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公开(公告)号:US10427992B2
公开(公告)日:2019-10-01
申请号:US15770522
申请日:2016-10-25
申请人: SHELL OIL COMPANY
摘要: The invention concerns a process for oxidative dehydrogenation of ethane. In the process an ethane comprising stream is fed to a distillation column to remove propane. The purified ethane stream is subjected to oxidative dehydrogenation using a catalyst comprising Mo/V/Sb, or Mo/V/Nb and Te or Sb in the orthorhombic M1 crystalline phase. The reactor effluent comprises ethylene. The effluent is washed with water to remove acetic acid. The acetic acid is recovered from the aqueous stream by means of solvent extraction.
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公开(公告)号:US11117848B2
公开(公告)日:2021-09-14
申请号:US16500249
申请日:2018-04-09
申请人: SHELL OIL COMPANY
发明人: Georgios Mitkidis
IPC分类号: C07C2/84 , B01D53/14 , B01D53/22 , B01D3/14 , B01D53/047 , C07C7/00 , C07C7/04 , C07C7/12 , C07C7/144
摘要: The present invention relates to a process for oxidative coupling of methane (OCM), comprising the steps of: (a) contacting, in a reactor, oxygen and methane with an OCM catalyst, resulting in a reactor effluent comprising ethylene, ethane, methane, carbon dioxide and water; (b) cooling the reactor effluent to obtain a liquid stream comprising water and a gas stream comprising ethylene, ethane, methane and carbon dioxide; (c) removing carbon dioxide from at least a part of the gas stream comprising ethylene, ethane, methane and carbon dioxide resulting in a gas stream comprising ethylene, ethane and methane; (d) passing at least a part of the gas stream comprising ethylene, ethane and methane as obtained in step (c) through a membrane, preferably a membrane comprising metal cations, more preferably a membrane comprising silver (I) ions (Ag+ ions) or copper (I) ions (Cu+ ions), to obtain a stream comprising ethane and a stream comprising ethylene.
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公开(公告)号:US11078134B2
公开(公告)日:2021-08-03
申请号:US16486535
申请日:2018-02-20
申请人: SHELL OIL COMPANY
发明人: Georgios Mitkidis , Guus Van Rossum , Maria San Roman Macia , Ronald Jan Schoonebeek , Michael Johannes Franciscus Maria Verhaak
摘要: The invention relates to a process for the production of an alkene by alkane oxidative dehydrogenation, comprising: (a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a catalyst comprising a mixed metal oxide, resulting in a stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne; (b) removing water from at least part of the stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne resulting from step (a), resulting in a stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne; (c) removing unconverted oxygen, carbon monoxide and optionally alkyne from at least part of the stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne resulting from step (b), wherein carbon monoxide and optionally alkyne are oxidized into carbon dioxide, resulting in a stream comprising alkene, unconverted alkane and carbon dioxide; (d) optionally removing carbon dioxide from at least part of the stream comprising alkene, unconverted alkane in and carbon dioxide resulting from step (c), resulting in a stream comprising alkene and unconverted alkane; (e) optionally separating at least part of the stream comprising alkene and unconverted alkane resulting from step (d), into a stream comprising alkene and a stream comprising unconverted alkane; (f) optionally recycling unconverted alkane from at least part of the stream comprising unconverted alkane resulting from step (e), to step (a).
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公开(公告)号:US10329222B2
公开(公告)日:2019-06-25
申请号:US15760272
申请日:2016-09-16
申请人: SHELL OIL COMPANY
发明人: Alouisius Nicolaas Renée Bos , Georgios Mitkidis , Guus Van Rossum , Maria San Roman Macia , Ronald Jan Schoonebeek , Vatsal Mukundlal Shah , Michael Johannes Franciscus Maria Verhaak
IPC分类号: C07C5/48 , C07C11/04 , B01J27/057 , C07D301/08
摘要: The invention relates to a process of the oxidative dehydrogenation of a C2-6 alkane, comprising subjecting a stream comprising methane and the C2-6 alkane, in which stream the volume ratio of methane to the C2-6 alkane is of from 0.005:1 to 100:1, to oxydehydrogenation conditions resulting in a stream comprising methane, a C2-6 alkene and optionally a C2-6 carboxylic acid.
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