公开(公告)号：US12113255B2

公开(公告)日：2024-10-08

申请号：US17495041

申请日：2021-10-06

Applicant: Hyundai Motor Company ,  Kia Corporation

Inventor： Il Seok Chae

IPC: H01M8/1044 ,  C08F212/14 ,  C08F220/36 ,  C08F220/38 ,  C25B1/04 ,  C25B9/19 ,  C25B13/08 ,  H01M8/1004 ,  H01M8/103 ,  H01M8/1034 ,  H01M8/1051

CPC classification number: H01M8/1004 ,  C08F212/26 ,  C08F212/30 ,  C08F220/36 ,  C08F220/382 ,  C25B1/04 ,  C25B9/19 ,  C25B13/08 ,  H01M8/103 ,  H01M8/1034 ,  H01M8/1051

Abstract: Disclosed is an electrolyte membrane for a membrane-electrode assembly including a block copolymer composed of a hydrophilic domain and a hydrophobic domain.

公开(公告)号：US20180131027A1

公开(公告)日：2018-05-10

申请号：US15575851

申请日：2016-05-26

Applicant: Charles Austen Angell ,  Younes Ansari ,  Telpriore Greg Tucker ,  Iolanda Santana Klein

Inventor： Charles Austen Angell ,  Younes Ansari ,  Telpriore Greg Tucker ,  Iolanda Santana Klein

IPC: H01M8/1034 ,  H01M8/1051 ,  H01M8/1072

CPC classification number: H01M8/1034 ,  H01M8/1016 ,  H01M8/1051 ,  H01M8/1072 ,  H01M2300/0008 ,  H01M2300/0068 ,  H01M2300/0085 ,  H01M2300/0091 ,  H01M2300/0094

Abstract: A solid electrolyte includes an amorphous silica network and phosphoric acid. The phosphoric acid is contained in the amorphous silica network, and is typically in molecular form. The ratio of silicon to phosphorus in the solid electrolyte is about 1:4, and the silicon is in a four-coordinated state. The solid electrolyte is in the form of a dried (e.g., anhydrous) gel. The solid electrolyte may be used in a fuel cell membrane. Preparing the solid electrolyte includes reacting phosphoric acid in the liquid state with tetrachloride compound including silicon and a displaceable ligand to yield a fluid suspension, heating the fluid suspension to yield a liquid electrolyte comprising a particulate solid, separating the particulate solid from the liquid electrolyte, combining the particulate solid with water to yield a homogenous solution, forming a gel from the homogeneous solution, and removing water from the gel to yield the solid electrolyte.

公开(公告)号：US09951170B2

公开(公告)日：2018-04-24

申请号：US15033829

申请日：2015-03-20

Applicant: Hulin Xu

Inventor： Hulin Xu ,  Changjin Zhu

IPC: C08F283/00 ,  C08J5/22 ,  C08F212/14 ,  C08F8/12 ,  C08F8/36 ,  H01M2/16 ,  H01M8/02 ,  H01M8/103 ,  H01M8/1034 ,  C08G79/025 ,  B01J39/19 ,  H01M8/1018

CPC classification number: C08F283/00 ,  B01J39/19 ,  C08F8/12 ,  C08F8/36 ,  C08F212/14 ,  C08F2438/01 ,  C08F2500/26 ,  C08F2810/20 ,  C08G79/025 ,  C08J5/22 ,  C08J5/2268 ,  C08J5/2287 ,  C08J2325/08 ,  C08J2351/08 ,  C08J2385/02 ,  H01M2/16 ,  H01M8/02 ,  H01M8/103 ,  H01M8/1034 ,  H01M2008/1095 ,  C08F212/08

Abstract: A sulfonated polyphosphazene copolymer proton exchange membrane material, and a method for preparing such membrane includes a macromolecule initiator as bromo polyphosphazene is subjected to atom transfer radical polymerization with styrene, yielding a graft copolymer, which is hydrazinolyzed with hydrazine hydrate resulting in a copolymer including a hydroxyl group. The copolymer is reacted with 1,4-butane sultone to yield a sulfonated copolymer finally. The polymer is cross-linked with 2,6-di(hydroxymethyl)-4-methyl phenol (BHMP) as a cross linking agent in the presence of methyl sulfonic acid, yielding cross-linked proton exchange membrane. Such cross-linked graft copolymer membrane has high proton conductivity, low methanol hindrance, and low cost, and has ideal effect when applied in fuel cells as proton exchange membrane material.

公开(公告)号：US09893374B2

公开(公告)日：2018-02-13

申请号：US14678688

申请日：2015-04-03

Applicant: LG CHEM, LTD.

