公开(公告)号：US3800011A

公开(公告)日：1974-03-26

申请号：US8022470

申请日：1970-10-12

申请人： SUMITOMO CHEMICAL CO

发明人： FUJIMOTO K ,  KAWANO S ,  TANAKA K ,  TAKEDA H ,  MUKAI K ,  HIRANO M

IPC分类号： A01N57/28 ,  C07F9/24 ,  A01N9/36

CPC分类号： C07F9/2458 ,  C07F9/24

摘要： Amidothiol phosphoric acid esters having the formula,

WHEREIN R1 is methyl, ethyl or propyl, R2 is a C3-C10 alkenyl, a C2-C10 alkylthioalkyl, a C2-C10 alkoxyalkyl or a C2-C10 cyanoalkyl, and A is a C1-C3 alkyl, a C3-C6 alkenyl, a C3-C6 alkinyl, a halogen-substituted C3-C6 alkenyl or a halogensubstituted C3-C6 alkinyl, which are used as an active ingredient of a pest controlling composition with a systemic action.

摘要翻译： 具有下式的氨基硫醇磷酸酯，其中R1是甲基，乙基或丙基，R2是C3-C10烯基，C2-C10烷硫基烷基，C2-C10烷氧基烷基或C2-C10氰基烷基，A是C1-C3 烷基，C 3 -C 6烯基，C 3 -C 6炔基，卤素取代的C 3 -C 6烯基或卤素取代的C 3 -C 6炔基，其用作具有全身作用的害虫控制组合物的活性成分。

公开(公告)号：US3850977A

公开(公告)日：1974-11-26

申请号：US19153971

申请日：1971-10-21

申请人： SUMITOMO CHEMICAL CO

发明人： ITAYA N ,  MIZUTANI T ,  FUJIMOTO K ,  OKUNO Y ,  KITAMURA S ,  KAMEDA N

IPC分类号： A01N53/00 ,  C07D207/32 ,  C07D207/333 ,  C07D307/45 ,  C07D317/60 ,  C07C69/74 ,  C07C69/76

CPC分类号： C07D207/333 ,  A01N53/00 ,  C07D307/42 ,  C07D317/60 ,  Y10S514/937 ,  Y10S514/957

摘要： 1. A 3-SUBSTITUTED-BENZYL CYCLOPROPANECARBOXYLATE REPRESENTED BY THE FORMULA,

1-R1,1-R2,2,2-DI(H3C-)-CYCLOPROP-3-YL-COO-CH2-(1,3-

PHENYLENE)-CH2-R3

WHEREIN R1 IS A HYDROGEN ATOM OR A METHYL GROUP; R2 IS METHYL, 2-METHYL-1-PROPENYL, 2-METHOXYCARBONYL-1-PROPENYL OR PHENYL WHEN R1 IS A HYDROGEN, OR METHYL GROUP WHEN R1 IS A METHYL GROUP; AND R3 IS A PHENYL GROUP WHICH MAY BE SUBSTITUTED BY A CHLORINE ATOM OR A METHYL GROUP.

公开(公告)号：US3725514A

公开(公告)日：1973-04-03

申请号：US3725514D

申请日：1969-11-03

申请人： SUMITOMO CHEMICAL CO

发明人： TSUCHIYA H ,  MUKAI K ,  OOISHI T ,  TAKEDA H ,  OKUNO S ,  TANAKA K ,  FUJIMOTO K ,  OZAKI T ,  KIMURA A ,  KAWANO S

IPC分类号： A01N57/10 ,  C07F9/18 ,  A01N9/36

CPC分类号： A01N57/10 ,  C07F9/18

摘要： X being phenyl, phenylalkyl, alkoxy, dialkylamino, acylamido or halogen, provided that at least one X is group other than halogen atom, and n being an integer of 1 - 5. These organic phosphorothiolates can be obtained by reacting a thionophosphate having the formula,
WHEREIN R and B are as defined above, with an alkali hydrosulfide having the formula,


WHEREIN R is lower alkyl; A is alkyl, alkenyl, alkinyl, haloalkyl or phenylalkyl; B is a group of the formula,

