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公开(公告)号：US20100047657A1
公开(公告)日：2010-02-25
申请号：US12197874
申请日：2008-08-25
IPC分类号： H01M8/10
CPC分类号： H01M8/0289 , C08J5/2275 , C08J2381/06 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1034 , H01M8/1039 , H01M8/1044 , H01M8/1053
摘要： An ion conducting polymeric structure suitable for fuel cell applications is provided. The polymeric structure comprises a non-homogenous polymeric layer. The non-homogeneous layer is a blend of a first polymer comprising cyclobutyl moiety; and a second polymer having a non-ionic polymer segment. The weight ratio of the first polymer to the second polymer varies as a function of position within the non-homogenous layer. The blend composition may be cast into an electrolyte membrane that can be used to prepare electrochemical cells such as batteries and fuel cells.
摘要翻译： 提供适用于燃料电池应用的离子导电聚合物结构。 聚合物结构包含非均匀的聚合物层。 非均匀层是包含环丁基部分的第一聚合物的共混物; 和具有非离子聚合物链段的第二聚合物。 第一聚合物与第二聚合物的重量比作为非均匀层内的位置的函数而变化。 共混组合物可以浇注到可用于制备电化学电池如电池和燃料电池的电解质膜中。
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2.发明申请POLYELECTROLYTE MEMBRANES COMPRISED OF BLENDS OF PFSA AND SULFONATED PFCB POLYMERS 有权包含PFSA和磺化PFCB聚合物的聚合物的聚电解质膜公开(公告)号：US20090278083A1
公开(公告)日：2009-11-12
申请号：US12434749
申请日：2009-05-04
IPC分类号： H01M4/86
CPC分类号： C08J5/2275 , C08J5/2281 , C08J2327/12 , C08J2345/00
摘要： A polymer blend useful as an ion conductor in fuel cells includes a first polymer having a cyclobutyl moiety and a second polymer include a sulfonic acid group.
摘要翻译： 用作燃料电池中的离子导体的聚合物共混物包括具有环丁基部分的第一聚合物和第二聚合物包括磺酸基团。
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公开(公告)号：US08999595B2
公开(公告)日：2015-04-07
申请号：US12956262
申请日：2010-11-30
CPC分类号： H01M8/1051 , H01M4/9041 , H01M8/0271 , H01M8/0289 , H01M8/0637 , H01M8/1004 , H01M2008/1095 , Y02E60/521 , Y02E60/566
摘要： A fuel cell or a fuel cell stack component comprises an active area and a non-active area. A peroxide decomposing metal compound or metal alloy is disposed in or on the non-active area of a fuel cell or a fuel cell component. The metal compound or alloy is capable of providing a peroxide decomposing metal species that can migrate from the non-active area to an active area of a fuel cell. A fuel cell or membrane electrode assembly having a peroxide decomposing metal compound or alloy disposed in its non-active area exhibits improved durability.
摘要翻译： 燃料电池或燃料电池堆组件包括有源区和非有源区。 过氧化物分解金属化合物或金属合金设置在燃料电池或燃料电池部件的非有源区域中或其上。 金属化合物或合金能够提供可以从非活性区迁移到燃料电池的有效区域的过氧化物分解金属物质。 具有设置在其非活性区域中的过氧化物分解金属化合物或合金的燃料电池或膜电极组件表现出改进的耐久性。
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公开(公告)号：US09083049B2
公开(公告)日：2015-07-14
申请号：US11549814
申请日：2006-10-16
申请人： Timothy J. Fuller , Michael R. Schoeneweiss , Tao Xie , Frank Coms , Sean M. MacKinnon , Gerald W. Fly
发明人： Timothy J. Fuller , Michael R. Schoeneweiss , Tao Xie , Frank Coms , Sean M. MacKinnon , Gerald W. Fly
CPC分类号： H01M4/8657 , H01M4/8652 , H01M8/1023 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/1051 , H01M8/1053 , H01M8/1067 , H01M8/1069 , H01M2300/0091 , H01M2300/0094 , Y02E60/522 , Y02P70/56
摘要： A fuel cell comprising: a first layer comprising a first ionomer and an additive, the additive comprising a metal oxide comprising an oxide at least one of of Ce, Mn, V, Pt, Ru, Zr, Ni, Cr, W, Co, Mo, or Sn, and wherein the additive is present in at least 0.1 weight percent of the ionomer is disclosed as one embodiment of the invention, and performance and durability are advantaged wherein one or all of the metal oxide consists essentially nanoparticles.
