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    Block copolymers having dissimilar nonelastomeric polymer blocks
    1.
    发明授权
    Block copolymers having dissimilar nonelastomeric polymer blocks 失效
    具有非线性非弹性聚合物块的嵌段共聚物

    公开(公告)号：US3706817A

    公开(公告)日：1972-12-19

    申请号：US3706817D

    申请日：1971-05-05

    Applicant: MILTON M WALD ,  SHELL OIL CO

    Inventor： WALD MILTON M ,  QUAM MYRON G

    IPC: C08F8/04 ,  C08F19/06 ,  C08F19/08

    CPC classification number: C08F8/04 ,  C08F297/04

    Abstract: THE RESISTANCE TO CREEP IS SUBSTANTIALLY IMPROVED IN BLOCK COPOLYMERS WHICH ARE SELECTIVELY HYDROGENATED AND HAVE WITHIN THE SAME BLOCK COPOLYMERIC MOLECULES NONELASTOMERIC BLOCKS A AND C AND ELASTOMERIC BLOCKS B WHEREIN, PRIOR TO HYDROGENATION, BLOCKS A ARE HOMOPOLYSTYRENE BLOCKS, BLOCKS B ARE CONJUGATED DIENE POLYMER BLOCKS AND BLOCKS C ARE HOMOPOLYMER BLOCKS OF ALPHA METHYL STYRENE; AND DUE TO HYDROGENATION, NO MORE THAN ABOUT 25% OF THE DOUBLE BONDS IN BLOCKS A AND C ARE REDUCED AND AT LEAST 90% OF THE ALIPHATIC DOUBLE BONDS OF BLOCKS B ARE REDUCED.

    Process of converting high-boiling hydrocarbon to lower-boiling fluid products
    4.
    发明授权
    Process of converting high-boiling hydrocarbon to lower-boiling fluid products 失效
    将高沸点碳氢化合物转化为低沸点流体产品的方法

    公开(公告)号：US3619411A

    公开(公告)日：1971-11-09

    申请号：US3619411D

    申请日：1969-07-15

    Applicant: SHELL OIL CO

    Inventor： WALD MILTON M

    IPC: C10G1/08 ,  B01J11/78 ,  C10G13/08 ,  C10G23/16

    CPC classification number: C10G47/08 ,  C10G1/086

    Abstract: Very high-boiling hydrocarbon, such as petroleum residue, is converted to low-boiling liquid products by passing it through a continuous phase of a catalyst system selected from antimony trichloride, tribromide or triiodide; bismuth trichloride or tribromide; or arsenic triiodide; maintained at a temperature between 200* and 550* C. and under hydrogen partial pressure of at least 250 p.s.i. whereby the catalyst system performs the functions of acting as a hydrogenation catalyst, acting as a cracking catalyst, and providing a medium for maintaining the reactants in suitable relation to one another to promote reactions and obtain beneficial product distribution.

    Selectively hydrogenated block copolymers
    9.
    发明授权
    Selectively hydrogenated block copolymers 失效
    选择性氢化嵌段共聚物

    公开(公告)号：US3700633A

    公开(公告)日：1972-10-24

    申请号：US3700633D

    申请日：1971-05-05

    Applicant: SHELL OIL CO ,  MILTON M WALA

    Inventor： WALD MILTON M ,  QUAM MYRON G

    IPC: C08F8/04 ,  C08F19/06 ,  C08F19/08

    CPC classification number: C08F8/04 ,  C08F297/04

    Abstract: BLOCK COPOLYMERS HAVING LOW MELT VISCOSITY AND IMPROVED PROCESSABILITY COMPRISE SELECTIVELY HYDROGENATED BLOCK COPOLYMERS COMPRISING A AND B, NON-ELASTOMERIC BLOCK A BEING SUBSTANTIALLY NON-HYDROGENATED HOMOPOLYMER BLOCKS OF MONO ALPHA ALKENYL ARENES AND ELASTOMERIC BLOCKS B BEING RANDOM COPOLYMER BLOCKS OF MONO ALPHA ALKENYL ARENES AND CONJUGATED DIENES WHEREIN AT LEAST 90% OF THE ALIPHATIC DOUBLE BONDS ARE HYDROGENATED.

    Process for hydroconversion of organic materials
    10.
    发明授权
    Process for hydroconversion of organic materials 失效
    有机材料的氢化过程

    公开(公告)号：US3668109A

    公开(公告)日：1972-06-06

    申请号：US3668109D

    申请日：1970-08-31

    Applicant: SHELL OIL CO

    Inventor： KIOVSKY THOMAS E ,  WALD MILTON M

    IPC: B01J27/06 ,  C10G1/08 ,  C10G1/06 ,  C10G13/02

    CPC classification number: C10G1/086 ,  B01J27/06

    Abstract: A process for hydroconversion or organic materials, particularly solid or very high boiling organic materials, by contacting such materials under hydrogen pressure and at elevated temperature with a continuous liquid phase catalyst containing gallium trichloride, gallium tribromide, gallium triiodide, mercuric bromide, mercuric iodide, stannic bromide, stannic iodide, stannous chloride, stannous bromide, stannous iodide, zirconium tetrachloride, zirconium tetrabromide, zirconium tetraiodide, titanium tetrabromide, titanium tetraiodide, titanium triiodide, cuprous chloride, cuprous bromide, cuprous iodide, hafnium tetrachloride, hafnium tetrabromide, or hafnium tetraiodide.

    Abstract translation: 通过在氢气压力和升高的温度下将这些材料与含有三氯化镓，三溴化镓，三碘化镓，溴化汞，碘化汞的连续液相催化剂接触，加氢转化的方法或有机材料，特别是固体或非常高沸点的有机材料， 溴化锡，碘化锡，氯化亚锡，溴化亚锡，四氯化锆，四溴化锆，四碘化锆，四溴化钛，四碘化钛，三碘化钛，氯化亚铜，溴化亚铜，碘化亚铜，四氯化铪，四溴化铪或铪 四碘化物

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