Novel organic phosphorothiolates, which have both strongly insecticidal and fungicidal activities and low toxicity to mammals, having the formula,

摘要翻译： 新型有机硫代磷酸酯具有强烈的杀虫活性和杀真菌活性，对哺乳动物毒性低，具有下式：其中R为低级烷基; A是烷基，烯基，炔基，卤代烷基或苯基烷基; B是式的基团，X是苯基，苯基烷基，烷氧基，二烷基氨基，酰基酰氨基或卤素，条件是至少一个X是除卤素原子以外的基团，n是1-5的整数。

公开(公告)号：US3716560A

公开(公告)日：1973-02-13

申请号：US3716560D

申请日：1970-03-26

申请人： SUMITOMO CHEMICAL CO

发明人： TAYA N ,  MIZUTANI T ,  FUJIMOTO K ,  KITAMURA S ,  OKUNO Y

IPC分类号： C07D307/80 ,  C07D493/04 ,  C07D5/36

CPC分类号： C07D493/04 ,  C07D307/80

摘要： Cyclopropanecarboxylic acid esters represented by the formula, WHEREIN R1 represents hydrogen or methyl; R2 represents methyl, 2-methyl-1-propenyl or 2-methoxy-carbonyl-1-propenyl when R1 is hydrogen and R2 represents methyl when R1 is methyl; R3 represents hydrogen or methyl; and R4 represents a lower alkylene radical containing or not containing oxygen or sulfur atom in its carbon chain, the alkylene having up to four carbon atoms, which may be useful as insecticides having high insecticidal effects and low toxicity to mammals.

摘要翻译： 由下式表示的环丙烷羧酸酯，WHEREIN R1表示氢或甲基; 当R 1为氢时，R 2表示甲基，2-甲基-1-丙烯基或2-甲氧基 - 羰基-1-丙烯基，当R 1为甲基时，R 2表示甲基; R3表示氢或甲基; R4表示在其碳链中含有或不含有氧或硫原子的低级亚烷基，该亚烷基具有至多4个碳原子，其可用作具有高杀虫作用和对哺乳动物毒性低的杀虫剂。

公开(公告)号：US3822307A

公开(公告)日：1974-07-02

申请号：US23050972

申请日：1972-02-29

申请人： SUMITOMO CHEMICAL CO

发明人： OKUNO Y ,  KAMOSHITA K ,  FUJIMOTO K ,  OGAWA T ,  SHIGEHIRO K ,  NAKAI S ,  KOTERA N

IPC分类号： A01N47/22 ,  C07C271/06 ,  G01R19/155 ,  H01J17/16 ,  C07C125/06

CPC分类号： G01R19/155 ,  A01N47/22 ,  C07C271/06 ,  H01J17/16

摘要： A CARBAMATE COMPOUND OF THE FORMULA:

1-(H3C-NH-CO-O-),2-(H3C-),5-R-BENZENE

WHEREIN R IS SEC-BUTYL OR TERT-BUTYL, WHICH IS PREPARED BY REACTING A HYDROXYL COMPOUND OF THE FORMULA:

2-(H3C-),5-R-PHENOL

WHEREIN R IS AS DEFINED ABOVE WITH PHOSGENE AND THEN REACTING THE RESULTANT CARBONYL CHLORIDE COMPOUND WITH METHYLAMINE OR BY REACTING THE SAID HYDROXYL COMPOUND WITH METHYL SIOCYANATE. THE CARBAMATE COMPOUND IS USEFUL AS AN INSECTICIDAL AGENT OF HIGH SAFETY.

公开(公告)号：US3799380A

公开(公告)日：1974-03-26

申请号：US21260271

申请日：1971-12-27

申请人： SUMITOMO CHEMICAL CO ,  HASHIMOTO KOGYO CO LTD

发明人： IWASA K ,  FUJIMOTO K ,  KANAIWA T ,  HASHIMOTO R ,  KAMADA H

IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/48 ,  C09K3/10 ,  B65D23/02 ,  B65D53/04

CPC分类号： C09K3/1021 ,  C08G18/00 ,  C08G18/10 ,  C08G18/4804 ,  C09K2200/023 ,  C09K2200/0239 ,  C09K2200/0243 ,  C09K2200/0252 ,  C09K2200/026 ,  C09K2200/0652 ,  Y10T428/24999 ,  C08G18/40

