摘要:
LINEAR POLYESTERS HAVING GOOD TEMPERATURE, HYDROLYTIC AND U.V. STABILITY ARE PREPARED FROM HYDROCARBON ADAMANTANE DIOLS AND CYCLOALKYL ORGANIC DIACIDS. THE HYDROXYL GROUPS ARE BRIDGEHEAD POSITIONS IN THE ADAMANTANE MOIETY AND PREFERABLY THE ADAMANTANE MOIETY CONTAINES SUBSTITUENTS AT THE REMAINING BRIDGEHEAD POSITIONS THUS REMOVING ALL TERTIARY HYDROGEN-ATOMS THEREFROM. THE POLYESTERS ARE USEFUL FOR PREPARING COATINGS, FILMS AND FIBERS.
摘要:
Polyamides are produced by reacting an organic dinitrile with adamantane and alkyl-adamantane compounds having two substituents selected from the group consisting of chlorine, bromine and hydroxy in the presence of a strong sulfuric acid corresponding to 99.5-118% H2SO4 equivalent or polyphosphoric acid.
摘要翻译:聚酰胺通过有机二腈与对应于99.5-118%H 2 SO 4当量或多聚磷酸的强硫酸存在下,具有两个选自氯,溴和羟基的取代基的金刚烷和烷基金刚烷化合物反应制备。
摘要:
POLYMERIZATION OF ISOBUTENE TO FORM A POLYISOBUTENE OIL HAVING A VISCOSITY INDEX OF FROM 90-130, IN THE PRESENCE OF A LOWER ALKYLHALIDE SUCH AS 2-CHLORO-2-METHYLPROPANE USING A CATALYST SELECTED FROM THE CLASS CONSISTING OF ETHYL ALUMINUM SESQUICHLORIDE, ETHYL ALUMINUM DICHLORIDE AND DIISOBUTYL ALUMINUM CHLORIDE AND A SOLVENT SELECTED FROM THE CLASS CONSISTING OF NITROMETHANE AND NITROBENZENE AT FROM -30 TO 100*C. AND PREFERABLY FROM 0*C. TO 50*C. OPTIONALLY A METAL HALIDE SUCH AS COBALT CHLORIDE MAY BE USED AS A PROMOTER FOR THE CATALYST.
摘要:
CURABLE POLYESTERS CONTAINING AN ADAMANTANE MOIETY ARE PREPARED IN ONE- OR TWO-STAGE CONDENSATION TYPE REACTIONS. THE POLYESTERS ARE PREPARED FROM A HYDROCARBON SUBSTITUTED ADAMANTANE DIOL AND ANHYDRIDE OF UNSATURATED DIACIDS SUCH AS MALEIC ACID ALONE OR WITH A SECOND DIOL SUCH AS ETHYLENE GLYCOL. IN ADDITION TO THE ANHYDRIDES OF UNSATURATED DIACIDS, THE POLYESTER CAN CONTAIN SATURATED DIACID MOIETIES. THE POLYESTERS SO PREPARED CAN BE CROSSLINKED WITH A CONVENTIONAL CROSSLINKING AGENT AND CURABLE POLYMER CAN BE CAST INTO SHEETS OR FILMS AND CURED. THE CURABLE BLEND CAN BE USED AS A COATING AND CURED IN PLACE TO GIVE CHEMICAL-RESISTANT SURFACES. THE CROSSLINKED POLYMERS EXHIBIT EXTREMELY GOOD HYDROLYTIC AND SOLVENT STABILITY WITH GOOD HEAT AND ULTRAVIOLET STABILITY.
摘要:
Normally liquid curable polyesters that are plasticizers which add ultraviolet stability to solid vinyl chloride polymers are prepared from Alpha , Alpha ''-dimethyl muconic acids and derivatives thereof and polyethylene glycols.
摘要:
SIMULTANEOUSLY OR SUCCESSIVELY POLYMERIZING OF ISOBUTENE TO FORM A POLYISOBUTENE HAVING A VISCOSITY INDEX OF FROM 95-130, AND A-METHYLSTYRENE, USING STANNIC CHLORIDE AS THE CATALYST AND NITROMETHANE AS THE SOLVENT AT FROM -30 TO 200*C.AND PREFERABLY FROM 0*C.TO 50* C. THE STANNIC CHLORIDE IS PRESENT IN FROM 0.5 TO 40 AND PREFERABLY 1 TO 20 VOLUME PERCENT AS BASED ON THE NITROMETHANE PRESENT.