one of the foregoing, wherein each of the aforementioned components, when present, is included in the composition in a particular amount. The resulting polyetherimide composition exhibits two or more useful properties. The polyetherimide composition can optionally further be combined with a polymer different from the polyetherimide to provide a thermoplastic composition. Methods of making the polyetherimide composition and articles including the polyetherimide composition are also described.
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公开(公告)号：US10829594B2
公开(公告)日：2020-11-10
申请号：US16067295
申请日：2016-12-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Thomas Link Guggenheim , Karthik Venkataraman
Abstract: A method of making a polyetherimide comprising: reacting an aromatic bis(ether anhydride) with an aromatic diamine in a solvent to form a first solid/liquid mixture having a first solids content within 5% of a first target solids content; cooling the first solid/liquid mixture to a temperature within 5% of a target temperature; separating a portion of the liquid component from the cooled first solid/liquid mixture to form a second solid/liquid mixture having a second solids content within 10% of a second target solids content; and melt polymerizing the second solid/liquid mixture to form the polyetherimide.
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公开(公告)号：US10240003B2
公开(公告)日：2019-03-26
申请号：US14263063
申请日：2014-04-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Eric Lee Lutz , William Hoy Heath , Roy Ray Odle , Thomas Link Guggenheim , Juan Justino Rodriguez Ordonez , Jose Roman Galdamez Pena
Abstract: A poly(aryl ether sulfone) comprises units of formula (I): wherein Ar1 is a divalent C6-C15 aromatic group, Ar2 is a divalent C6-C15 aromatic group, Ar3 is a divalent C6-C15 aromatic group, and n is greater than 1; and a terminal group of formula (II) derived from a monofunctional phenoxide wherein is X is a hydrogen atom or an organic substituent having from 1 to 20 carbon atoms; wherein the poly(aryl ether sulfone) has a hydroxyl group content greater than 0 and less than 50 parts per million (ppm), based on the poly(aryl ether sulfone) weight, a glass transition temperature of 180 to 290° C., a weight average molecular weight of 20,000 to 100,000, a halogen content of greater than 0 and less than 3000 ppm based on the poly(aryl ether sulfone) weight. The poly(aryl ether sulfone) is free of methoxy groups.
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4.发明申请公开(公告)号：US20190135750A1
公开(公告)日：2019-05-09
申请号：US16096491
申请日：2017-04-20
Applicant: SABIC Global Technologies B.V.
Inventor： Joshua McClellan Croll , Mohannad Aljarrah , Thomas Link Guggenheim
Abstract: A method for producing an aromatic bisimide includes reacting a dialkali metal salt of a dihydroxy aromatic compound with a reactive substituted phthalimide under conditions effective to form a product mixture, introducing the product mixture to a liquid-liquid extraction column including an aqueous alkali metal hydroxide solution, and recovering from the liquid-liquid extraction column a purified aromatic bisimide having less than 500 ppm of residual dialkali metal salt of the dihydroxy aromatic compound, the corresponding dihydroxy aromatic compound, the corresponding mono-substituted salt of the dihydroxy aromatic compound, or a combination including at least one of the foregoing. A method for the manufacture of a polyetherimide from an aromatic bisimide prepared by the above method is also disclosed. A polyetherimide having less than 100 ppb of residual bisphenol A and an article made therefrom are also described.
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公开(公告)号：US11279692B2
公开(公告)日：2022-03-22
申请号：US16065246
申请日：2016-12-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Thomas Link Guggenheim , Roy Ray Odle , Mani Raj Chaulagain
IPC: C07D403/12 , C07D209/48 , C08G73/10
Abstract: A method for producing an aromatic bisimide includes reacting a dialkali metal salt of a dihydroxy aromatic compound with an N-alkyl nitrophthalimide to form a product mixture including the aromatic bisimide. The N-alkyl nitrophthalimide includes 4-nitro-N—(C1-13 alkyl)phthalimide, 3-nitro-N—(C1-13 alkyl)phthalimide, or a combination including at least one of the foregoing, and 4-hydroxy-3,5-dinitro-N—(C1-13 alkyl)phthalimide in an amount of 1-10000 ppm. The aromatic bisimide can be obtained in a yield of greater than 75%, or 90-99.8%. A method for the manufacture of a polyetherimide, a polyetherimide, and an article including the polyetherimide are also disclosed. A mixed acid nitration process for the preparation of an N-alkyl nitrophthalimide is also described.
