公开(公告)号：US4529412A

公开(公告)日：1985-07-16

申请号：US552895

申请日：1983-11-17

申请人： Saburo Hayashi ,  Hiroo Tsuchiya ,  Kazuo Haruna

发明人： Saburo Hayashi ,  Hiroo Tsuchiya ,  Kazuo Haruna

IPC分类号： B01D53/04 ,  C01B13/02 ,  C01B21/04 ,  C01B23/00

CPC分类号： C01B23/00 ,  B01D53/047 ,  B01D2256/18

摘要： A process for obtaining high concentration argon from air by means of pressure-swing-adsorption, characterized by passing air through a zeolite molecular sieve-packed adsorption apparatus and a carbon molecular sieve-packed adsorption apparatus in this order, subjecting the air to pressure-swing-adsorption operation independently in the above pieces of adsorption apparatus, thereby obtaining concentrated argon and high purity oxygen simultaneously.

摘要翻译： 通过变压吸附从空气中获得高浓度氩的方法，其特征在于使空气依次通过沸石分子筛填充吸附装置和碳分子筛填充吸附装置， 在上述吸附装置中独立地进行摆动吸附操作，从而同时获得浓氩和高纯氧。

公开(公告)号：US4661125A

公开(公告)日：1987-04-28

申请号：US734511

申请日：1985-05-16

申请人： Kazuo Haruna ,  Saburo Hayashi

发明人： Kazuo Haruna ,  Saburo Hayashi

IPC分类号： B01D53/04 ,  B01D53/047 ,  C01B13/02 ,  C01B21/04

CPC分类号： B01D53/0476 ,  B01D53/0473 ,  B01D2253/108 ,  B01D2253/116 ,  B01D2253/25 ,  B01D2253/308 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/18 ,  B01D2257/102 ,  B01D2257/104 ,  B01D2259/40001 ,  B01D2259/40037 ,  B01D2259/40064 ,  B01D2259/40066 ,  B01D2259/402 ,  B01D2259/403

摘要： In production of high concentration oxygen by a pressure-swing-adsorption method using air as a raw material, air is introduced into a first step adsorption apparatus packed with a zeolite molecular sieve and is subjected to a pressure-swing-adsorption operation to obtain a non-adsorbed gas comprising oxygen as the major component, argon and nitrogen; the non-adsorbed gas is introduced into a second step adsorption apparatus packed with a carbon molecular sieve and is subjected to a pressure-swing-adsorption operation to separate argon and nitrogen from oxygen as a non-adsorbed gas; and the desorbed oxygen is obtained as high concentration oxygen.

摘要翻译： 在使用空气作为原料的变压吸附法生产高浓度氧气的同时，将空气引入装有沸石分子筛的第一级吸附装置中，进行变压吸附操作，得到 以氧为主要成分的非吸附气体，氩气和氮气; 将未吸附气体引入到装有碳分子筛的第二级吸附装置中，并进行变压吸附操作，从而将作为非吸附气体的氧分离为氩气和氮气; 并且作为高浓度氧获得解吸氧。

公开(公告)号：US4917710A

公开(公告)日：1990-04-17

申请号：US313887

申请日：1989-02-23

申请人： Kazuo Haruna ,  Kanji Ueda ,  Masahiro Inoue ,  Hitosi Someda

发明人： Kazuo Haruna ,  Kanji Ueda ,  Masahiro Inoue ,  Hitosi Someda

IPC分类号： B01D53/04 ,  B01D53/047 ,  C01B13/02

CPC分类号： B01D53/0473 ,  B01D2253/108 ,  B01D2256/12 ,  B01D2257/102 ,  B01D2259/40015 ,  B01D2259/40032 ,  B01D2259/40045 ,  B01D2259/40052 ,  B01D2259/40069 ,  B01D2259/40081 ,  B01D2259/402 ,  B01D53/0476 ,  B01D53/053

摘要： A process for recovering an oxygen enriched gas from a mixed gas mainly composed of nitrogen gas and oxygen gas by means of PSA comprising:providing two adsorbers A and B packed with zeolite molecular sieve as the adsorbent and a gas reservoir for accumulating the recovered oxygen enriched gas which is connected to the outlet side of each adsorber and used in common to both adsorbers, introducing the mixed gas into adsorber A to adsorb nitrogen gas, and desorbing nitrogen has previously adsorbed in adsorber B therefrom under reduced pressure.Introduction, adsorption and desorption are carried out according to adsorption, desorption, rinsing, recovering, pressure accumulation and pressurization steps in turn with alternation of adsorbers A and B.