摘要翻译： 一种燃料电池，包括：包含第一离聚物和添加剂的第一层，所述添加剂包括含有Ce，Mn，V，Pt，Ru，Zr，Ni，Cr，W，Co， Mo或Sn，并且其中添加剂存在于至少0.1重量％的离聚物中作为本发明的一个实施方案公开，并且性能和耐久性有利于其中一种或全部金属氧化物基本上由纳米颗粒组成。
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5.发明申请Hydrophilic Polyelectrolyte Membranes Containing Poly(Vinyl Acetate) and Poly(Vinyl Alcohol) 审中-公开含聚（乙酸乙烯酯）和聚（乙烯醇）的亲水性聚电解质膜公开(公告)号：US20110159405A1
公开(公告)日：2011-06-30
申请号：US12650019
申请日：2009-12-30
IPC分类号： H01M8/10
CPC分类号： H01M8/1025 , H01M8/1023 , H01M8/1032 , H01M8/1034 , H01M8/1039 , H01M8/1044 , H01M2300/0082
摘要： An ion conducting membrane for fuel cell applications includes a combination of a polyvinyl polymer and an ion conducting polymer that is different than the polyvinyl polymer. The ion conducting membrane of this embodiment is able to operate in fuel cells at elevated temperatures with minimal external humidification. A fuel cell incorporating the ion conducting membrane between a first and second catalyst layer is also provided.
摘要翻译： 用于燃料电池应用的离子导电膜包括与聚乙烯基聚合物不同的聚乙烯基聚合物和离子导电聚合物的组合。 该实施例的离子导电膜能够在最小的外部加湿下在高温下在燃料电池中操作。 还提供了在第一和第二催化剂层之间并入离子传导膜的燃料电池。
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6.发明申请ION EXCHANGE MEMBRANE HAVING LAMELLAR MORPHOLOGY AND PROCESS OF MAKING THE SAME 有权具有LAMELLAR MORPHOLOGY的离子交换膜及其制备方法公开(公告)号：US20110054050A1
公开(公告)日：2011-03-03
申请号：US12551272
申请日：2009-08-31
CPC分类号： H01M8/1039 , C08J5/2237 , C08J2327/18 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1081 , H01M2300/0082 , Y02P70/56
摘要： An ion exchange membrane is prepared from a block copolymer comprising a hydrophobic polymer segment and a polar polymer segment. The ion exchange membrane is formed by placing a film layer in steam, water or an electric field at a temperature greater than about 40° C. for sufficient amount of time to develop a bicontinuous morphology. The ion exchange membrane is also formed from a film layer comprising a block copolymer and a solvent. The film layer is placed in an electric field at an elevated temperature and dried therein. The film layer is thereby converted into an ion exchange membrane with bicontinuous morphology. The ion exchange membrane prepared according to these processes exhibits improved mechanical and electrochemical properties.
摘要翻译： 离子交换膜由包含疏水性聚合物链段和极性聚合物链段的嵌段共聚物制备。 通过在大于约40℃的温度下将膜层置于蒸汽，水或电场中形成足够的时间以形成双连续形态来形成离子交换膜。 离子交换膜也由包含嵌段共聚物和溶剂的膜层形成。 将膜层放置在高温下的电场中并干燥。 由此将膜层转化为具有双连续形态的离子交换膜。 根据这些方法制备的离子交换膜表现出改进的机械和电化学性能。
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7.发明申请SULFONATED-POLYPERFLUORO-CYCLOBUTANE-POLYPHENLENE POLYMERS FOR PEM FUEL CELL APPLICATIONS 有权用于PEM燃料电池应用的磺化多氟聚醚 - 环戊二烯聚苯乙烯聚合物公开(公告)号：US20090281270A1
公开(公告)日：2009-11-12
申请号：US12197545
申请日：2008-08-25
CPC分类号： C08G61/12 , H01M4/96 , H01M8/16 , Y02E60/527
摘要： A polymer for ion conductor applications includes a polymer segment having a perfluorocyclobutyl moiety and a polymer segment not having such a moiety. One of these polymer segments is sulfonated to improve ionic conductivity. Fuel cells incorporating the ion conducting polymers are provided.
