TRANSPARENT GLASS CERAMIC AND COVER PANE
    2.
    发明公开

    公开(公告)号:US20240199473A1

    公开(公告)日:2024-06-20

    申请号:US18542213

    申请日:2023-12-15

    Applicant: SCHOTT AG

    Abstract: A transparent, chemically prestressable or chemically prestressed glass ceramic has a high transmittance, a low haze and a high crystal phase content of keatite solid solution. A method of making such a glass ceramic includes producing a silicate green glass with a melting process and subsequent hot shaping, temperature treating the silicate green glass with at least one nucleation step carried out in the temperature range of 690° C. to 850° C. for a period of 5 min to 72 h and at least one ceramization step carried out in the temperature range of 780° ° C. to 1100° C. for a period of 3 min to 150 h, and performing at least one ion exchange in an exchange bath at a temperature of the exchange bath between 370° C. and 500° ° C. for a period of between 2 hours and 50 hours

    ALUMINUM-DOPED LITHIUM ION CONDUCTOR BASED ON A GARNET STRUCTURE

    公开(公告)号:US20210344039A1

    公开(公告)日:2021-11-04

    申请号:US17244355

    申请日:2021-04-29

    Applicant: SCHOTT AG

    Abstract: The disclosure relates to an aluminum-doped lithium ion conductor based on a garnet structure comprising lanthanum, in particular an aluminum-doped lithium lanthanum zirconate (LLZO), in which the latter is co-doped with at least one trivalent M3+ ion on the lanthanum site, and in which the trivalent M3+ ion has an ionic radius that is smaller than that of La3+, and a higher lithium content is present in comparison to a stoichiometric garnet structure, with the provision that if M3+ is yttrium, a further trivalent M3+ ion, which is different than Y3+ and has an ionic radius that is smaller than that of La3+, is co-doped on the lanthanum site. A co-doping strategy is carried out, in which a doping on the lanthanum site with ions of the same valence, but smaller diameter brings about the change in the lattice geometry to the cubic modification. This leads to a stabilization of the cubic crystal modification that is present also with superstoichiometric quantities of lithium.

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