公开(公告)号：US11453653B2

公开(公告)日：2022-09-27

申请号：US17259979

申请日：2019-06-17

申请人： SABIC GLOBAL TECHNOLOGIES B.V.

发明人： Jintang Duan

IPC分类号： C07D301/08 ,  C07D303/04

摘要： Systems and methods for producing ethylene oxide (EO) are disclosed. Ethylene oxide is produced by direct oxidizing ethylene with oxygen in a reactor. The effluent from the reactor is processed to produce (a) a product stream comprising water and ethylene oxide, (b) a reabsorber overhead stream comprising ethylene, methane, argon, and carbon dioxide, and (c) a carbonate flash gas stream comprising carbon dioxide, ethylene, methane, and water. The reabsorber overhead stream and the carbonate flash gas stream are combined to form a reclaim gas stream. The reclaimed gas stream is separated in a membrane separation unit to remove carbon dioxide and argon, forming a recycle stream comprising primarily ethylene and methane, collectively.

公开(公告)号：US20210395171A1

公开(公告)日：2021-12-23

申请号：US17287758

申请日：2019-11-01

申请人： Trustees of Tufts College

发明人： Prashant Deshlahra ,  Leelavathi Annamalai

IPC分类号： C07C5/48 ,  C07D301/08 ,  B01J23/22 ,  B01J21/08

摘要： Disclosed are gas-phase ODH and OCP processes for converting alkanes (e.g., C2H6 and C3H8) to alkenes (e.g., C2H4 and C3H6) or oxygenates (e.g., methanol, ethanol, isopropanol, or propylene oxide) or converting alkenes (e.g., ethylene and propene) and oxygenates (e.g., methanol, ethanol, isopropanol or propylene oxide) to longer carbon-chain alkenes or longer carbon-chain alkanes with or without solid catalysts.

公开(公告)号：US10099189B2

公开(公告)日：2018-10-16

申请号：US15033749

申请日：2014-10-30

申请人： NIPPON SHOKUBAI CO., LTD.

发明人： Yuuji Shimasaki

IPC分类号： B01J19/30 ,  B01J7/00 ,  C07D307/60 ,  B01J8/06 ,  C07C37/58 ,  C07C51/25 ,  C07D301/08

摘要： In a fixed-bed flow reaction using a multitubular heat exchange type reactor, an object of the present invention is to provide a novel packing for a reaction tube, which can control the reaction ratio in the vicinity of the reaction tube inlet, reduce the load unevenly placed on the catalyst in the reaction region, and distribute the load on the entire catalyst layer, a heat exchange type reactor, and a reaction method using the reaction tube. The packing for a reaction tube of the present invention is characterized in that the volume is continuously or step-by-step decreased from one end part or midway toward the other end part.

公开(公告)号：US20170247309A1

公开(公告)日：2017-08-31

申请号：US15291011

申请日：2016-10-11

申请人： Novomer, Inc.

发明人： Richard V. PORCELLI ,  Jay J. FARMER ,  Robert E. LAPOINTE

IPC分类号： C07C51/09 ,  C08G63/81 ,  C07C51/12 ,  C07C67/36 ,  C07C57/04 ,  C08G63/82 ,  C07D305/12 ,  C07D301/08 ,  C07C67/475 ,  C08G63/08 ,  C08G63/06

CPC分类号： C07C51/09 ,  C07C51/12 ,  C07C67/03 ,  C07C67/36 ,  C07C67/475 ,  C07D301/08 ,  C07D305/12 ,  C08G63/06 ,  C08G63/08 ,  C08G63/81 ,  C08G63/82 ,  C08G63/823 ,  Y02P20/125 ,  C07C57/04 ,  C07C69/54

摘要： In one aspect, the present invention encompasses integrated processes for the conversion of epoxides to acrylic acid derivatives and polyesters. In certain embodiments, the methods of the present invention comprise the steps of: providing a feedstock stream comprising an epoxide and carbon monoxide; contacting the feedstock stream with a metal carbonyl in a first reaction zone to effect conversion of at least a portion of the provided epoxide to a beta lactone; directing the effluent from the first reaction zone to a second reaction zone where the beta lactone is subjected to conditions that convert it to a compound selected from the group consisting of: an alpha beta unsaturated acid, an alpha beta unsaturated ester, an alpha beta unsaturated amide, and an optionally substituted polypropiolactone polymer; and isolating a final product comprising the alpha-beta unsaturated carboxylic acid, the alpha-beta unsaturated ester, the alpha-beta unsaturated amide or the polypropiolactone.

