摘要:
A polyester resin has excellent adhesiveness and excellent grindability. The polyester resin includes a constitutional unit A derived from a carboxylic acid having a cyclic structure and containing 5 or more carboxyl groups, a constitutional unit derived from a dicarboxylic acid, and a constitutional unit derived from a polyhydric alcohol. The constitutional unit A has a content of 0.01 parts by mole or more and 45 parts by mole or less with respect to 100 parts by mole of the constitutional unit derived from a dicarboxylic acid. The hydroxyl value of the polyester resin is 6 mgKOH/g or more and 27 mgKOH/g or less.
摘要:
The preparation of cyclohexadienes from one or more plant oils is disclosed. The cyclohexadiene can be used to form polymers or derivatized to form other monomers that can be used to form polymeric materials.
摘要:
The present invention is directed to a series of polyesters that are made by the reaction of a diacid with a pre-formed mono-hydroxy, di-hydroxy and optionally a tri-hydroxy ester of polyols selected from pentaerythritol, dipentearythritol trimethylolpropane and mixtures thereof. When reacted in the sequence shown, that is pre-formation of the mono-ester, di-ester and tri-ester, selection of the proper ratio of one to the other and then and only then reacted with the diacid, do these polyesters remain free of a gel and form cosmetically elegant oil phases.
摘要:
This invention relates to the new functional norbornanyl ester derivative and/or polymer compositions which are easily obtainable by reacting the Diels-Alder adduct of appropriate dienes and dienophiles with carboxylic acids. In particular, this invention relates to a new process for making cyclic chemical raw materials suitable for production coating, ink, adhesive, plasticizer, thermoplastic or thermosetting plastic and functional polymers.
摘要:
A toner for developing an electrostatic charge image which contains a polyester resin as a binder resin is provided. The toner has excellent toner properties including low temperature fixing properties, anti-blocking property and anti-offset property, etc. Also a polyester resin for a toner is provided, which is used in the above-mentioned toner. As the binder resin for toner, a polyester resin comprising (1) an aromatic dicarboxylic acid and (2) a disproportionated rosin as an acid component, and (3) a tri- or more-valent polyhydric alcohol as an alcohol component is used, wherein the molar ratio (3)/(1) of the alcohol component (3) and the acid component (1) is from 1.05 to 1.65 and the molar ratio (2)/(1) of the acid components (2) and (1) is from 0.40 to 2.60.
摘要:
This invention relates to a process for making at least one polyester comprising: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; (b) a glycol component comprising: (i) 10 to 50 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, which is a combination of greater than 80 mole % of cis-2,2,4,4-tetramethyl-1,3-cyclobutanediol and less than 20 mole % of trans-2,2,4,4-tetramethyl-1,3-cyclobutanediol, or greater than 85 mole % of cis-2, 2,4,4-tetramethyl-1,3-cyclobutanediol and less than 15 mole % of trans-2,2,4,4-tetramethyl-1,3-cyclobutanediol, or greater than 90 mole % of cis-2,2,4,4-tetramethyl-1,3-cyclobutanediol and less than 10 mole % of trans-2,2,4,4-tetramethyl-1,3-cyclobutanediol, or greater than 95 mole % of cis-2, 2,4,4-tetramethyl-1,3-cyclobutanediol and less than 5 mole % of trans-2,2,4,4-tetramethyl-1,3-cyclobutanediol; (ii) 50 to 90 mole % of cyclohexanedimethanol residues; and (iii) optionally, residues of at least one modifying glycol; wherein the total mole % of the dicarboxylic acid component of the final polyester is 100 mole %; wherein the total mole % of the glycol component of the final polyester is 100 mole %; and wherein the inherent viscosity of the final polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.; and wherein the final polyester has a Tg from 85° C. to 150° C.