公开(公告)号：US3725514A

公开(公告)日：1973-04-03

申请号：US3725514D

申请日：1969-11-03

申请人： SUMITOMO CHEMICAL CO

发明人： TSUCHIYA H ,  MUKAI K ,  OOISHI T ,  TAKEDA H ,  OKUNO S ,  TANAKA K ,  FUJIMOTO K ,  OZAKI T ,  KIMURA A ,  KAWANO S

IPC分类号： A01N57/10 ,  C07F9/18 ,  A01N9/36

CPC分类号： A01N57/10 ,  C07F9/18

摘要： X being phenyl, phenylalkyl, alkoxy, dialkylamino, acylamido or halogen, provided that at least one X is group other than halogen atom, and n being an integer of 1 - 5. These organic phosphorothiolates can be obtained by reacting a thionophosphate having the formula,
WHEREIN R and B are as defined above, with an alkali hydrosulfide having the formula,


WHEREIN R is lower alkyl; A is alkyl, alkenyl, alkinyl, haloalkyl or phenylalkyl; B is a group of the formula,

Novel organic phosphorothiolates, which have both strongly insecticidal and fungicidal activities and low toxicity to mammals, having the formula,

摘要翻译： 新型有机硫代磷酸酯具有强烈的杀虫活性和杀真菌活性，对哺乳动物毒性低，具有下式：其中R为低级烷基; A是烷基，烯基，炔基，卤代烷基或苯基烷基; B是式的基团，X是苯基，苯基烷基，烷氧基，二烷基氨基，酰基酰氨基或卤素，条件是至少一个X是除卤素原子以外的基团，n是1-5的整数。

公开(公告)号：US3824306A

公开(公告)日：1974-07-16

申请号：US32371473

申请日：1973-01-15

申请人： SUMITOMO CHEMICAL CO

发明人： TSUCHIYA H ,  MUKAI K ,  FUJIMOTO K ,  OZAKI T ,  KIMURA A ,  KAWANO S ,  OOISHI T ,  TAKEDA H ,  OKUNO Y ,  TANAKA K

IPC分类号： A01N57/10 ,  C07F9/18 ,  A01N9/36

CPC分类号： A01N57/10 ,  C07F9/18

摘要： AN INSECTICIDAL OR FUNGICIDAL COMPOSITION WHICH HAS STRONGLY INSECTICIDAL OR FUNGICIDAL ACTIVITY AND LOW TOXICIRY TO MAMMALS, CONTAINING AN ORGANIC PHOSPHOROTHIOLATE HAVING THE FORMULA,

B-O-P(=O)(-OR)-S-A

WHEREIN R IS LOWER ALKYL; A IS ALKYL, HALOALKYL OR PHENYLALKYL; B IS A GROUP OF THE FORMULA,

(X)N-PHENYL OR NAPHTHYL

X BEING PHENYL, PHENYLALKYL, OR HALOGEN, PROVIDED THAT AT LEAST ONE X IS A GROUP OTHER THAN HALOGEN ATOM, AND N BEING AN INTEGER OF 1-5 IS DISCLOSED.

公开(公告)号：US3812223A

公开(公告)日：1974-05-21

申请号：US16409071

申请日：1971-07-19

申请人： SUMITOMO CHEMICAL CO

发明人： TSUCHIYA H

IPC分类号： C07F9/02 ,  C07C67/00 ,  C07C325/00 ,  C07C333/20 ,  C07C333/24 ,  C07F9/165 ,  C07F9/22 ,  C07F9/24 ,  C07F9/30 ,  C07F9/32 ,  C07F9/38 ,  C07F9/44 ,  C08K5/49 ,  C08K5/5398

CPC分类号： C08K5/49 ,  C07F9/165 ,  C07F9/222 ,  C07F9/24 ,  C07F9/30 ,  C07F9/38 ,  C07F9/44 ,  C08K5/5398 ,  C08L21/00

摘要： Thio- or dithio-phosphoric acid salts, which are indispensable intermediates for producing phosphoric acid esters of the thiol or dithiol type useful as agricultural chemicals, are produced by reacting a thionophosphoric acid ester with an alkali metal salt of a dithiocarbamic acid at 50* to 150*C in the presence of a solvent such as an aqueous or anhydrous alcohol, a Cellosolve, dimethylformamide, dimethyl sulfoxide, or the like.

公开(公告)号：US3725546A

公开(公告)日：1973-04-03

申请号：US3725546D

申请日：1970-08-05

申请人： SUMITOMO CHEMICAL CO

发明人： TSUCHIYA H ,  MUKAI K ,  KIMURA A ,  WAKATSUKI T ,  NISHIZAWA Y ,  OKUNO Y ,  OGAWA T ,  FUJIMOTO K ,  OZAKI T

IPC分类号： A01N57/10 ,  C07F9/165 ,  C07F9/173 ,  C07F9/177 ,  C07F9/18 ,  A01N9/36

CPC分类号： C07F9/18 ,  A01N57/10 ,  C07F9/1651 ,  C07F9/1653 ,  C07F9/173 ,  C07F9/177

摘要： Method for controlling insects and fungi, in which the insects and fungi are contacted with a phosphorodithiolate of the formula,

WHEREIN R is a lower alkyl; A is a lower alkyl, etc.; and B is phenylalkyl, etc. Two typical examples of the phosphorodithiolates are shown by the formula

The compounds can be prepared by condensing a dithioate of the formula,

WHEREIN A and R are as mentioned above and M is an alkali metal or ammonium group, with a halide of the formula,

摘要翻译： 用于控制昆虫和真菌的方法，其中昆虫和真菌与下式的二硫代硫酸盐接触，WHEREIN R是低级烷基; A是低级烷基等; 并且B是苯基烷基等。下式示出了二硫代硫酸盐的两个典型实例。化合物可以通过将下式的二硫代酸酯，其中WHEREIN A和R如上所述并且M是碱金属或铵基团与 一种式B的卤化物。