Inventor： Eun Ju Kim ,  Chong Kyu Shin ,  Bong Keun Lee ,  Seong Ho Choi

IPC: H01M8/1053 ,  H01M8/1058 ,  H01M8/1007 ,  H01M8/1067 ,  H01M8/1039 ,  H01M8/103 ,  H01M8/1062 ,  H01M8/1034 ,  H01M8/1025 ,  H01M8/04082 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1023 ,  H01M8/106 ,  H01M8/1081

CPC classification number: H01M8/1053 ,  H01M8/04197 ,  H01M8/1007 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1039 ,  H01M8/1058 ,  H01M8/106 ,  H01M8/1062 ,  H01M8/1067 ,  H01M8/1081 ,  H01M2300/0082 ,  H01M2300/0088 ,  H01M2300/0094 ,  Y02E60/521 ,  Y02P70/56

Abstract: Disclosed is a composite electrolyte membrane comprising a microporous polymer substrate and a sulfonated polymer electrolyte. The composite electrolyte membrane comprises: a first polymer electrolyte layer formed of a first non-fluorinated or partially-fluorinated sulfonated polymer electrolyte; a non-fluorinated or partially-fluorinated microporous polymer substrate stacked on the first polymer electrolyte layer, wherein pores of the microporous polymer substrate are impregnated with a second non-fluorinated or partially-fluorinated sulfonated polymer electrolyte, and the first polymer electrolyte and the second polymer electrolyte are entangled with each other on an interface thereof; and a third polymer electrolyte layer formed on the microporous polymer substrate impregnated with the second polymer electrolyte by a third non-fluorinated or partially-fluorinated sulfonated polymer electrolyte, wherein the second polymer electrolyte and the third polymer electrolyte are entangled with each other on an interface thereof. A method for manufacturing the composite electrolyte membrane, and a membrane-electrode assembly (MEA) and a fuel cell comprising the composite electrolyte membrane are also disclosed.

公开(公告)号：US20170267823A1

公开(公告)日：2017-09-21

申请号：US15505606

申请日：2015-08-22

Applicant: TAKAHATA PRECISION JAPAN CO., LTD. ,  UNIVERSITY OF YAMANASHI

Inventor： Manai SHIMADA ,  Naoki YOKOTA ,  Kenji MIYATAKE ,  Masahiro WATANABE ,  Junpei MIYAKE ,  Hideaki ONO ,  Eriko NISHINO ,  Koichiro ASAZAWA

IPC: C08J5/22 ,  C08G75/02 ,  H01M8/1067 ,  H01B1/12 ,  H01M4/90 ,  H01M4/86 ,  C08G61/10 ,  C08G65/40

CPC classification number: C08J5/2281 ,  C08G61/10 ,  C08G61/12 ,  C08G65/40 ,  C08G75/02 ,  C08G2261/143 ,  C08G2261/146 ,  C08G2261/312 ,  C08G2261/3424 ,  C08G2261/344 ,  C08G2261/412 ,  C08G2261/516 ,  C08G2261/598 ,  C08G2261/62 ,  C08J5/2262 ,  C08J2365/00 ,  C08J2365/02 ,  H01B1/122 ,  H01M4/8668 ,  H01M4/9008 ,  H01M8/06 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1037 ,  H01M8/1067 ,  H01M2004/026 ,  Y02P70/56

Abstract: The present invention provides an anion exchange resin capable of producing an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a battery electrode catalyst layer. The anion exchange resin of the present invention has a hydrophobic unit, a hydrophilic unit and divalent fluorine-containing groups. The hydrophobic unit has divalent hydrophobic groups composed of one aromatic ring or a plurality of aromatic rings that are repeated via carbon-carbon bond. The hydrophilic unit has divalent hydrophilic groups composed of one aromatic ring or a plurality of aromatic rings, at least one of which has an anion exchange group, that are repeated via carbon-carbon bond. The divalent fluorine-containing groups have a specific structure and are bonded via carbon-carbon bond to the hydrophobic unit and/or the hydrophilic unit and/or a moiety other than these units.