公开(公告)号：US09067902B2

公开(公告)日：2015-06-30

申请号：US14152519

申请日：2014-01-10

申请人： Scientific Design Company, Inc.

发明人： Ashok S. Padia ,  Hassan Eisa Al-Ahmadi

IPC分类号： C07D301/03 ,  C07C43/00 ,  C07C29/00 ,  C07D301/10 ,  C07D301/08 ,  C07C29/10

CPC分类号： C07D301/10 ,  C07C29/106 ,  C07D301/08 ,  C07C31/202

摘要： A method for the epoxidation of an olefin comprising the steps of reacting a feed gas composition containing an olefin, oxygen, and a moderator having a post-conditioning step where the catalyst is exposed to reactor feed having a chlorides concentration of from about 5 ppm to about 7 ppm and at a temperature of about 215° C. to about 225° C.

摘要翻译： 一种用于烯烃环氧化的方法，包括以下步骤：使含有烯烃，氧和具有后处理步骤的缓和剂的进料气体组合物反应，其中催化剂暴露于反应器进料中，氯化物浓度为约5ppm至 约7ppm和约215℃至约225℃的温度

公开(公告)号：US20150073160A1

公开(公告)日：2015-03-12

申请号：US14385435

申请日：2013-03-15

申请人： UNIVERSITY OF KWAZULU-NATAL

发明人： David Lokhat ,  Maciej Starzak ,  Deresh Ramjugernath

IPC分类号： C07D301/08

CPC分类号： C07D301/08 ,  C07D303/08

摘要： A process for the production of HFPO includes introducing a feedstock comprising HFP and molecular oxygen into a heated reaction zone of a reactor. The reaction zone is at a reaction temperature Tr, where 180° C.≦Tr

摘要翻译： 用于生产HFPO的方法包括将包含HFP和分子氧的原料引入反应器的加热反应区。 反应区处于反应温度Tr，其中180℃＆amp; Tr; 230℃。通过HFP的环氧化使原料反应以产生HFPO。 HFPO从反应区撤出。 将原料引入反应区并将产物从反应区中取出是连续的。

公开(公告)号：US08871677B2

公开(公告)日：2014-10-28

申请号：US13316783

申请日：2011-12-12

申请人： Michael A. Richard ,  John David Covey

发明人： Michael A. Richard ,  John David Covey

IPC分类号： B01J23/02 ,  B01J23/10 ,  B01J23/48 ,  B01J23/50 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  B01J35/10 ,  C07D301/08 ,  C07C213/04 ,  B01J37/02 ,  B01J23/68

CPC分类号： B01J35/04 ,  B01J23/50 ,  B01J23/688 ,  B01J35/00 ,  B01J35/0066 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/024 ,  C07C29/106 ,  C07C41/03 ,  C07C213/04 ,  C07D301/04 ,  C07D301/08 ,  C07C215/08

摘要： A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.

摘要翻译： 公开了一种载体，其具有至少三个叶片，第一端部，第二端部，端部之间的壁和在端部和壁部的交叉点处的不均匀的过渡半径。 还公开了包含载体，银和沉积在载体上并可用于烯烃的环氧化的助催化剂的催化剂。 还公开了制备载体的方法，制备催化剂的方法以及与催化剂烯烃的环氧化方法。

公开(公告)号：US08822372B2

公开(公告)日：2014-09-02

申请号：US13516226

申请日：2010-12-14

申请人： Selim Senkan ,  Anusom Seubsai

发明人： Selim Senkan ,  Anusom Seubsai

IPC分类号： B01J27/13 ,  B01J23/40 ,  B01J23/70 ,  C07D301/03 ,  C07D301/04 ,  C07D301/10 ,  B01J23/89 ,  B01J35/00 ,  C07D301/08 ,  B01J37/02 ,  B01J35/10 ,  B01J21/06

CPC分类号： C07D301/10 ,  B01J21/063 ,  B01J21/066 ,  B01J23/89 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/0201 ,  C07D301/04 ,  C07D301/08

摘要： A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising a copper oxide and a ruthenium oxide on a porous support.