公开(公告)号：US4684377A

公开(公告)日：1987-08-04

申请号：US870052

申请日：1986-06-03

申请人： Kazuo Haruna ,  Kanji Ueda ,  Masaru Uno

发明人： Kazuo Haruna ,  Kanji Ueda ,  Masaru Uno

IPC分类号： C01B13/02 ,  B01D53/04 ,  B01D53/047 ,  C01B21/04

CPC分类号： B01D53/0476 ,  B01D53/0473 ,  B01D2253/108 ,  B01D2253/308 ,  B01D2256/12 ,  B01D2257/102 ,  B01D2259/4006 ,  B01D2259/403

摘要： An oxygen-enriched gas having an oxygen concentration of, for example, 93% by volume, is produced at a high oxygen recovery rate from a gas mixture containing oxygen and nitrogen as main gas components by pressure swing adsorption, using a set of three adsorption columns, each packed with a zeolite molecular sieve as an adsorbent through a cyclic operation of adsorption under a pressure of from atmospheric pressure to 5,000 mm H.sub.2 O and desorption under vacuum pressure down to the final pressure of 150 mm Hg abs.

公开(公告)号：US4713100A

公开(公告)日：1987-12-15

申请号：US879753

申请日：1986-06-25

申请人： Kazuo Haruna ,  Iwamitsu Shiozawa

发明人： Kazuo Haruna ,  Iwamitsu Shiozawa

IPC分类号： B01D53/04 ,  B01D53/047 ,  B01J8/02

CPC分类号： B01D53/0446 ,  B01D53/0423 ,  B01J8/0257 ,  B01D2253/108 ,  B01D2256/12 ,  B01D2259/40003 ,  B01D2259/4009 ,  B01D2259/401 ,  B01D53/047

摘要： An adsorption apparatus with a good heat recovery and a good noise abatement for separating a gas mixture into its components by pressure swing adsorption comprises a closed vessel having an inlet nozzle for a gas mixture at one end, an adsorbent packed as a bed in the closed vessel and a passage for an unadsorbed gas being vertically provided in the vessel through the adsorbent bed, whose one end is open above the top of the adsorbent bed and whose another end passes through the closed vessel at the inlet nozzle side to the outside.

公开(公告)号：US08715400B2

公开(公告)日：2014-05-06

申请号：US13518257

申请日：2010-12-22

申请人： Kazuo Haruna ,  Kiyokazu Maruta ,  Hidenori Kuwata ,  Koichi Shima

发明人： Kazuo Haruna ,  Kiyokazu Maruta ,  Hidenori Kuwata ,  Koichi Shima

IPC分类号： B01D53/02 ,  F04B41/06 ,  F04B37/14 ,  F04B37/16 ,  B01D53/04 ,  B01D53/047

CPC分类号： F04B41/06 ,  B01D53/0446 ,  B01D53/047 ,  B01D53/0476 ,  B01D2259/402 ,  F04B37/14 ,  F04B37/16 ,  F04B49/007 ,  F04C18/126 ,  F04C23/001 ,  F04C25/02 ,  F04C28/02 ,  F04C28/26 ,  F04C2240/81 ,  F04C2270/18

摘要： A double vacuum pump apparatus (Y2) includes positive displacement vacuum pumps (40A, 40B) and lines (52, 60). Each of the vacuum pumps includes a suction port (41) and a discharge port (42), and a pressure detector (80) is provided in the vicinity of the suction port (41) of the double vacuum pump apparatus (Y2). The line (52) connects the discharge port (42) of the vacuum pump (40A) to the suction port (41) of the vacuum pump (40B). The line (60) has an end (E6) and an end (E5) that are connected to the connection line (52), and includes a buffer tube (Z1) and an on-off valve (61) located between the tube (Z1) and the end (E5). A pressure detection signal from the pressure detector (80) is used as an on/off signal for the on-off valve (61).