公开(公告)号：US20170095809A1

公开(公告)日：2017-04-06

申请号：US15237537

申请日：2016-08-15

Applicant: Thomas Häring

Inventor： Thomas Häring

IPC: B01J39/19 ,  H01M8/1027 ,  H01M8/1032 ,  C08G75/23 ,  C08G65/48

CPC classification number: B01J39/19 ,  B01D67/0093 ,  B01D71/52 ,  B01D71/68 ,  B01D71/80 ,  B01D71/82 ,  B01D2323/30 ,  B01J41/12 ,  B01J47/12 ,  C08G65/48 ,  C08G75/23 ,  C08G2650/02 ,  C08G2650/20 ,  C08J5/2256 ,  C08J5/2275 ,  C08J2371/00 ,  C08J2381/06 ,  C08L71/00 ,  C08L81/06 ,  C08L2312/00 ,  H01M8/0289 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1039 ,  H01M2008/1095 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02E60/523

Abstract: A non crosslinked, covalently crosslinked and/or ionically crosslinked polymer, having repeating units of the general formula (1) —K—R—  (1) In which K is a bond, oxygen, sulfur, the radical R is a divalent radical of an aromatic or heteroaromatic compound.

公开(公告)号：US09240607B2

公开(公告)日：2016-01-19

申请号：US13876101

申请日：2012-04-02

Applicant: Dong Hoon Lee ,  Na Young Kim ,  Moo Seok Lee ,  Yong Cheol Shin

Inventor： Dong Hoon Lee ,  Na Young Kim ,  Moo Seok Lee ,  Yong Cheol Shin

IPC: H01M8/10 ,  C08J5/22 ,  C08F283/00 ,  C08G65/48 ,  C08L71/00 ,  H01B1/12

CPC classification number: H01M8/1027 ,  C08F283/00 ,  C08G65/48 ,  C08G2261/3442 ,  C08G2650/40 ,  C08J5/2206 ,  C08J5/2275 ,  C08J2371/12 ,  C08L71/00 ,  H01B1/122 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1039 ,  H01M8/1062 ,  H01M8/1072 ,  H01M2300/0082 ,  Y02E60/521 ,  Y02P70/56 ,  C08F226/10

Abstract: Provided are a polymer electrolyte membrane used in fuel cells, and a method for producing the same, the method including a step of filling a crosslinkable ion conductor in the pores of a porous nanoweb support; and a step of crosslinking the ion conductor filled in the pores of the porous nanoweb support. The method for producing a polymer electrolyte membrane uses a relatively smaller amount of an organic solvent, can ameliorate defects of the support caused by solvent evaporation, and can enhance the impregnability of the ion conductor to the support and the convenience of the process.

Abstract translation: 提供了一种用于燃料电池的聚合物电解质膜及其制造方法，该方法包括在多孔纳米网络载体的孔中填充可交联离子导体的步骤; 以及将填充在多孔纳米网络载体的孔中的离子导体交联的步骤。 聚合物电解质膜的制造方法使用相对较少量的有机溶剂，可以改善由溶剂蒸发引起的载体缺陷，并且可以提高离子导体对载体的浸渍性和方法的便利性。

公开(公告)号：US20150214563A1

公开(公告)日：2015-07-30

申请号：US14678688

申请日：2015-04-03

Applicant: LG CHEM, LTD.

Inventor： Eun Ju KIM ,  Chong Kyu SHIN ,  Bong Keun LEE ,  Seong Ho CHOI

IPC: H01M8/10

CPC classification number: H01M8/1053 ,  H01M8/04197 ,  H01M8/1007 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1039 ,  H01M8/1058 ,  H01M8/106 ,  H01M8/1062 ,  H01M8/1067 ,  H01M8/1081 ,  H01M2300/0082 ,  H01M2300/0088 ,  H01M2300/0094 ,  Y02E60/521 ,  Y02P70/56

Abstract: Disclosed is a composite electrolyte membrane comprising a microporous polymer substrate and a sulfonated polymer electrolyte. The composite electrolyte membrane comprises: a first polymer electrolyte layer formed of a first non-fluorinated or partially-fluorinated sulfonated polymer electrolyte; a non-fluorinated or partially-fluorinated microporous polymer substrate stacked on the first polymer electrolyte layer, wherein pores of the microporous polymer substrate are impregnated with a second non-fluorinated or partially-fluorinated sulfonated polymer electrolyte, and the first polymer electrolyte and the second polymer electrolyte are entangled with each other on an interface thereof; and a third polymer electrolyte layer formed on the microporous polymer substrate impregnated with the second polymer electrolyte by a third non-fluorinated or partially-fluorinated sulfonated polymer electrolyte, wherein the second polymer electrolyte and the third polymer electrolyte are entangled with each other on an interface thereof. A method for manufacturing the composite electrolyte membrane, and a membrane-electrode assembly (MEA) and a fuel cell comprising the composite electrolyte membrane are also disclosed.