摘要： A gasket is prepared in a bottle cap by reacting in the bottle cap a first component containing a polyol having 2 or 3 hydroxyl functional groups in one molecule and a second component containing a polymethylene polyphenylisocyanate, preferably a quasi-prepolymer of a polymethylene polyphenylisocyanate having an isocyanate equivalent of not more than 300 until a cured substantially non-porous polyurethane gasket is obtained. The thus obtained seaing gasket undergoes neither deformation, color change nor weight loss over a prolonged period of time and has no tackiness on its surface.

摘要翻译： 在瓶盖中通过在一个分子中使包含具有2或3个羟基官能团的多元醇的第一组分和含有多亚甲基多苯基异氰酸酯的第二组分（优选多亚甲基多苯基异氰酸酯的准预聚物）在瓶盖中反应来制备密封垫， 异氰酸酯当量不超过300，直到获得固化的基本上无孔聚氨酯垫片为止。 这样得到的海垫在长时间内不会发生变形，颜色变化和体重损失，并且在其表面上没有粘性。

公开(公告)号：US3857863A

公开(公告)日：1974-12-31

申请号：US16836971

申请日：1971-08-02

申请人： SUMITOMO CHEMICAL CO

发明人： OHNO N ,  ITAYA N ,  MIZUTANI T ,  KAWANAMI T ,  OKUNO Y ,  FUJIMOTO K

IPC分类号： C07D333/16 ,  A01N53/04 ,  C07D307/42 ,  C07D307/45 ,  C07D307/56 ,  C07D5/18 ,  C07D5/16 ,  C07D5/20

CPC分类号： C07D307/42 ,  C07D307/56

摘要： A cyclopropanecarboxylate represented by the formula,

WHEREIN R1 is hydrogen atom, methyl or ethyl group, R2 is methyl, ethyl, 2-methyl-1-propenyl or 2-methoxycarbonyl-1propenyl group when R1 is hydrogen atom, or R2 is methyl or ethyl group when R1 is methyl or ethyl group, and R3 and R4 are respectively hydrogen atom, methyl or ethyl group, provided that the case where R1, R3 and R4 are simultaneously hydrogen atom is excluded, R5 is a lower alkynyl or a lower alkenyl group, R6 is a lower alkynyl, a lower alkenyl or a lower alkoxyalkyl group, R7 is hydrogen atom, a lower alkyl or a lower alkoxy group or a halogen atom, n is 1 or 2, and X is oxygen or sulfur atom, which is useful as an active ingredient of insecticides.

摘要翻译： 由式表示的环丙烷羧酸酯，其中当R1是氢原子时，R1是氢原子，甲基或乙基，R2是甲基，乙基，2-甲基-1-丙烯基或2-甲氧基羰基-1-丙烯基，或R2是甲基 或R1为甲基或乙基时为乙基，R3和R4分别为氢原子，甲基或乙基，但R1，R3和R4同时为氢原子的情况除外，R5为低级炔基或低级 烯基，R6为低级炔基，低级烯基或低级烷氧基烷基，R7为氢原子，低级烷基或低级烷氧基或卤素原子，n为1或2，X为氧或硫原子， 其作为杀虫剂的活性成分是有用的。

公开(公告)号：US3857858A

公开(公告)日：1974-12-31

申请号：US2485870

申请日：1970-04-01

申请人： SUMITOMO CHEMICAL CO

发明人： FUJIMOTO K ,  KITAMURA S ,  OKUNO Y ,  ITAYA N ,  MIZUTANI T

IPC分类号： A01N53/04 ,  C07C69/00 ,  C07C69/74 ,  C07D63/12 ,  C07D5/16

摘要： Novel carboxylic acid esters represented by the formula,

WHEREIN R1 represents hydrogen atom or methyl group; R2 represents methyl, 2-methyl-1-propenyl or 2-methoxy-carbonyl-1propenyl group when R1 is hydrogen atom, and R2 represents methyl group when R1 is methyl group; and R represents

(WHEREIN R3 is a phenylene group, a thiophene residue or a furan residue),

(WHEREIN R4 is an allyl or propargyl group) or R5-CH2-C*C(CH2)n- (wherein R5 is a phenyl, chlorophenyl, tolyl, thienyl, furyl or ethynyl group, and n is an integer of 1 or 2), which may be useful for the production of insecticides having excellent insecticidal activity and low toxicity to mammals.