摘要翻译： 双真空泵装置（Y2）包括正排量真空泵（40A，40B）和管线（52,60）。 每个真空泵包括吸入口（41）和排出口（42），并且压力检测器（80）设置在双重真空泵装置（Y2）的吸入口（41）附近。 管线（52）将真空泵（40A）的排出口（42）与真空泵（40B）的吸入口（41）连接。 线（60）具有连接到连接线（52）的端部（E6）和端部（E5），并且包括位于管（...）之间的缓冲管（Z1）和开关阀（61） Z1）和末端（E5）。 来自压力检测器（80）的压力检测信号用作开关阀（61）的开/关信号。

公开(公告)号：US20120255445A1

公开(公告)日：2012-10-11

申请号：US13518257

申请日：2010-12-22

申请人： Kazuo Haruna ,  Kiyokazu Maruta ,  Hidenori Kuwata ,  Koichi Shima

发明人： Kazuo Haruna ,  Kiyokazu Maruta ,  Hidenori Kuwata ,  Koichi Shima

IPC分类号： F04C2/20 ,  B01D53/047

CPC分类号： F04B41/06 ,  B01D53/0446 ,  B01D53/047 ,  B01D53/0476 ,  B01D2259/402 ,  F04B37/14 ,  F04B37/16 ,  F04B49/007 ,  F04C18/126 ,  F04C23/001 ,  F04C25/02 ,  F04C28/02 ,  F04C28/26 ,  F04C2240/81 ,  F04C2270/18

摘要： A double vacuum pump apparatus (Y2) includes positive displacement vacuum pumps (40A, 40B) and lines (52, 60). Each of the vacuum pumps includes a suction port (41) and a discharge port (42), and a pressure detector (80) is provided in the vicinity of the suction port (41) of the double vacuum pump apparatus (Y2). The line (52) connects the discharge port (42) of the vacuum pump (40A) to the suction port (41) of the vacuum pump (40B). The line (60) has an end (E6) and an end (E5) that are connected to the connection line (52), and includes a buffer tube (Z1) and an on-off valve (61) located between the tube (Z1) and the end (E5). A pressure detection signal from the pressure detector (80) is used as an on/off signal for the on-off valve (61).

摘要翻译： 双真空泵装置（Y2）包括正排量真空泵（40A，40B）和管线（52,60）。 每个真空泵包括吸入口（41）和排出口（42），并且压力检测器（80）设置在双重真空泵装置（Y2）的吸入口（41）附近。 管线（52）将真空泵（40A）的排出口（42）与真空泵（40B）的吸入口（41）连接。 线（60）具有连接到连接线（52）的端部（E6）和端部（E5），并且包括位于管（...）之间的缓冲管（Z1）和开关阀（61） Z1）和末端（E5）。 来自压力检测器（80）的压力检测信号用作开关阀（61）的开/关信号。

公开(公告)号：US5755856A

公开(公告)日：1998-05-26

申请号：US737144

申请日：1996-10-30

申请人： Masanori Miyake ,  Kazuo Haruna ,  Hiroaki Sasano

发明人： Masanori Miyake ,  Kazuo Haruna ,  Hiroaki Sasano

IPC分类号： B01D53/04 ,  B01D53/047 ,  C01B13/02

CPC分类号： B01D53/047 ,  C01B13/0259 ,  B01D2256/12 ,  B01D2257/102 ,  B01D2259/40069 ,  B01D2259/402 ,  B01D53/0446 ,  C01B2210/0046

摘要： In a process of recovering oxygen-enriched gas by pressure swing adsorption with use of adsorbers (A, B) each packed with an adsorbent which selectively adsorbs nitrogen from a gas mixture mainly containing nitrogen and oxygen, recovery of remaining oxygen-enrich gas is fully carried out by pressure equalization between both adsorbers (A, B), and a vacuum pump (8) is always connected to either adsorber (A or B) for continuous evacuation of nitrogen. For this purpose, the pressure equalization between both adsorbers (A, B) is conducted at least in two steps wherein one adsorber (A or B) is pressurized, whereas the other adsorber (B or A) is pressurized, so that recovery of oxygen-enriched gas is possible until there is substantially no pressure difference between both adsorbers (A, B).