Abstract translation: 公开了包含微孔聚合物基材和磺化聚合物电解质的复合电解质膜。 复合电解质膜包括：由第一非氟化或部分氟化的磺化聚合物电解质形成的第一聚合物电解质层; 堆叠在第一聚合物电解质层上的非氟化或部分氟化的微孔聚合物基材，其中微孔聚合物基材的孔用第二非氟化或部分氟化的磺化聚合物电解质浸渍，并且第一聚合物电解质和第二聚合物电解质 聚合物电解质在其界面上彼此缠结; 以及第三聚合物电解质层，其通过第三非氟化或部分氟化的磺化聚合物电解质在所述第二聚合物电解质浸渍的所述微孔聚合物基材上形成，其中所述第二聚合物电解质和所述第三聚合物电解质在界面上彼此缠结 其中。 还公开了复合电解质膜的制造方法以及膜电极组件（MEA）和包含该复合电解质膜的燃料电池。

公开(公告)号：US20150094446A1

公开(公告)日：2015-04-02

申请号：US14346288

申请日：2012-09-06

Applicant: Qiao Chen ,  Fangke Shao ,  Gang Wu ,  Daisuke Izuhara ,  Hiroaki Umeda

Inventor： Qiao Chen ,  Fangke Shao ,  Gang Wu ,  Daisuke Izuhara ,  Hiroaki Umeda

IPC: C08G65/00 ,  C07C317/14 ,  H01M8/10 ,  C07C309/00

CPC classification number: C08G65/00 ,  C07C309/00 ,  C07C309/44 ,  C07C317/14 ,  C08G65/4043 ,  C08G65/4056 ,  H01B1/122 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1032 ,  H01M8/1034 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02P70/56

Abstract: It is an object of the present invention to provide a sulfonic acid group-containing polymer and a sulfonic acid group-containing aromatic compound, which have excellent proton conductivity even under the low humidification condition, are excellent in mechanical strength and chemical stability and, moreover, can attain high output and excellent physical durability when processed into a solid polymer fuel cell, as well as a polymer electrolyte material, a polymer electrolyte molded product and a solid polymer fuel cell respectively using the same. The sulfonic acid group-containing polymer of the present invention is a sulfonic acid group-containing polymer comprising a constituent unit containing a sulfonic acid group (A1), and a constituent unit not containing a sulfonic acid group (A2), wherein the polymer contains a constituent unit having a specified structure as at least one constituent unit containing a sulfonic acid group (A1) at 25 mol % or more based on a sum of the constituent unit containing a sulfonic acid group (A1). Further, the polymer electrolyte material, polymer electrolyte molded product and solid polymer fuel cell of the present invention are constituted using such a sulfonic acid group-containing polymer.

Abstract translation: 本发明的目的是提供即使在低加湿条件下也具有优异的质子传导性的含磺酸基的聚合物和含磺酸基的芳族化合物，其机械强度和化学稳定性优异，而且 当加工成固体聚合物燃料电池时，可以获得高产量和优异的物理耐久性，以及分别使用它们的聚合物电解质材料，聚合物电解质模制产品和固体聚合物燃料电池。 本发明的含磺酸基的聚合物是含有含有磺酸基（A1）的构成单元和不含磺酸基（A2）的构成单元的含磺酸基的聚合物，其中，聚合物含有 基于含有磺酸基（A1）的构成单元的总和，具有指定结构的构成单元作为至少一种含有25mol％以上的磺酸基（A1）的构成单元。 此外，本发明的高分子电解质材料，高分子电解质成型体和固体高分子型燃料电池使用这样的含有磺酸基的聚合物构成。

公开(公告)号：US20140308600A1

公开(公告)日：2014-10-16

申请号：US14253339

申请日：2014-04-15

Applicant: Advent Technologies Inc.

Inventor： Christos L. Chochos ,  Vasilis G. Gregoriou

IPC: C08G73/18 ,  H01M8/10 ,  H01M4/90

CPC classification number: C08G73/18 ,  H01M4/8668 ,  H01M4/8835 ,  H01M4/886 ,  H01M8/1004 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1081 ,  H01M2300/0082 ,  Y02P70/56

Abstract: New polymeric networks bearing benzimidazole units have been prepared. These polymeric networks will combine high proton conductivity, superior mechanical properties and thermal and oxidative stability due to the existence of polar benzimidazole groups and the presence of the unique polymeric architecture. The prepared polymer networks can be used in the catalyst ink of the electrodes in high temperature PEM fuel cells.

Abstract translation: 已经制备了具有苯并咪唑单元的新的聚合物网络。 由于存在极性苯并咪唑基团和存在独特的聚合物结构，这些聚合物网络将结合高质子传导性，优异的机械性能和热和氧化稳定性。 制备的聚合物网络可用于高温PEM燃料电池中电极的催化剂油墨中。