摘要:
A positive active material, a method of preparing the same, and a lithium battery including the positive active material, the positive active material including a core, the core including an overlithiated lithium transition metal oxide; and a coating layer on the core, the coating layer including Li3VO4.
摘要:
A composite cathode active material includes: a first metal oxide including a plurality of layered crystalline phases comprising a first layered crystalline phase and a second layered crystalline phase, wherein the first and second layered crystalline phases have a different compositions than each other, and a second metal oxide different from the first metal oxide and including a composite crystalline phase, that is different from the first metal oxide, wherein the second metal oxide is represented by Formula 1, wherein at least a portion of the second metal oxide is disposed on a first layered crystalline phase of the plurality of layered crystalline phases of the first metal oxide, and wherein the first layer crystalline phase is in a space group of R-3m: LixMyOz Formula 1 wherein, in Formula 1, 0≤x≤3, 1≤y≤3, and 2≤z≤8, and M is at least one selected from a Group 4 element to a Group 13 element.
摘要:
Provided are a method of manufacturing a composite positive active material, a composite positive active material manufactured by the method, and a positive electrode and a lithium battery including the composite positive active material. The method may include acid-treating an overlithiated lithium transition metal oxide; and applying fluorine onto the acid-treated overlithiated lithium transition metal oxide using a fluorine compound.
摘要:
A positive active material including: a core including an overlithiated lithium transition metal oxide, and a coating layer which is disposed on at least a portion of a surface of the core, the coating layer including a polymer having an oxidation potential of about 4.4 volts to about 4.7 volts versus lithium metal. Also a manufacturing method thereof, and a positive electrode and a lithium battery including the positive active material.
摘要:
A positive active material includes an overlithiated lithium transition metal oxide including: a metal cation and a Li2MO3 phase, wherein M is at least one metal selected from a Period 4 transition metal having an average oxidation number of +4 and a Period 5 transition metal having an average oxidation number of +4, and wherein an amount of the Li2MO3 phase is less than or equal to about 20 mole percent, based on 1 mole of the overlithiated lithium transition metal oxide.
摘要:
In an aspect, a positive active material for a rechargeable lithium battery including overlithiated layered oxide (OLO), a method of preparing the same, and a positive electrode for a rechargeable lithium battery and a rechargeable lithium battery including the same is disclosed.
摘要:
A cathode active material includes a secondary particle including an aggregate of a plurality of primary particles, wherein the secondary particle includes a nickel-containing lithium transition metal oxide having a layered crystal structure, wherein the plurality of primary particles includes a first primary particle having a size greater than about 400 nanometers, a second primary particle having a size less than about 150 nanometers, and a third primary particle having a size of about 150 nanometers to about 400 nanometers, wherein the third primary particle has a area of greater than or equal to about 80% of a total area of the plurality of primary particles, and wherein the secondary particle has a porosity of less than or equal to about 10% of a total area of the cathode active material.
摘要:
A positive active material includes an over-lithiated lithium transition metal oxide having a core-shell structure, wherein a shell layer of the core-shell structure includes a metal cation.
摘要:
A composite positive active material includes: a composite including a first metal oxide represented by Formula 1 and having a layered structure, and a second metal oxide having at least one crystal structure selected from a layer structure, a perovskite structure, a rock salt structure, and a spinel structure, wherein a content of the second metal oxide is greater than 0 and equal to or less than 0.2 moles, per mole of the composite, LiNixM11-xO2-eM2e Formula 1 wherein, in Formula 1, M1 is at least one element selected from Group 4 to Group 14 of the Periodic Table of the Elements; Ma is at least one element selected from F, S, Cl, and Br; 0.7≤x
摘要:
A composite positive electrode active material including: an overlithiated layered oxide (OLO) including vanadium (V) and magnesium (Mg), wherein the vanadium and magnesium have a molar ratio of about 1:2. Also a method of manufacturing the composite positive electrode active material, a positive electrode including the composite positive electrode, and a lithium battery including the positive electrode.