摘要翻译： PCT No.PCT / JP95 / 00452 Sec。 371日期1996年10月30日 102（e）日期1996年10月30日PCT PCT 1996年2月26日PCT公布。 WO96 / 26894 PCT出版物 日期1996年9月6日在使用吸附剂（A，B）通过变压吸附回收富氧气体的过程中，每个吸附器填充有主要含有氮和氧的气体混合物选择性吸附氮气的吸附剂，回收剩余的氧气 通过两个吸附器（A，B）之间的压力均衡完全实现了富气体，真空泵（8）总是连接到吸附器（A或B）上以连续抽出氮气。 为此，两个吸附器（A，B）之间的压力平衡至少在两个步骤中进行，其中一个吸附器（A或B）被加压，而另一个吸附器（B或A）被加压，使得氧气回收 在两个吸附器（A，B）之间基本上没有压力差是可能的。

公开(公告)号：US4955998A

公开(公告)日：1990-09-11

申请号：US424933

申请日：1989-10-20

申请人： Kanji Ueda ,  Kazuo Haruna ,  Masahiro Inoue

发明人： Kanji Ueda ,  Kazuo Haruna ,  Masahiro Inoue

IPC分类号： B01D53/22 ,  C01B13/02

CPC分类号： B01D53/22

摘要： A process for separating a specific component from air which comprises alternately and repeatedly carrying out a step of feeding air under pressure to a non-porous gas separation membrane and suctioning of a permeating gas under vacuum after feeding of air is stopped.

公开(公告)号：US20100294130A1

公开(公告)日：2010-11-25

申请号：US12446085

申请日：2007-10-17

申请人： Kazuo Haruna ,  Masanori Miyake ,  Hiroaki Sasano ,  Mayumi Fukushima

发明人： Kazuo Haruna ,  Masanori Miyake ,  Hiroaki Sasano ,  Mayumi Fukushima

IPC分类号： B01D53/047

CPC分类号： C01B3/56 ,  B01D53/047 ,  B01D2253/102 ,  B01D2253/108 ,  B01D2256/16 ,  B01D2259/403 ,  B01D2259/4146 ,  B01J20/18 ,  B01J20/20 ,  B01J20/28052 ,  C01B2203/043 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/048

摘要： A hydrogen gas separation method utilizing PSA process employs a plurality of adsorption towers A, B, C loaded with an adsorbent for separating the hydrogen gas from a hydrogen-containing gas mixture, and a cycle including introducing the gas mixture into the adsorption tower, adsorbing unnecessary gas in the gas mixture by the adsorbent, leading out product gas having high hydrogen concentration from the adsorption tower, desorbing the unnecessary gas from the adsorbent, and leading out desorbed gas containing the unnecessary gas and residual gas in the adsorption tower from the adsorption tower, is repeated. The adsorbent includes an activated carbon-based first adsorbent D located on the upstream side of the flow direction of the gas mixture in the adsorption tower with an filling ratio of 60 to 80%, and a zeolite-based second adsorbent E located on the downstream side of the flow direction with filling ratio of 40 to 20%.

摘要翻译： 使用PSA方法的氢气分离方法使用多个吸附塔A，B，C，其加载有用于从含氢气体混合物中分离氢气的吸附剂，以及包括将气体混合物引入吸附塔的循环，吸附 通过吸附剂在气体混合物中不必要的气体，从吸附塔引出具有高氢浓度的产物气体，从吸附剂中解吸不需要的气体，并从吸附物中引出含有不需要的气体和残留气体的脱附气体 塔，重复。 吸附剂包括位于吸附塔中的气体混合物的流动方向的上游侧，以填充率为60至80％的活性炭基第一吸附剂D和位于下游的沸石基第二吸附剂E 流动方向一侧的填充比为40〜20％。