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公开(公告)号：US3663452A
公开(公告)日：1972-05-16
申请号：US3663452D
申请日：1970-05-15
Applicant: SHELL OIL CO
Inventor： KIOVSKY THOMAS E , WALD MILTON M
CPC classification number: C10G45/46 , B01J21/02 , B01J27/24 , C07C5/11 , C07C2527/125 , C07C2527/133 , C07C2527/135 , C07C2527/138 , Y10S585/943 , C07C13/48
Abstract: A CATALYST FOR INCREASING THE RATE OF HYDROGENATION REACTIONS INCLUDING A COMPLEX SALT OF THE CHLORIDE, BROMIDE OR IODINE OF ZINC, TIN, ANTIMONY, BISMUTH, CADMIUM, GALLIUM, MERCURY OR ARSENIC, AND THE CORRESPONDING AMMONIUM HALIDE.
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公开(公告)号：US3657108A
公开(公告)日：1972-04-18
申请号：US3657108D
申请日：1970-04-27
Applicant: SHELL OIL CO
Inventor： KIOVSKY THOMAS E , PETZNY WILFRIED J
Abstract: A process for regenerating metal halide catalysts deactivated in hydroconversion of nitrogen-containing feedstocks by the formation of metal halide-ammonium halide complexes is disclosed. Regeneration is effected by contacting the complex with an electron donor solvent for metal halide at conditions at which the solvent effects decomposition of the complex and separation of the resultant metal halide and ammonium halide decomposition products by dissolving the metal halide.
Abstract translation: 公开了通过形成金属卤化物 - 卤化铵络合物在含氮原料的加氢转化中失活的金属卤化物催化剂的再生方法。 通过使络合物与金属卤化物的电子给体溶剂接触，在溶剂分解络合物并通过溶解金属卤化物分离所得金属卤化物和卤化铵分解产物的条件下进行再生。
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公开(公告)号：US3685962A
公开(公告)日：1972-08-22
申请号：US3685962D
申请日：1970-04-27
Applicant: SHELL OIL CO
Inventor： KIOVSKY THOMAS E , PETZNY WILFRIED J
Abstract: A PROCESS IS DISCLOSED FOR RECOVERING METAL HALIDE FROM A METAL HALIDE-AMMONIUM HALIDE COMPLEX BY HEATING THE COMPLEX IN A THERMAL DECOMPOSITION ZONE AND PASSING THE RESULTING VAPOR PHASE SERIALLY THROUGH AT LEAST TWO CONDENSING ZONES, THE FIRST CONDENSING ZONE BEING MAINTAINED AT A TEMPERATURE AT WHICH THE HIGHER BOILING OF THE METAL HALIDE AND THE AMMONIUM HALIDE DECOMPOSITION PRODUCTS CONDENSES AND THE LOWER BOILING OF THE TWO IS IN VAPOR PHASE, AND THE SECOND CONDENSING ZONE BEING MAINTAINED AT A TEMPERATURE WHERE THE LOWER BOILING DECOMPOSITION PRODUCT CONDENSES.
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公开(公告)号：US3668109A
公开(公告)日：1972-06-06
申请号：US3668109D
申请日：1970-08-31
Applicant: SHELL OIL CO
Inventor： KIOVSKY THOMAS E , WALD MILTON M
Abstract: A process for hydroconversion or organic materials, particularly solid or very high boiling organic materials, by contacting such materials under hydrogen pressure and at elevated temperature with a continuous liquid phase catalyst containing gallium trichloride, gallium tribromide, gallium triiodide, mercuric bromide, mercuric iodide, stannic bromide, stannic iodide, stannous chloride, stannous bromide, stannous iodide, zirconium tetrachloride, zirconium tetrabromide, zirconium tetraiodide, titanium tetrabromide, titanium tetraiodide, titanium triiodide, cuprous chloride, cuprous bromide, cuprous iodide, hafnium tetrachloride, hafnium tetrabromide, or hafnium tetraiodide.
Abstract translation: 通过在氢气压力和升高的温度下将这些材料与含有三氯化镓，三溴化镓，三碘化镓，溴化汞，碘化汞的连续液相催化剂接触，加氢转化的方法或有机材料，特别是固体或非常高沸点的有机材料， 溴化锡，碘化锡，氯化亚锡，溴化亚锡，四氯化锆，四溴化锆，四碘化锆，四溴化钛，四碘化钛，三碘化钛，氯化亚铜，溴化亚铜，碘化亚铜，四氯化铪，四溴化铪或铪 四碘化物
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