摘要翻译： 由式表示的新型羧酸酯，WHERE R1表示氢原子或甲基; 当R 1是氢原子时，R 2表示甲基，2-甲基-1-丙烯基或2-甲氧基 - 羰基-1-丙烯基，当R 1是甲基时，R 2表示甲基; 并且R表示（其中R 3是亚苯基，噻吩残基或呋喃残基），（其中R 4是烯丙基或炔丙基）或R 5 -CH 2 -C 3 CF（CH 2）n - （其中R 5是苯基 ，氯苯基，甲苯基，噻吩基，呋喃基或乙炔基，n为1或2的整数），其可用于生产具有优异的杀虫活性和对哺乳动物毒性低的杀虫剂。

公开(公告)号：US3824306A

公开(公告)日：1974-07-16

申请号：US32371473

申请日：1973-01-15

申请人： SUMITOMO CHEMICAL CO

发明人： TSUCHIYA H ,  MUKAI K ,  FUJIMOTO K ,  OZAKI T ,  KIMURA A ,  KAWANO S ,  OOISHI T ,  TAKEDA H ,  OKUNO Y ,  TANAKA K

IPC分类号： A01N57/10 ,  C07F9/18 ,  A01N9/36

CPC分类号： A01N57/10 ,  C07F9/18

摘要： AN INSECTICIDAL OR FUNGICIDAL COMPOSITION WHICH HAS STRONGLY INSECTICIDAL OR FUNGICIDAL ACTIVITY AND LOW TOXICIRY TO MAMMALS, CONTAINING AN ORGANIC PHOSPHOROTHIOLATE HAVING THE FORMULA,

B-O-P(=O)(-OR)-S-A

WHEREIN R IS LOWER ALKYL; A IS ALKYL, HALOALKYL OR PHENYLALKYL; B IS A GROUP OF THE FORMULA,

(X)N-PHENYL OR NAPHTHYL

X BEING PHENYL, PHENYLALKYL, OR HALOGEN, PROVIDED THAT AT LEAST ONE X IS A GROUP OTHER THAN HALOGEN ATOM, AND N BEING AN INTEGER OF 1-5 IS DISCLOSED.

公开(公告)号：US3725546A

公开(公告)日：1973-04-03

申请号：US3725546D

申请日：1970-08-05

申请人： SUMITOMO CHEMICAL CO

发明人： TSUCHIYA H ,  MUKAI K ,  KIMURA A ,  WAKATSUKI T ,  NISHIZAWA Y ,  OKUNO Y ,  OGAWA T ,  FUJIMOTO K ,  OZAKI T

IPC分类号： A01N57/10 ,  C07F9/165 ,  C07F9/173 ,  C07F9/177 ,  C07F9/18 ,  A01N9/36

CPC分类号： C07F9/18 ,  A01N57/10 ,  C07F9/1651 ,  C07F9/1653 ,  C07F9/173 ,  C07F9/177

摘要： Method for controlling insects and fungi, in which the insects and fungi are contacted with a phosphorodithiolate of the formula,

WHEREIN R is a lower alkyl; A is a lower alkyl, etc.; and B is phenylalkyl, etc. Two typical examples of the phosphorodithiolates are shown by the formula

The compounds can be prepared by condensing a dithioate of the formula,

WHEREIN A and R are as mentioned above and M is an alkali metal or ammonium group, with a halide of the formula,

摘要翻译： 用于控制昆虫和真菌的方法，其中昆虫和真菌与下式的二硫代硫酸盐接触，WHEREIN R是低级烷基; A是低级烷基等; 并且B是苯基烷基等。下式示出了二硫代硫酸盐的两个典型实例。化合物可以通过将下式的二硫代酸酯，其中WHEREIN A和R如上所述并且M是碱金属或铵基团与 一种式B的卤化物。