摘要翻译： 一种制备烯烃氧化物的方法，其包括在多孔载体上在包含氧化铜和氧化钌的催化剂存在下使烯烃与氧反应。

公开(公告)号：US20130281722A1

公开(公告)日：2013-10-24

申请号：US13978266

申请日：2011-12-15

申请人： Yoshihiko Ohishi ,  Anusorn Seubsai ,  Selim Senkan

发明人： Yoshihiko Ohishi ,  Anusorn Seubsai ,  Selim Senkan

IPC分类号： B01J27/057 ,  C07D301/08

CPC分类号： B01J27/0576 ,  B01J23/58 ,  B01J23/72 ,  B01J23/76 ,  B01J23/78 ,  B01J23/8926 ,  B01J23/8933 ,  B01J23/8946 ,  B01J27/08 ,  B01J27/128 ,  B01J27/13 ,  B01J35/002 ,  B01J37/0201 ,  C07D301/06 ,  C07D301/08

摘要： A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising a copper oxide and a tellurium oxide.

摘要翻译： 一种制备烯烃氧化物的方法，其包括在包含氧化铜和氧化碲的催化剂存在下使烯烃与氧反应。

公开(公告)号：US08334395B2

公开(公告)日：2012-12-18

申请号：US12678276

申请日：2008-11-07

申请人： Harvey E. Andresen ,  Christopher P. Christenson ,  Charles W. Lipp ,  John R. Mayer ,  Thomas J. Kling ,  Victor R. Fey ,  Laurence G. Britton ,  Michael J. Rangitsch ,  Michael L. Hutchison

发明人： Harvey E. Andresen ,  Christopher P. Christenson ,  Charles W. Lipp ,  John R. Mayer ,  Thomas J. Kling ,  Victor R. Fey ,  Laurence G. Britton ,  Michael J. Rangitsch ,  Michael L. Hutchison

IPC分类号： C07D301/08 ,  B01J19/00

CPC分类号： B01J12/00 ,  B01F3/04049 ,  B01F5/045 ,  B01F5/0453 ,  B01F5/0456 ,  B01F5/0475 ,  B01F5/048 ,  B01J4/002 ,  B01J19/26 ,  B01J2219/00263 ,  C07D301/08

摘要： A hydrocarbon-containing gas is mixed with an oxygen gas in a gas mixer in the presence of coarse water droplet environment, e.g., a ‘rainy’ or ‘driving rainstorm’ environment in which the water droplets generally have a size greater than 200 microns SMD. The water droplets surround and contact entrained particles in either the oxygen gas stream or the hydrocarbon-containing gas stream. The water acts to suppress, prevent and quench ignition of the hydrocarbon gas in the mixer which would otherwise be caused by energetic collisions between such particles and structures within the gas mixer. In one configuration the gas mixer includes water pipes having coarse water droplet-producing nozzles at the peripheral end thereof concentrically located within oxygen supply pipes. Additionally, nozzles introduce coarse water droplets into a pipe carrying the hydrocarbon gas and forming a mixing chamber for the hydrocarbon and oxygen gases.

摘要翻译： 在粗水滴环境（例如其中水滴通常具有大于200微米SMD的尺寸的雨水或驾驶暴雨环境）的存在下，在气体混合器中将含烃气体与氧气混合。 水滴在氧气流或含烃气流中包围并接触夹带的颗粒。 该水起到抑制，预防和熄灭混合器中的烃气体的点燃作用，否则其将由气体混合器内的这种颗粒和结构之间的能量碰撞引起。 在一种配置中，气体混合器包括在其外周端具有粗水分产生喷嘴的水管，其同心地位于供氧管内。 此外，喷嘴将粗水滴引入携带烃气体的管道中，并形成烃和氧气体的混合室。