公开(公告)号：US20170044656A1

公开(公告)日：2017-02-16

申请号：US15305547

申请日：2015-04-21

Applicant: SAINT-GOBAIN GLASS FRANCE

Inventor： Kamel CHAHBOUNE ,  Elodie DUCOURTHIAL

IPC: C23C14/10 ,  C23C14/35 ,  C03C17/34 ,  C03C17/00 ,  C03C8/14 ,  C03C17/04

CPC classification number: C23C14/10 ,  C03C8/14 ,  C03C17/002 ,  C03C17/04 ,  C03C17/3411 ,  C03C17/3417 ,  C03C2205/02 ,  C03C2217/213 ,  C03C2217/216 ,  C03C2217/228 ,  C03C2217/477 ,  C03C2217/485 ,  C03C2217/72 ,  C03C2218/119 ,  C03C2218/156 ,  C23C14/35

Abstract: The present invention relates to a process for manufacturing a one-way vision glass pane comprising one or more separate enamel patterns composed of a number of exactly aligned layers, characterized in that:a) at least one protective layer based on oxides, having a thickness greater than or equal to 10 nm, is deposited on the glass substrate, b) at least two layers of different compositions are deposited on the protective layer, the composition of one containing at least one mineral pigment and being free of glass frit, the composition of the other being an enamel containing at least one glass frit and at least one mineral pigment having a color different from that of the layer free of glass frit, the layer free of glass frit being deposited over all or some of the surface of the pane and the layer of enamel being deposited by screen printing in the shape of the desired pattern(s), c) the pane coated with said layers is heated at a temperature sufficient to fire the enamel, and d) the pigments not fixed by the enamel that are located outside of the pattern(s) are removed, the particles of pigment(s) and the particles of glass frit(s) having a similar size, in particular a particle size distribution such that 50% of the particles have a size of less than 7 μm.

Abstract translation: 本发明涉及一种用于制造提供单向视觉功能的玻璃面板的方法，并且包括由精确重合的多个层组成的一个或多个分立的釉质图案，其特征在于：a）至少一种基于氧化物 在玻璃基板上沉积厚度大于等于10nm的保护层; b）至少两层不同的组合物沉积在保护层上，这些层之一的组合物含有至少一种矿物颜料并且不含玻璃料，另一层的组合物是含有至少一块玻璃料的搪瓷 和至少一种与不含玻璃料的层的颜色不同的矿物颜料，没有玻璃料的层被沉积在面板的所有或一些表面上，并且搪瓷层通过丝网印刷以 所需的图案; c）将涂有所述层的面板加热至足够高的温度以烘烤搪瓷; 和d）不被釉质保持的颜料，即位于图案之外的颜料被去除，颜料颗粒和玻璃料的颗粒具有相似的尺寸，特别是具有 颗粒尺寸分布使得50％的颗粒尺寸小于7μm。

公开(公告)号：US20140212639A1

公开(公告)日：2014-07-31

申请号：US14230098

申请日：2014-03-31

Applicant: SAINT-GOBAIN GLASS FRANCE

Inventor： Sebastien WERY ,  Elodie DUCOURTHIAL ,  Angelique DEBRAINE ,  Benoit BARBIER ,  Virginie DUCLAUX

IPC: C09D11/10 ,  B32B17/10

CPC classification number: C09D11/106 ,  B32B17/10339 ,  C09D11/033 ,  C09D11/037 ,  Y10T428/24802 ,  Y10T428/24868

Abstract: The invention relates to a composition suitable for the black printing, via screen printing, of a sheet of polyvinyl butyral intended to be part of a laminated glazing unit, characterized in that it comprises: 11% to 13% by weight of polyvinyl butyral, 35% to 40% by weight of at least one aliphatic dicarboxylic acid diester, and at least one black pigment in an amount and with a specific surface area that are selected so that the Brookfield viscosity of the composition at 20° C. is between 9 and 13 Pa.s; a process for printing, via screenprinitng, a sheet of polyvinyl butyral intended to be part of a laminated glazing unit, using this composition; a sheet of polyvinyl butyral intended to be part of a laminated glazing unit, and printed, via screen printing, using this composition; and a laminated glazing unit comprising such a sheet of polyvinyl butyral.

Abstract translation: 本发明涉及一种适用于通过丝网印刷黑色印刷的组合物，其旨在成为层压玻璃单元的一部分的聚乙烯醇缩丁醛片，其特征在于其包含：11重量％至13重量％的聚乙烯醇缩丁醛，35 至少一种脂肪族二羧酸二酯的至少一种至少40重量％，以及至少一种黑色颜料，其数量和比表面积被选择为使组合物在20℃下的布鲁克菲尔德粘度在9和 13 Pa.s; 通过使用该组合物通过筛选印刷旨在成为层压玻璃单元的一部分的聚乙烯醇缩丁醛片的方法; 一层聚乙烯醇缩丁醛，其旨在成为层压玻璃单元的一部分，并通过丝网印刷使用该组合物印刷; 以及包括这种聚乙烯醇缩丁醛片的层压玻璃单元。

公开(公告)号：US20190276354A1

公开(公告)日：2019-09-12

申请号：US16334210

申请日：2017-09-19

Applicant: SAINT-GOBAIN GLASS FRANCE

Inventor： Elodie DUCOURTHIAL ,  Juliette MARIA ,  Christian RAVAGNANI ,  Marion LALLEMENT

IPC: C03C17/42

Abstract: A glass substrate includes on a face a water-insoluble polymeric temporary protective layer intended to be removed by heat treatment during a processing operation, and an enamel layer that has a mixture of glass frit, inorganic pigments and organic components that is deposited on at least one portion of the protective layer. The enamel has a glass transition temperature Tg above the temperature Tc60%, defined as being the temperature at which 60% of the initial weight of the protective layer is consumed, a maximum shrinkage measured by thermomechanical analysis between 450° C. and 650° C. greater than 20%, a difference between the inflection point temperature Tinflection and the glass transition temperature Tg less than 60° C., the inflection point temperature being defined as being the temperature at which the rate of displacement measured by thermomechanical analysis of the enamel is maximum, and a content of inorganic pigments less than 35% by weight.