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Patent Agency Ranking
公开(公告)号：US20210206747A1
公开(公告)日：2021-07-08
申请号：US16065246
申请日：2016-12-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Thomas Link Guggenheim , Roy Ray Odle , Mani Raj Chaulagain
IPC: C07D403/12 , C07D209/48 , C08G73/10
Abstract: A method for producing an aromatic bisimide includes reacting a dialkali metal salt of a dihydroxy aromatic compound with an N-alkyl nitrophthalimide to form a product mixture including the aromatic bisimide. The N-alkyl nitrophthalimide includes 4-nitro-N—(C1-13 alkyl)phthalimide, 3-nitro-N—(C1-13 alkyl)phthalimide, or a combination including at least one of the foregoing, and 4-hydroxy-3,5-dinitro-N—(C1-13 alkyl)phthalimide in an amount of 1-10000 ppm. The aromatic bisimide can be obtained in a yield of greater than 75%, or 90-99.8%. A method for the manufacture of a polyetherimide, a polyetherimide, and an article including the polyetherimide are also disclosed. A mixed acid nitration process for the preparation of an N-alkyl nitrophthalimide is also described.
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公开(公告)号：US20200231753A1
公开(公告)日：2020-07-23
申请号：US16647780
申请日：2018-09-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Nitin Vilas Tople , Viswanathan Kalyanaraman , Kelly Leung , Thomas Link Guggenheim
IPC: C08G73/10
Abstract: A method for modifying a polyimide includes reacting a first polyimide with an amine to produce a second polyimide having an anhydride-amine stoichiometry of −2 to −40 mol % and reacting the second polyimide with a monoanhydride, a bis(anhydride), a bis(ether anhydride) or a tetracarboxylic acid to produce a final polyimide having an anhydride-amine stoichiometry of −1 to 2 mol %.
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公开(公告)号：US20190315690A1
公开(公告)日：2019-10-17
申请号：US16474256
申请日：2017-12-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Thomas Link Guggenheim , Hendrich Chiong , Bernabe Quevedo Sanchez , Carmen Rocio Misiego Arpa , Juan Justino Rodriguez Ordonez , Javier Nieves Remacha
IPC: C07D209/48 , C08G73/10
Abstract: A method for producing a reactive intermediate composition, including: reacting a substituted phthalic anhydride of the formula (I) with a diamine of the formula H2N—R—NH2 in the presence of an aromatic dianhydride in an amount of 10 to 50 mole percent based on the total moles of anhydride functionality in the reaction; wherein the reacting is conducted in an aprotic solvent in a reactor, under conditions effective to produce the reactive intermediate composition; and wherein X comprises a halogen or a nitro group, and R comprises a C6-36 aromatic hydrocarbon group or a halogenated derivative thereof, a straight or branched chain C2-20 alkylene or a halogenated derivative thereof, or a C3-8 cycloalkylene or a halogenated derivative thereof.
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公开(公告)号：US20180371169A1
公开(公告)日：2018-12-27
申请号：US16065432
申请日：2016-12-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Mark A. Sanner , Thomas Link Guggenheim , Roy Ray Odle
Abstract: A polyetherimide composition includes a polyetherimide and two or more of a residual metal content, a sulfate anion, a phosphate anion, a nitrite anion, a nitrate anion, or a combination including at least one of the foregoing, a residual solvent content, a phosphorus-containing stabilizer, and alkali metal halide, alkaline earth metal halide, alkali metal carbonate, or a combination including at least one of the foregoing, wherein each of the aforementioned components, when present, is included in the composition in a particular amount. The resulting polyetherimide composition exhibits two or more useful properties. The polyetherimide composition can optionally further be combined with a polymer different from the polyetherimide to provide a thermoplastic composition. Methods of making the polyetherimide composition and articles including the polyetherimide composition are also described.
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公开(公告)号：US11359059B2
公开(公告)日：2022-06-14
申请号：US16342026
申请日：2017-10-20
Applicant: SABIC Global Technologies B.V.
Inventor： Viswanathan Kalyanaraman , Thomas Link Guggenheim
Abstract: A method of preparing polymer particles includes combining a polyetherimide and a solvent at a first temperature to provide a slurry, wherein the polyetherimide is not soluble in the solvent at the first temperature; heating the slurry to a second temperature and at a pressure effective to dissolve the polyetherimide in the solvent to provide a homogenous solution; cooling the homogenous solution to a third temperature to provide a dispersion including a plurality of polymer particles; and isolating the polymer particles. The polymer particles have a Dv90 particle size of less than or equal to 250 micrometers. Polymers powders prepared according to the method are also described herein, wherein the powder includes a plurality of semi-crystalline polymer particles having a Dv90 of less than or equal to 250 micrometers.
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