摘要翻译： 用于离子导体应用的聚合物包括具有全氟环丁基部分的聚合物链段和不具有这种部分的聚合物链段。 这些聚合物链段之一被磺化以改善离子电导率。 提供并入离子导电聚合物的燃料电池。
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8.发明申请Hydrocarbon PEM Membranes with Perfluorosulfonic Acid Groups for Automotive Fuel Cells 审中-公开用于汽车燃料电池的具有全氟磺酸基团的烃PEM膜公开(公告)号：US20110045381A1
公开(公告)日：2011-02-24
申请号：US12542900
申请日：2009-08-18
IPC分类号： H01M8/10
CPC分类号： H01M8/1023 , H01M8/1072 , H01M2300/0082 , Y02P70/56
摘要： A solid electrochemical cell membrane composition comprises a hydrocarbon polymeric main chain and a perfluorinated superacid side group. A method of producing the membrane composition is also disclosed.
摘要翻译： 固体电化学电池组合物包含烃聚合主链和全氟化超酸侧基。 还公开了一种制备膜组合物的方法。
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公开(公告)号：US20090281245A1
公开(公告)日：2009-11-12
申请号：US12197530
申请日：2008-08-25
IPC分类号： C08F114/18
CPC分类号： C08F214/18 , C08J5/2268 , C08J2381/06 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1034 , H01M8/1039 , H01M2300/0082
摘要： A proton conductive graft polymer comprises at least a structure unit of a sulfonated polymer side chain covalently attached to a hydrophobic perfluorocyclobutane polymer main chain. The sulfonated condensation polymer side chain has a high local ion exchange capacity while the main polymer chain is substantially free of sulfonic acid group. A membrane made from the graft polymer can provide good mechanical properties and high proton conductivity at wide range of humidity and temperatures.
摘要翻译： 质子传导性接枝聚合物至少包含共价连接到疏水性全氟环丁烷聚合物主链上的磺化聚合物侧链的结构单元。 磺化缩聚物侧链具有高的局部离子交换能力，而主要聚合物链基本上不含磺酸基团。 由接枝聚合物制成的膜可以在宽的湿度和温度范围内提供良好的机械性能和高质子传导性。
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公开(公告)号：US20080166620A1
公开(公告)日：2008-07-10
申请号：US11549814
申请日：2006-10-16
申请人： Timothy J. Fuller , Michael R. Schoeneweiss , Tao Xie , Frank Coms , Sean M. MacKinnon , Gerald W. Fly
发明人： Timothy J. Fuller , Michael R. Schoeneweiss , Tao Xie , Frank Coms , Sean M. MacKinnon , Gerald W. Fly
IPC分类号： H01M2/02
CPC分类号： H01M4/8657 , H01M4/8652 , H01M8/1023 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/1051 , H01M8/1053 , H01M8/1067 , H01M8/1069 , H01M2300/0091 , H01M2300/0094 , Y02E60/522 , Y02P70/56
摘要： A fuel cell comprising: a first layer comprising a first ionomer and an additive, the additive comprising a metal oxide comprising an oxide at least one of of Ce, Mn, V, Pt, Ru, Zr, Ni, Cr, W, Co, Mo, or Sn, and wherein the additive is present in at least 0.1 weight percent of the ionomer is disclosed as one embodiment of the invention, and performance and durability are advantaged wherein one or all of the metal oxide consists essentially nanoparticles.
摘要翻译： 一种燃料电池，包括：包含第一离聚物和添加剂的第一层，所述添加剂包括含有Ce，Mn，V，Pt，Ru，Zr，Ni，Cr，W，Co， Mo或Sn，并且其中添加剂存在于至少0.1重量％的离聚物中作为本发明的一个实施方案公开，并且性能和耐久性有利于其中一种或全部金属氧化物基本上由纳米颗粒组成。
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